Development of organic integrated circuit by patterning of p-type/n-type properties in monolithic organic semiconductor material

• Project/Area Number: 22350084
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials/Devices
• Research Institution: The Institute of Physical and Chemical Research
• Principal Investigator: AOYAMA Tetsuya 独立行政法人理化学研究所, 内山元素化学研究室, 専任研究員 (50342738)
• Project Period (FY): 2010-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000); Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2010: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
• Keywords: 有機半導体素子 / 有機トランジスタ / チエノキノイド / 量子化学計算

Outline of Final Research Achievements

Organic devices with a quinoidal oligothiophene derivative (QQT(CN)4) have been developed and the structure-property relationship in organic semiconductor has been investigated. A simple and versatile solution-processing method based on molecular self-assembly was used to fabricate one dimensional organic single crystal microwires of QQT(CN)4. The single crystal microwires exhibited excellent ambipolar transport properties. The molecular packing plays a key-role in a large range of organic optoelectronics devices. A combination of X-ray diffraction technique, atomic force microscopy, quantum chemical calculation and transistor characterization could provide significant insights into the interplay between molecular packing and charge transport properties in organic thin films.

Research Products

• [Journal Article] Ambipolar organic field-effect transistors based on solution-processed single crystal microwires of a quinoidal oligothiophene derivative (2015)
  • Author(s): J. C. Ribierre, L. Zhao, S. Furukawa, T. Kikitsu, D. Inoue, A. Muranaka, K. Takaishi, T. Muto, S. Matsumoto, D. Hashizume, M. Uchiyama, P. Andre, C. Adachi, T. Aoyama
  • Journal Title: Chem. Commun. Volume: 51 Issue: 27 Pages: 5836-5839
  • DOI: 10.1039/c4cc09608h
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Influence of the grain orientation on the charge transport properties of organic field-effect transistors (2014)
  • Author(s): J. C. Ribierre, Y. Yokota, M. Sato, A. Ishizuka, T. Tanaka, S. Watanabe, M. Matsumoto, A. Muranaka, S. Matsumoto, M. Uchiyama, T. Aoyama
  • Journal Title: RSC Adv. Volume: 4 Issue: 69 Pages: 36729-36737
  • DOI: 10.1039/c4ra04964k
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Non-volatile organic memory with sub-millimetre bending radius (2014)
  • Author(s): R. H. Kim, H. J. Kim, I. Bae, S. K. Hwang, D. B. Velusamy, S. M. Cho, K. Takaishi, T. Muto, D. Hashizume, M. Uchiyama, P. Andre´, F. Mathevet, B. Heinrich, T. Aoyama, D. E. Kim, H. Lee, J. C. Ribierre, C. Park
  • Journal Title: Nature Commun. Volume: - Issue: 1 Pages: 1-12
  • DOI: 10.1038/ncomms4583
  • Peer Reviewed / Open Access
• [Journal Article] Influence of gate dielectric on the ambipolar characteristics of solution-processed organic field-effect transistors (2011)
  • Author(s): J. C. Ribierre, S. Ghosh, K. Takaishi, T. Muto, T. Aoyama
  • Journal Title: Journal of Physics D : Applied Physics Volume: 44 Issue: 20 Pages: 205102-205102
  • DOI: 10.1088/0022-3727/44/20/205102
  • Peer Reviewed
• [Journal Article] Flexible organic field-effect transistors and complementary inverters based on a solution-processable quinoidal oligothiophene derivative (2011)
  • Author(s): J. C. Ribierre, K. Takaishi, T. Muto, T. Aoyama
  • Journal Title: Optical Materials Volume: 33 Issue: 9 Pages: 1415-1418
  • DOI: 10.1016/j.optmat.2011.03.015
