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Synthesis of Chiral and Cyclic pai-Conjugated System Using Cycloaddition

Research Project

Project/Area Number 22350046
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionWaseda University

Principal Investigator

SHIBATA Takanori  早稲田大学, 理工学術院, 教授 (80265735)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2011: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2010: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords共役系 / 不斉 / 環状化合物 / 触媒 / 機能性物質 / 選択的合成・反応 / 有機金属触媒 / ファインケミカルズ / 不斉合成 / 有機電子材料・素子
Research Abstract

We achieved an easy-to-use protocol for the synthesis of substituted o,o,o,o-tetraphenylenes: two triynes with phenylene-bridged 1,5-diyne moiety was homo-coupled by consecutive inter- and intramolecular [2+2+2] cycloadditions, and tetraphenylenes were obtained with good to excellent enantiomeric excess. We further examined meta-phenylene tethered triynes and achieved the first construction of o,m,o,m-tetraphenylenes in cis-form. In addition to the tetraphenylenes as dimers, o,m,o,m,o,m-hexaphenylenes were also obtained as trimers. In the reaction of para-phenylene tethered triynes, o,p,o,p,o,p-hexaphenylenes were major products along with the formation of o,p,o,p,o,p,o,p-octaphenylenes as tetramers.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (76 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (51 results) (of which Invited: 11 results) Book (3 results) Remarks (2 results)

  • [Journal Article] Enantioselective Synthesis of Planar-Chiral Phosphines with 1,N-Dioxa[n]paracyclophane Scaffold and Their Application as Chiral Ligands2014

    • Author(s)
      Kanda, K.; Oshima, S.; Shizuno, T.; Hamanaka, R.; Fukai, M.; Shibata, T.
    • Journal Title

      Heterocycles

      Volume: 88 Pages: 1355-1370

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ir(I)-Catalyzed Synthesis of N-Substituted Pyridones from 2-Alkoxypyridines via CO Bond Cleavage2013

    • Author(s)
      Pan, S; Ryu, N; Shibata, T.
    • Journal Title

      Org. Lett.

      Volume: 15 Pages: 1902-1905

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Cyclic Polyphenylenes by Consecutive Inter- and Intramolecular Cycloadditions of Ortho, Meta, and Para-Phenylene-Tethered Triynes2012

    • Author(s)
      Shibata, T. ; Fujimoto, M; Hirashima, H; Chiba, T; Endo, K. Synthesis
    • Journal Title

      Feature Article

      Volume: 44 Pages: 3269-3284

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversal enantioselectivity induced by achiral alcohols in asymmetric autocatalysis in the presence of a chiral diol as a chiral initiator2012

    • Author(s)
      Shibata, T ; Tarumi, H; Kawasaki, T; Soai, K.
    • Journal Title

      Tetrahedron : Asymmetry

      Volume: 23 Pages: 1023-1027

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ir(I)-Catalyzed Intermolecular Regio- and Enantioselective Hydroamination of Alkenes with Heteroaromatic Amines2012

    • Author(s)
      Pan, S.; Endo, K.; Shibata, T.
    • Journal Title

      Org. Lett.

      Volume: 14 Pages: 780-783

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition2012

    • Author(s)
      Shibata, T. ; Uchiyama, T.; Yoshinami, Y.; Takayasu, S.; Tsuchikama, K.; Endo, K.
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 1311-1313

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric ortho-lithiation of 1,n-dioxa[n]paracyclophane derivatives for the generation of planar chirality2012

    • Author(s)
      Kanda, K.; Hamanaka, R.; Endo, K.; Shibata, T.
    • Journal Title

      Tetrahedron

      Volume: 68 Pages: 1407-1416

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective synthesis of tripodal cyclophanes and pyridinophanes by intramolecular [2+2+2] cycloaddition2012

    • Author(s)
      Shibata, T. ; Miyoshi, M.; Uchiyama, T.; Endo, K.; Miura, N.; Monde, K.
    • Journal Title

      Tetrahedron

      Volume: 68 Pages: 2679-2686

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange2012

    • Author(s)
      Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T .
    • Journal Title

      Org. Biomol. Chem.

      Volume: 10 Pages: 3815-3818

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Cyclic Polyphenylenes by Consecutive Inter- and Intramolecular Cycloadditions of Ortho, Meta, and Para-Phenylene-Tethered Triynes2012

    • Author(s)
      Shibata, T; Fujimoto, M; Hirashima, H; Chiba, T; Endo, K.
    • Journal Title

      Synthesis

      Volume: 44 Issue: 21 Pages: 3269-3284

    • DOI

      10.1055/s-0032-1316793

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition2012

    • Author(s)
      Shibata, T.; Uchiyama, T.; Yoshinami, Y.; Takayasu, S.; Tsuchikama, K.
    • Journal Title

      Chem.Commun.

