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Characterization of acidic properties of mesoporous silica catalysts and its application to organic synthesis

Research Project

Project/Area Number 22350089
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

IWAMOTO Masakazu  東京工業大学, 資源化学研究所, 教授 (10108342)

Co-Investigator(Kenkyū-buntansha) ISHITANI Haruo  東京工業大学, 資源化学研究所, 講師 (50302617)
AKIYAMA Katsuhiro  東京工業大学, 資源化学研究所, 助教 (10550569)
TANAKA Masashi  東京工業大学, 資源化学研究所, 助教 (00528002)
Project Period (FY) 2010-04-01 – 2013-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2011: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2010: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywordsメソ多孔体 / シリカ / 固体触媒 / 有機合成 / バイオエタノール / 酸触媒作用 / メゾ多孔体 / エタノール / 銅イオン担持体 / シリカメゾ多孔体 / ナノ細孔 / ニッケルイオン / 酸触媒 / 固体NMR / 壁イオン交換 / リン酸イオン / バイオマスリファイナリー / セルロース / グルコース
Research Abstract

The present group has found the new type of acid-type catalysis on mesoporous silica. In this study, the acid catalysis was characterized in details and then combined with metal ions. At first, the acid catalysis was investigated as a function of the pore diameter, the shape of the pore, and a surface aluminum ion as an impurity. The volcano-shaped dependence of the catalysis was clearly found on the pore diameter and was not dependent on the kinds of reactants, indicating that the surface acidity resulted from the pore structure. Next, the combination of the acidity with a copper ion resulted in the catalysis for the selective aryl formation, which was the first example reported on copper except for the catalysis on Pd. At last, nickel ion-loaded mesoporous silica, in which nickel ion was supported using the template ion exchange method, was found to show a catalytic activity for the conversion of bio-ethanol to propene. The reaction pathways were also suggested.

Report

(4 results)
  • 2013 Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (158 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (62 results) (of which Peer Reviewed: 52 results) Presentation (80 results) (of which Invited: 3 results) Book (4 results) Remarks (1 results) Patent(Industrial Property Rights) (11 results) (of which Overseas: 1 results)

  • [Journal Article] Surface structure of yttrium- modified ceria catalysts and reaction pathways from ethanol to propene2014

    • Author(s)
      F. Hayashi, M. Tanaka, D. Lin, M. Iwamoto
    • Journal Title

      J. Catal.

      Volume: 316 Pages: 112-120

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic and mechanistic studies on direct H2O2 synthesis from H2 and O2 catalyzed by Pd in the presence of H+ and Br−in water2014

    • Author(s)
      T. Deguchi, H. Yamano, M. Iwamoto
    • Journal Title

      Catal. Today

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective catalytic conversion of bio-ethanol to propene : a review of catalysts and reaction pathways2014

    • Author(s)
      M. Iwamoto
    • Journal Title

      Catal. Today

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Propene Synthesis from Ethene or Ethanol : Catalysis and Characterization of Nickel Ion-Loaded Mesoporous Silica, "Comprehensive Guide for Mesoporous Materials"2014

    • Author(s)
      M. Iwamoto, M. Tanaka
    • Journal Title

      Nova Science Pub., New York

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Yttrium- Modified Ceria as a Highly Durable Catalyst for the Selective Conversion of Ethanol to Propene and Ethene2013

    • Author(s)
      F. Hayashi, M. Iwamoto
    • Journal Title

      ACS Catalysis

      Volume: 3 Pages: 14-14

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Hydrodeoxygenation of Cellulose and Xylan to Lower Alkanes on Ruthenium Catalysts in Subcritical Water2013

    • Author(s)
      Y. Osaka, Y. Ikeda, M. Iwamoto
    • Journal Title

      Biomass and Bioenergy

      Volume: 56 Pages: 1-7

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Porous MOx-ZrO2 (M = W, Cr, Mo, and V) Composite Oxides through Wall Ion-Exchange Method2013

    • Author(s)
      I. Suh, S. Hori, M. Tanaka, M. Iwamoto
    • Journal Title

      Micro. Meso. Mater.