  • Peer Reviewed
• [Journal Article] Thickness Dependence of the Ambipolar Charge Transport Properties in Organic Field-Effect Transistors based on a Quinoidal Oligothiophene Derivative (2011)
  • Author(s): J. C. Ribierre, S. Watanabe, M. Matsumoto, T. Muto, D. Hashizume, T. Aoyama
  • Journal Title: The Journal of Physical Chemistry C Volume: 115 Issue: 42 Pages: 20703-20709
  • DOI: 10.1021/jp206129g
  • Peer Reviewed
• [Journal Article] Flexible organic field-effect transistors and complementary inverters based on a solution-processable quinoidal oligothiophene derivative
  • Author(s): Jean-Charles RIBIERRE
  • Journal Title: Optical Materials Volume: (印刷中)
  • Peer Reviewed
• [Presentation] 有機半導体材料における分子パッキング制御と光電子デバイスへの応用 (2014)
  • Author(s): 青山哲也
  • Organizer: 平成26年度理研シンポジウム「有機エレクトロニクスの実用化に向けた次世代製造技術」
  • Place of Presentation: 理化学研究所(埼玉県和光市)
  • Year and Date: 2014-12-03
• [Presentation] Control of molecular packing and grain orientation for organic optoelectronic devices (2014)
  • Author(s): T. Aoyama
  • Organizer: The 14th International Symposium on Advanced Organic Photonics (ISAOP-14)
  • Place of Presentation: 大阪大学銀杏会館(大阪府吹田市)
  • Year and Date: 2014-11-05
  • Invited
• [Presentation] フレキシブルなチエノキノイド半導体薄膜におけるラビングによる分子パッキング構造制御 (2014)
  • Author(s): 青山哲也, 横田裕基, 橋爪大輔, 高石和人, 内山真伸, Pascal Andre, 田中利彦, 松本真哉, Jean-Charles Ribierre
  • Organizer: 第75回応用物理学会秋季学術講演会
  • Place of Presentation: 北海道大学(北海道札幌市)
  • Year and Date: 2014-09-17
• [Presentation] Analysis of molecular packing and carrier transport in bisazomethine dye derivatives by X-ray diffraction and quantum chemical calculations (2014)
  • Author(s): T. Aoyama, Y. Yokota, B.-S. Kim, T. Tanaka, D. Hashizume, A. Muranaka, M. Uchiyama, J. C. Ribierre, S. Matsumoto
  • Organizer: 22nd International Conference for Science and Technology of Synthetic Metals (ICSM 2014)
  • Place of Presentation: Turku, Finland
  • Year and Date: 2014-07-01
• [Presentation] チエノキノイド薄膜トランジスタにおける両極性電荷輸送特性の膜厚依存性と分子パッキング構造 (2012)
  • Author(s): 青山哲也, 渡邉智, 松本睦良, 橋爪大輔, 石塚亜弥, 松本真哉, 武藤豪志, 高石和人, 村中厚哉, 内山真伸, J. C. Rjbierre
  • Organizer: 第59回応用物理学関係連合講演会
  • Place of Presentation: 早稲田大学(東京都)
  • Year and Date: 2012-03-16
• [Presentation] Control of the optical and charge transport properties of a solution-processable quinoidal oligothiophene derivative (2011)
  • Author(s): J. C. Ribierre, O. P. M. Gaudin, K. Takaishi, P. Andrd, T. Fujihara, T. Muto, M. Uchiyama, T. Aoyama
  • Organizer: The 7th International Conference on Advanced Materials and Devices (ICAMD2011)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2011-12-09
• [Presentation] Optical and charge transport properties of a solution-processable low band gap quinoidal oligothiophene derivative (2011)
  • Author(s): J. C. Ribierre, T. Aoyama
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics
  • Place of Presentation: Gyeongju, Korea
  • Year and Date: 2011-09-17
  • Invited
• [Presentation] Reversible p-n conversion and logic gates based on a solution-processible thienoquinoid semiconductor (2011)
  • Author(s): T. Aoyama, T. Fujihara, T. Muto, K. Takaishi, A. Nakao, S. Watanabe, M. Matsumoto, S. Matsumoto, S. Inoue, A. Muranaka, D. Hashizume, M. Uchiyama, J. C. Ribierre
  • Organizer: The 11th European Conference on Molecular Electronics (ECME2011)
  • Place of Presentation: Barcelona, Spain
  • Year and Date: 2011-09-09
• [Presentation] Role of the film morphology on the ambipolar charge transport properties of a quinoidal oligothiophene derivative (2011)