      Volume: 48 Issue: 9 Pages: 1311-1313

    • DOI

      10.1039/c1cc16762f

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] tioselective synthesis of tripodal cyclophanes and pyridinophanes by intramolecular [2+2+2] cycloaddition2012

    • Author(s)
      Shibata, T.; Miyoshi, M.; Uchiyama, T.; Endo, K.; Miura, N.; Monde, K.Enan
    • Journal Title

      Tetrahedron

      Volume: 68 Issue: 12 Pages: 2679-2686

    • DOI

      10.1016/j.tet.2012.01.046

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective construction of new chiral cyclic scaffolds using [2 + 2 + 2] cycloaddition2011

    • Author(s)
      Shibata, T. ; Uchiyama, T.; Hirashima, H.; Endo, K.
    • Journal Title

      Pure Appl. Chem.

      Volume: 83 Pages: 597-605

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Rh and Ir Catalyzed-Intramolecular Cycloaddition of Hexaynes for the Construction of New Chiral Skeletons2011

    • Author(s)
      Shibata, T.; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K.
    • Journal Title

      Heteroat.Chem.

      Volume: 22 Issue: 3-4 Pages: 363-370

    • DOI

      10.1002/hc.20691

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective construction of new chiral cyclic scaffolds using [2+2+2] cycloaddition2011

    • Author(s)
      Shibata, T., Uchiyama, T., Hirashima, H., Endo, K.
    • Journal Title

      Pure Applied Chemistry

      Volume: 83 Pages: 597-605

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Catalytic S_Nar Reaction of Nonactivated Fluoroarenes with Amines Using η^6 -Benzene Ru(II) Complex2010

    • Author(s)
      Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T.
    • Journal Title

      Synlett

      Pages: 2601-2606

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Intramolecular [2+2+2] Cycloaddition of Dienynes for the Construction of Adjacent Three Chiral Centers2010

    • Author(s)
      Shibata, T. ; Otomo, M.; Endo, K.
    • Journal Title

      Synlett

      Pages: 1235-1238

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Planar-Chiral 1,n-Dioxa[n]paracyclophanes via Catalytic Asymmetric Ortho-Lithiation2010

    • Author(s)
      Kanda, K.; Endo, K.; Shibata, T.
    • Journal Title

      Org. Lett.

      Volume: 12 Pages: 1980-1983

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sequential Catalytic Reactions for the Synthesis of Benzofulvenes Using an Iridium Complex with Dual Function2010

    • Author(s)
      Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T.
    • Journal Title

      Synlett

      Pages: 97-100

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] nantioselective Intramolecular [2+2+2] Cycloaddition of Dienynes for the Construction of Adjacent Three Chiral Centers2010

    • Author(s)
      Eshibata, T., Otomo, M., Endo, K.
    • Journal Title

      Synlett

      Pages: 1235-1238

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] パラシクロファン骨格を有する面不斉リン配位子のエナンチオ選択的合成と不斉カップリングへの応用2014

    • Author(s)
      大嶋 祥也, 静野 翼, 深井 実紅, 神田 和正, 柴田 高範
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋 大学(愛知)
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] ロジウム触媒による[2+2+2]付加環化反応を利用したジベンゾチオフェンジオキシド誘導体の効率合成2014

    • Author(s)
      峨家 愛実, 田原 優樹, 柴田 高範
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Enantioselective Synthesis of Paracyclophanes and Their Application as Chiral Ligands2013

    • Author(s)
      Shibata, T. ; Kanda, K.; Oshima, S.
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2013
    • Place of Presentation
      北京(中国)
    • Year and Date
      2013-12-04
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Enantioselective Synthesis of Paracyclophanes and Their Application2013

    • Author(s)
      Shibata, T. ; Kanda, K.; Oshima, S.
    • Organizer
      IUPAC 9th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      上海(中国)
    • Year and Date
      2013-10-19
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Consecutive Inter- and Intramolecular [2+2+2] Cycloadditions of Triynes for the Synthesis of Macrocyclic Heteroarylene2013

    • Author(s)
      柴田 高範, 藤本 雅 子, 大 谷 卓
    • Organizer
      14th European Symposium on Organic Reactivity
    • Place of Presentation
      プラハ(チェコ)
    • Year and Date
      2013-09-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Macrocyclic Heteroarylenes by Consecutive Inter- and Intramolecular Cycloadditions2013

