| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
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| Research Abstract |
(1) We elucidated the unusual stability of our self-assembled hydrogen-bonded cavitand heterocapsule with encapsulation of 1,4-bis(1-propynyl)benzene. Based on this result, we designed and synthesized a dumbbell type of cavitand molecules directed to supramolecular capsule polymers.
(2) We found that our self-assembled boronic ester cavitand capsule serves as a guard nanocontainer against photochemical reactions of anthracene derivatives by the encapsulation. We also succeeded in the synthesis of a chiral boronic ester cavitand capsule.
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