  • Author(s): J. C. Ribierre, T. Fujihara, S. Watanabe, M. Matsumoto, T. Muto, K. Takaishi, A. Nakao, S. Matsumoto, S. Inoue, A. Muranaka, D. Hashizume, M. Uchiyama, T. Aoyama
  • Organizer: The 2011 Spring Meeting of the European Mater. Res. Soc. (E-MRS), the Int. Conf. on Adv. Mater. (ICAM) of the Int. Union of Mater. Res. Soc. (IUMRS)
  • Place of Presentation: Nice, France
  • Year and Date: 2011-05-09
• [Presentation] チエノキノイド半導体における加熱・溶媒処理によるリバーシブルp-n変換 (2010)
  • Author(s): 青山 哲也
  • Organizer: 第71回応用物理学会学術講演会
  • Place of Presentation: 長崎県長崎市
  • Year and Date: 2010-09-15
• [Presentation] Direct laser writing of solution-processed organic CMOS logic circuits and p-n microstructures (2010)
  • Author(s): Jean-Charles RIBIERRE
  • Organizer: International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
  • Place of Presentation: 京都府京都市
  • Year and Date: 2010-07-08
• [Presentation] Carrier transport properties and quantum chemical calculations in ambipolar organic thin film transistors
  • Author(s): T. Aoyama, Y. Yokota, A. Muranaka, A. Ishizuka, M. Sato, T. Tanaka, D. Hashizume, T. Muto, K. Takaishi, M. Uchiyama, S. Matsumoto, J. C. Ribierre
  • Organizer: E-MRS 2013 Spring Meeting
  • Place of Presentation: Strasbourg, France
• [Presentation] Study of exciton diffusion in a solution-processable low bandgapquinoidaloligothiophene derivative using femtosecond transient absorption measurements
  • Author(s): H. -Y. Shin, J. H. Woo, M. J. Kwon, M. Barthelemy, M. Vomir, T. Muto, T. Takaishi, M. Uchiyama, D. Hashizume, T. Aoyama, D. -W. Kim, S. Yoon, J. -Y. Bigot, J. W. Wu, J. C. Ribierre
  • Organizer: E-MRS 2013 Spring Meeting
  • Place of Presentation: Strasbourg, France
• [Presentation] Quantum chemical calculations and photoresponses in bisazomethine dye ambipolar thin film transistors
  • Author(s): T. Aoyama
  • Organizer: The 13th International Symposium on Advanced Organic Photonics (ISAOP-13)
  • Place of Presentation: Kingston, Canada
  • Invited
• [Presentation] 有機トランジスタにおけるambipolar輸送特性の量子化学計算による検討
  • Author(s): 青山哲也, 横田裕基，村中厚哉，石塚亜弥，田中利彦，橋爪大輔，武藤豪志，高石和人，内山真伸，ジーン・チャールズリビエル，松本真哉
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 京都, 日本
• [Presentation] Thermally Induced Majority Carriers Conversion Kinetics in Quinoidal Thiophene
  • Author(s): L. Mazur, F. Mathevet, A. -J. Attias, K. Matczyszyn, M. Samoc, J. W. Wu, K. Takaishi, T. Muto, M. Uchiyama, T. Aoyama, J. C. Ribierre
  • Organizer: 12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
  • Place of Presentation: Auckland, NewZealand
• [Presentation] Analysis by quantum chemical calculations on ambipolar organic thin film transistors
  • Author(s): T. Aoyama, Y. Yokota, A. Muranaka, A. Ishizuka, T. Tanaka, D. Hashizume, T. Muto, K. Takaishi, M. Uchiyama, S. Matsumoto, J. C. Ribierre
  • Organizer: 12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
  • Place of Presentation: Auckland, NewZealand
• [Presentation] Control of Molecular Alignment and Transport Properties of Bisazomethine Dye Thin-Film Transistors
  • Author(s): Y. Yokota, B. -S. Kim, A. Ishizuka, M. Sato, J. C. Ribierre, T. Tanaka, A. Muranaka, M. Uchiyama, S. Matsumoto, T. Aoyama
  • Organizer: 12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM2013)
  • Place of Presentation: Auckland, NewZealand
• [Presentation] ビスアゾメチン色素誘導体を用いたトランジスタにおける分子配向と輸送特性の相関
  • Author(s): 横田裕基, Byung-Soon Kim，橋爪大輔，Jean-Charles Ribierre，田中利彦，村中厚哉，内山真伸，松本真哉，青山哲也
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 相模原, 日本