    • Author(s)
      柴田 高範, 藤本 雅子, 大谷 卓
    • Organizer
      Asian Chemical Congress
    • Place of Presentation
      シンガポール(シンガポール)
    • Year and Date
      2013-08-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 不斉オルトリチオ化を利用した [n] パラシクロファン骨格を有する新規面不斉リン配位子の合成とパラジウム触媒を用いた不斉カップリングへの応用2013

    • Author(s)
      大嶋 祥也, 濵中 理紗, 神田 和正, 柴田 高範
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀)
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 不斉薗頭カップリング反応による面不斉を有するパラシクロファンの高エナンチオ選択的合成2013

    • Author(s)
      濵中 理紗, 神田 和正, 柴田 高範
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀)
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 連続的[2+2+2]付加環化反応を利用したチオフェンを含む環状ヘテロアリレン骨格の構築2013

    • Author(s)
      藤本 雅子, 大谷 卓, 柴田 高範
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀)
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Cyclic Polyarylenes by Consecutive Cycloadditions2013

    • Author(s)
      Shibata, T
    • Organizer
      The 4th Symposium on Chiral Science & Technology
    • Place of Presentation
      東京
    • Year and Date
      2013-03-01
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] New Approach to the Enantioselective Synthesis of Paracyclophanes2012

    • Author(s)
      Shibata, T.
    • Organizer
      Cambodian Malaysian Chemical Conference (CMCC)
    • Place of Presentation
      Siem Reap (Cambodia)
    • Year and Date
      2012-10-19
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Enantioselective Synthesis of Cyclic Polyarylenes by Consecutive Cycloadditions2012

    • Author(s)
      Shibata, T.
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis, IUPAC 8th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      西安(中国)
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 面不斉パラシクロファンの高エナンチオ選択的合成法の開発2012

    • Author(s)
      神田 和正, 濱中 理紗, 小池 珠美, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川)
    • Year and Date
      2012-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 不斉オルトリチオ化を利用した[n]パラシクロファン骨格を有する新規不斉リン配位子の合成と応用2012

    • Author(s)
      濱中 理紗,神田 和正,遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川)
    • Year and Date
      2012-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 連続的[2+2+2]付加環化反応を利用したヘテロ芳香環を含む環状ポリアリレン骨格の構築2012

    • Author(s)
      藤本 雅, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川)
    • Year and Date
      2012-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 連続的[2+2+2]付加環化反応を利用したヘテロ芳香環を含む環状ポリアリレン骨格の構築2012

    • Author(s)
      藤本雅子・遠藤恆平・柴田高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] アレーンルテニウム錯体を用いた触媒反応開発2012

    • Author(s)
      大塚 麻依子, 横山 裕也, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川)
    • Year and Date
      2012-03-25
    • Related Report
      2013 Final Research Report
  • [Presentation] η6アレーンルテニウム錯体を経由するα-置換スチレンへの触媒的不斉求核付加反応2012

    • Author(s)
      横山 裕也, 大塚 麻依子, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川)
    • Year and Date
      2012-03-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of cyclic polyphenylenes using consecutive [2+2+2] cycloadditions2011

    • Author(s)
      Shibata, T.
    • Organizer
      14th Asian Chemical Congress
    • Place of Presentation
      バンコク, タイ
    • Year and Date
      2011-09-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Synthesis of cyclic polyphenylenes using consecutive [2+2+2] cycloadditions2011

    • Author(s)
      T.Shibata
    • Organizer
      14th Asian Chemical Congress
    • Place of Presentation
      バンコク(タイ)(招待講演)
    • Year and Date
      2011-09-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Strategy for the Construction of Cyclic Polyphenylenes by Consecutive [2+2+2] Cycloaddition2011

    • Author(s)
      Shibata, T .; Fujimoto, M.; Hirashima, H.; Chiba, T.; Endo, K.
    • Organizer
      4th International Symposium on Advances in Synthetic and Medicinal Chemistry
    • Place of Presentation
      サンクトペテルブルグ, ロシア
    • Year and Date
      2011-08-24
    • Related Report
      2013 Final Research Report
  • [Presentation] New Strategy for the Construction of Cyclic Polyphenylenes by Consecutive [2+2+2] Cycloaddition2011