      Pages: 4970-4975

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Properties of Surface Sites on Pd Clusters for Direct H2O2 Synthesis from H2 and O2: A DFT Study2013

    • Author(s)
      T. Deguchi, M. Iwamoto
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Pages: 18540-18548

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct and Selective Production of Propene from Bio-Ethanol on Sc-Loaded In2O3 Catalysts2013

    • Author(s)
      M. Iwamoto, S. Mizuno, M. Tanaka
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Pages: 7214-7220

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] ナノ反応場の精密調製と触媒反応の制御2013

    • Author(s)
      岩本正和
    • Journal Title

      触媒の設計・反応制御事例集

      Volume: 第2章第1節 Pages: 53-59

    • Related Report
      2013 Final Research Report
  • [Journal Article] In2O3触媒上でのエタノールのプロピレンへの選択的転換2013

    • Author(s)
      水野翔太,黒澤美佳,田中大士,岩本正和
    • Journal Title

      触媒年鑑2013

      Pages: 290-291

    • Related Report
      2013 Final Research Report
  • [Journal Article] 形状選択性に頼らないでバイオエタノールを直接プロピレンに転換する2013

    • Author(s)
      岩本正和
    • Journal Title

      バイオインダストリー

      Volume: 30(5) Pages: 3-10

    • Related Report
      2013 Final Research Report
  • [Journal Article] ゼオライトを使わないでバイオエタノールをプロピレンに転換する2013

    • Author(s)
      田中大士、岩本正和
    • Journal Title

      触媒

      Volume: 55 Pages: 256-263

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] "Direct and Selective Production of Propene from Bio-Ethanol on Sc-Loaded In2O3 Catalysts"2013

    • Author(s)
      Masakazu Iwamoto, Shota Mizuno, Masashi Tanaka
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 22 Pages: 7214-7220

    • DOI

      10.1002/chem.201203977

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Catalytic Properties of Surface Sites on Pd Clusters for Direct H2O2 Synthesis from H2 and O2: A DFT Study"2013

    • Author(s)
      Takashi Deguchi, Masakazu Iwamoto
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 36 Pages: 18540-18548

    • DOI

      10.1021/jp4056297

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Direct hydrodeoxygenation of cellulose and xylan to lower alkanes on ruthenium catalysts in subcritical water"2013

    • Author(s)
      Yuriko Osaka, Yoichi Ikeda, Daisuke Hashizume, Masakazu Iwamoto
    • Journal Title

      Biomass and Bioenergy

      Volume: 56 Issue: 28 Pages: 4970-4975

    • DOI

      10.1002/ejic.201300613

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Yttrium-Modified Ceria As a Highly Durable Catalyst for the Selective Conversion of Ethanol to Propene and Ethene"2013

    • Author(s)
      Fumitaka Hayashi, Masakazu Iwamoto
    • Journal Title

      ACS Catal.

      Volume: 3 Issue: 1 Pages: 14-17

    • DOI

      10.1021/cs3006956

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 「ゼオライトを使わないでバイオエタノールをプロピレンへ転換する」2013

    • Author(s)
      岩本正和,田中大士
    • Journal Title

      触媒

      Volume: 855 Pages: 256-263

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 「形状選択性に頼らないでバイオエタノールを直接プロピレンに転換する」2013

    • Author(s)
      岩本正和
    • Journal Title

      月刊バイオインダストリー

      Volume: 30 Pages: 3-10

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Effect of Pore Size and Nickel Content of Ni-MCM-41 on Catalytic Activity for Ethene Dimerization and Local Structures of Nickel Ions2012

    • Author(s)
      M. Tanaka, A. Itadani, Y. Kuroda, M. Iwamoto
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 5664-5664

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of direct H2O2 synthesis from H2 and O2 on a Pd nano-particle catalyst protected with polyvinylpyrrolidone2012

