| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2010: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
|
|---|
| Research Abstract |
We have developed various organic-inorganic hybrid complexes having successive physical properties coupled with photon-spin-charge. The topics are as follows. (1) We synthesized Ph4N[MnIIFeIII(C2O3S)3] exhibiting a rapid spin equilibrium (τ < 10-7 s) between the high-spin and low-spin states at the FeIIIO3S3 site. Owing to the fluctuation of internal magnetic field caused by the rapid spin equilibrium, Ph4N[MnIIFeIII(mto)3] undergoes the successive magnetic phase transitions at 30 K and 23 K. (2)We synthesized a pH-sensitive spin-crossover complex film consisting of [FeII(diAMsar)] (diAMsar =1,8-diaminosarcophagine) and ion-exchange polymer, Nafion. By using this pH-sensitive spin-crossover complex film, we succeeded in visually detecting the proton flow in Nafion
|
