Emergence of Functions in Self-Assembled Cavitand-Based Capsules
Project/Area Number |
22350060
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials chemistry
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Research Institution | Shizuoka University |
Principal Investigator |
KOBAYASHI Kenji 静岡大学, 創造科学技術大学院, 教授 (40225503)
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Project Period (FY) |
2010 – 2012
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Project Status |
Completed (Fiscal Year 2012)
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Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
|
Keywords | 超分子 / 分子自己集合 / カプセル / 水素結合 / 動的共有結合 / 包接 / 高分子 / 分子認識 / 超分子化学 / ポリマー |
Research Abstract |
(1) We elucidated the unusual stability of our self-assembled hydrogen-bonded cavitand heterocapsule with encapsulation of 1,4-bis(1-propynyl)benzene. Based on this result, we designed and synthesized a dumbbell type of cavitand molecules directed to supramolecular capsule polymers. (2) We found that our self-assembled boronic ester cavitand capsule serves as a guard nanocontainer against photochemical reactions of anthracene derivatives by the encapsulation. We also succeeded in the synthesis of a chiral boronic ester cavitand capsule.
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Report
(4 results)
Research Products
(23 results)
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[Journal Article] Bis(methylthio)tetracenes : Synthesis, Crystal Packing structures, and OFET Properties2011
Author(s)
T.Kimoto, K.Tanaka, M.Kawahata, K.Yamaguchi, S.Otsubo, Y.Sakai, Y.Ono, A.Ohno, K.Kobayashi
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Journal Title
J.Ore.Chem.
Volume: 76
Issue: 12
Pages: 5018-5025
DOI
Related Report
Peer Reviewed
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