    • Author(s)
      T. Deguchi, H. Yamano, M. Iwamoto
    • Journal Title

      J. Catal.

      Volume: 287 Pages: 55-55

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric S–O Bond Formation by Oxidation2012

    • Author(s)
      H. Ishitani, M. Iwamoto
    • Journal Title

      Comprehensive Chirality

      Volume: 5 Pages: 198-198

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-path and selective conversion of ethanol to propene on scandium-modified indium oxide catalysts2012

    • Author(s)
      S. Mizuno, M. Kurosawa, M. Tanaka, M. Iwamoto
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 892-892

    • NAID

      10031030788

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reply to "Comment on 'Effect of Pore Size and Nickel Content of Ni-MCM-41 on Catalytic Activity for Ethene Dimerization and Local Structures of Nickel Ions'"2012

    • Author(s)
      M. Tanaka, Y. Kuroda, M. Iwamoto
    • Journal Title

      J. Phys. Chem.

      Volume: C 116 Pages: 22649-22649

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 足し算から掛け算へ-メゾ多孔体への機能集積による触媒反応の高効率化2012

    • Author(s)
      石谷暖郎,岩本正和
    • Journal Title

      化学

      Volume: 67 Pages: 66-66

    • Related Report
      2013 Final Research Report
  • [Journal Article] ナノ空間が創出する新しい触媒機能2012

    • Author(s)
      岩本正和
    • Journal Title

      科学と工業

      Volume: 86 Pages: 145-145

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] 新世代ナノチューブの合成と応用2012

    • Author(s)
      岩本正和
    • Journal Title

      未来材料

      Volume: 11(12) Pages: 1-1

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] Dynamics of direct H2O2 synthesis from H2 and O2 on a Pd nano-particle catalyst protected with polyvinylpyrrolidone2012

    • Author(s)
      T.Deguchi
    • Journal Title

      J.Catal.

      Volume: 287 Pages: 55-61

    • DOI

      10.1016/j.jcat.2011.12.004

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 足し算から掛け算へ-メゾ多孔体への機能集積による触媒反応の高効率化-2012

    • Author(s)
      石谷暖郎
    • Journal Title

      化学

      Volume: 67(2) Pages: 66-67

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Effect of Pore Size and Nickel Content of Ni-MCM-41 on Catalytic Activity for Ethene Dimerization and Local Structures of Nickel Ions2012

    • Author(s)
      M.Tanaka
    • Journal Title

      J.Phys.Chem.C

      Volume: (in press) Issue: 9 Pages: 5664-5672

    • DOI

      10.1021/jp2103066

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and Simulation Including Mass-Transfer Processes of Direct H2O2 Synthesis from H2 and O2 over Pd/C Catalyst in Water Containing H+ and Br- Ions2011

    • Author(s)
      T. Deguchi, M. Iwamoto
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 50 Pages: 4351-4358

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fast and Quantitative Dehydration of Lower Alcohols to Corresponding Olefins on Mesoporous Silica Catalyst2011

    • Author(s)
      T. Haishi, K. Kasai, M. Iwamoto
    • Journal Title

      Chem. Lett.

      Volume: 40 Pages: 614-616

    • NAID

      10028243974

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia synthesis over rhenium supported on mesoporous silica MCM-412011

    • Author(s)
      F. Hayashi, M. Iwamoto
    • Journal Title

      Micro. Meso. Mater.