    • Author(s)
      T.Shibata, M.Fujimoto, H.Hiroshima, T.Chiba, K.Endo
    • Organizer
      4th International Symposium on Advances in Synthetic and Medicinal Chemistry
    • Place of Presentation
      サンクトペテルブルグ(ロシア)
    • Year and Date
      2011-08-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] HIGHLY ENANTIOSELECTIVE SYNTHESIS OF PYRIDINOPHANES BY INTRAMOLECULAR [2+2+2] CYCLOADDITION2011

    • Author(s)
      M.Miyoshi, T.Uchiyama, K.Endo, T.Shibata
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      上海(中国)
    • Year and Date
      2011-07-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] SYNTHESIS OF CYCLIC POLYPHENYLENES BY CONSECUTIVE INTER-AND INTRAMOLECULAR [2+2+2] CYCLO ADDITIONS2011

    • Author(s)
      M.Fujimoto, H.Hirashima, K.Endo, T.Shibata
    • Organizer
      14th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      上海(中国)
    • Year and Date
      2011-07-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] エナンチオ選択的オルトリチオ化を利用した新規な面不斉パラシクロファン骨格の創製2011

    • Author(s)
      神田 和正, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 分子間,分子内[2+2+2]付加環化反応を利用したシロール環を含むヘリセンのエナンチオ選択的合成2011

    • Author(s)
      内山 理文, 吉浪 雄亮, 土釜 恭直, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] η6-ベンゼンルテニウム錯体を用いた不活性フルオロアレーンと環状アミンの効率的な触媒的芳香族求核置換反応2011

    • Author(s)
      横山 裕也, 大塚 麻依子, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 連続的[2+2+2]付加環化反応を利用したヘキサフェニレン骨格の構築2011

    • Author(s)
      藤本 雅子, 平島 裕之, 千羽 達也, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 分子内[2+2+2]付加環化反応を利用したピリジノファンの高エナンチオ選択的合成2011

    • Author(s)
      三好 真由, 内山 理文, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 分子間・分子内[2+2+2]付加環化反応を利用したシロール環を含むヘリセンのエナンチオ選択的合成2011

    • Author(s)
      内山理文・吉浪雄亮・土釜恭直・遠藤恆平・柴田高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 連続的[2+2+2]付加環化反応を利用したヘキサフェニレン骨格の構築2011

    • Author(s)
      藤本雅子・平島裕之・千羽達也・遠藤恆平・柴田高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 分子内[2+2+2]付加環化反応を利用したピリジノファンの高エナンチオ選択的合成2011

    • Author(s)
      三好真由・内山理文・遠藤恆平・柴田高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] スチレンクロム錯体に対する逆マルコフニコフ型アルコキシ化2011

    • Author(s)
      大塚 麻依子, 遠藤 恆平, 柴田 高範
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川)
    • Year and Date
      2011-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] トリインの連続的分子間・分子内付加環化反応による環状ポリフェニレン類の触媒的合成2011

    • Author(s)
      平島裕之・藤本雅子・千羽達也・遠藤恆平・柴田高範
    • Organizer
      The 2nd Symposium on Chiral Science & Technology
    • Place of Presentation
      日本・東京・早稲田大学
    • Year and Date
      2011-03-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enantioselective synthesis of chiral tripodal cage compounds by intramolecular [2+2+2] cycloaddition of branched triynes and diyne-nitriles2010

    • Author(s)
      T.Uchiyama, K.Endo, T.Shibata
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      米国、ホノルル
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Catalytic Synthesis of Cyclic Polyphenylenes : Consecutive Inter- and Intramolecular Cycloadditions of Several Triynes.2010

    • Author(s)
      H.Hirashima, M.Fujimoto, T.Chiba, K.Endo, T.Shibata
    • Organizer
      2011 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      米国、ホノルル
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Construction of New Chiral Cyclic Skeletons Based on the Enantioselective [2+2+2] Cycloaddition2010

    • Author(s)
      Shibata, T
    • Organizer
      7th Symposium on Chemical Approaches to Chirality
    • Place of Presentation
      東京理科大学, 東京
    • Year and Date
      2010-09-29
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Construction of New Chiral Cyclic Skeletons Based on the Enantioselective [2+2+2] Cycloaddition2010

    • Author(s)
      T.Shibata
    • Organizer
      7th Symposium on Chemical Approaches to Chirality
    • Place of Presentation
      日本、東京、東京理科大学(招待講演)
    • Year and Date
      2010-09-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enantioselective Construction of New Chiral Cyclic Scaffolds Using [2+2+2] Cycloaddition2010

    • Author(s)
      18th International Conference on Organic Synthesis (ICOS18)
    • Organizer
      18th International Conference on Organic Synthesis (ICOS18)
    • Place of Presentation
      ノルウェー、ベルゲン
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enantioselective Construction of New Chiral Cyclic Scaffolds Using [2+2+2] Cycloaddition2010

