Budget Amount *help |
¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
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Research Abstract |
(1) Thermochromic organic magnetic materials: A series of ground triplet compounds showed successive structural phase transitions, and each phase was characterized to be S = 0, 1/2, or 1 spin state. (2) Paramagnetic host-guest compounds: Biradical host compounds were synthesized. The ground spin state was switched between the S = 0 and 1 states on adding or removing diamagnetic guest ions. (3) Radical-coordinated lanthanide complexes: 4f-3d and 4f-2p Hetero-spin systems are prepared, and the exchange coupling among the hetero-spins were precisely determined.
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