    • Author(s)
      Shibata, T
    • Organizer
      18th International Conference on Organic Synthesis (ICOS18)
    • Place of Presentation
      ベルゲン, ノルウェー
    • Year and Date
      2010-08-02
    • Related Report
      2013 Final Research Report
  • [Presentation] 触媒的不斉付加環化反応の新展開2010

    • Author(s)
      柴田 高範
    • Organizer
      ファインケミカルズ合成触媒のフロンティア
    • Place of Presentation
      東京農工大学, 東京
    • Year and Date
      2010-06-05
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 触媒的不斉付加環化反応の新展開2010

    • Author(s)
      柴田高範
    • Organizer
      ファインケミカルズ合成触媒のフロンティア
    • Place of Presentation
      日本、東京、東京農工大学(招待講演)
    • Year and Date
      2010-06-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Axially Chiral Polyaryls using Ir-catalyzed [2+2+2] Cycloaddition2010

    • Author(s)
      Shibata, T
    • Organizer
      1st Annual World Congress of Catalytic Asymmetric Synthesis-2010
    • Place of Presentation
      北京, 中国
    • Year and Date
      2010-05-21
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Enantioseleetive Synthesis of Axially Chiral Polyaryls using Ir-catalyzed [2+2+2] Cycloaddition2010

    • Author(s)
      T.Shibata
    • Organizer
      1st Annual World Congress of Catalytic Asymmetric Synthesis-2010
    • Place of Presentation
      中国・北京(招待講演)
    • Year and Date
      2010-05-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Heteroarylenes by Consecutive Inter- and Intramolecular Cycloadditions

    • Author(s)
      柴田 高範, 藤本 雅子, 大谷 卓
    • Organizer
      Asian Chemical Congress
    • Place of Presentation
      シンガポール
    • Related Report
      2013 Annual Research Report
  • [Presentation] Consecutive Inter- and Intramolecular [2+2+2] Cycloadditions of Triynes for the Synthesis of Macrocyclic Heteroarylenes

    • Author(s)
      柴田 高範, 藤本 雅子, 大谷 卓
    • Organizer
      14th European Symposium on Organic Reactivity
    • Place of Presentation
      プラハ
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Paracyclophanes and Their Application

    • Author(s)
      Shibata, T.; Kanda, K.; Oshima, S.
    • Organizer
      IUPAC 9th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      上海
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Paracyclophanes and Their Application as Chiral Ligands

    • Author(s)
      Shibata, T.; Kanda, K.; Oshima, S.
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2013
    • Place of Presentation
      北京
    • Related Report
      2013 Annual Research Report
  • [Presentation] ロジウム触媒による[2+2+2]付加環化反応を利用したジベンゾチオフェンジオキシド誘導体の効率合成

    • Author(s)
      峨家 愛実, 田原 優樹, 柴田 高範
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Cyclic Polyarylenes by Consecutive Cycloaddtions IUPAC 8th International Conference on Novel Materials and their Synthesis

    • Author(s)
      T. Shibata, M. Fujimoto, H. Hirashima, K. Endo
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      中国・西安
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthesis of Cyclic Polyarylenes by Consecutive Cycloadditions

    • Author(s)
      T. Shibata, M. Fujimoto, H. Hirashima, K. Endo
    • Organizer
      The 4Th Symposium on Chiral Science & Technology
    • Place of Presentation
      日本・東京
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] Asymmetric Cycloaddition Reactions in in Comprehensive Inorganic Chemistry II, Vol 62013

    • Author(s)
      Shibata, T.
    • Publisher
      Elsevier
    • Related Report
      2013 Annual Research Report
  • [Book] Synthesis of Planar Chiral Aromatic Compounds in Transition-Metal-Mediated Aromatic Ring Construction2013

    • Author(s)
      Shibata, T.; Tanaka, K.
    • Publisher
      Wiley-VCH
    • Related Report
      2013 Annual Research Report
  • [Book] Synthesis of Axially Chiral Aromatic Compounds in Transition-Metal-Mediated Aromatic Ring Construction,2013

    • Author(s)
      Tanaka, K.; Shibata, T.
    • Publisher
      Wiley-VCH
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.waseda.ac.jp/shibata/

    • Related Report
      2013 Final Research Report
  • [Remarks] 柴田研究室・発表論文

    • URL

      http://www.chem.waseda.ac.jp/shibata/japanese/attainment/attainment.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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