      Volume: 146 Pages: 184-189

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reaction mechanism of direct H2O2 synthesis from H2 and O2 over Pd/C catalyst in water with H+ and Br- ions2011

    • Author(s)
      T. Deguchi, M. Iwamoto
    • Journal Title

      J. Catal.

      Volume: 280 Pages: 239-246

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of Ethanol into Polyolefin Building Blocks : Reaction Pathways on Nickel Ion-loaded Mesoporous Silica2011

    • Author(s)
      M. Iwamoto, K. Kasai, T. Haishi
    • Journal Title

      ChemSusChem

      Volume: 4 Pages: 1055-1058

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One Step Formation of Propene from Ethene or Ethanol through Metathesis on Nickel Ion-loaded Silica2011

    • Author(s)
      M. Iwamoto
    • Journal Title

      Molecules

      Volume: 16 Pages: 7844-7863

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Role of entropy in supramolecular photochirogenesis : enantiodifferentiating photoisomerization of cyclooctenes in chiral sensitizer- immobilized MCM-41 cavities2011

    • Author(s)
      R. Maeda, T. Wada, A. Kusaka, T. Mori, M. Iwamoto, Y. Inoue
    • Journal Title

      Photochem. Photobiol. Sci.

      Volume: 10 Pages: 1390-1392

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reaction pathways of glucose and fructose on Pt nanoparticles in subcritical water under a hydrogen atmosphere"2011

    • Author(s)
      Y. Kanie, K. Akiyama, M. Iwamoto
    • Journal Title

      Catal. Today

      Volume: 178 Pages: 58-63

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 非可食原料バイオ燃料への可能性を開く-セルロースの水中水素化による燃料合成2011

    • Author(s)
      池田陽一,逢坂有里子,秋山勝宏,岩本正和
    • Journal Title

      MATERIAL STAGE

      Volume: 11 Pages: 1-2

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] エチレンをプロピレンへ2011

    • Author(s)
      岩本正和
    • Journal Title

      未来材料

      Volume: 11(1) Pages: 24-29

    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Journal Article] Kinetics and Simulation Including Mass-Transfer Processes of Direct H2O2 Synthesis from H2 and O2 over Pd/C Catalyst in Water Containing H+ and Br-Ions2011

    • Author(s)
      T.Deguchi
    • Journal Title

      Ind.Eng.Chem.Res

      Volume: 50 Issue: 8 Pages: 4351-4358

    • DOI

      10.1021/ie102074z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast and Quantitative Dehydration of Lower Alcohols to Corresponding Olefins on Mesoporous Silica Catalyst2011

    • Author(s)
      T.Haishi
    • Journal Title

      Chem.Lett.

      Volume: 40 Pages: 614-616

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia synthesis over rhenium supported on mesoporous silica MCM-412011

    • Author(s)
      F.Hayashi
    • Journal Title

      Micro.Meso.Mater.

      Volume: 146 Issue: 1-3 Pages: 184-189

    • DOI

      10.1016/j.micromeso.2011.03.035

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction mechanism of direct H2O2 synthesis from H2 and O2 over Pd/C catalyst in water with H+ and Br-ions2011

    • Author(s)
      T.Deguchi
    • Journal Title

      J.Catal.

      Volume: 280 Issue: 2 Pages: 239-246

    • DOI

      10.1016/j.jcat.2011.03.019

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Roles of Entropy in Supramolecular Photochirogenesis : Enantiodifferentiating Photoisomerization of Cyclooctenes in Chiral Sensitizer-Immobilized MCM-41 Cavities2011

    • Author(s)
      R.Maeda, T.Wada, A.Kusaka, T.Mori, M.Iwamoto, Y.Inoue
    • Journal Title

      Photochemical and Photobiological Sciences

      Volume: 10 Issue: 9 Pages: 1390-1392

    • DOI

      10.1039/c1pp05087g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction pathways of glucose and fructose on Pt nanoparticles in subcritical water under a hydrogen atmosphere2011

    • Author(s)
      Y.Kanie
    • Journal Title

      Catal.Today

      Volume: 178 Issue: 1 Pages: 58-63

    • DOI

      10.1016/j.cattod.2011.07.031

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast and Almost Complete Nitridation of Mesoporous Silica with Ammonia in a Plug-Flow Reactor2010

    • Author(s)
      F.Hayashi, K.Ishizu, M.Iwamoto
    • Journal Title

      J.Amer.Ceram.Soc

      Volume: 93 Pages: 104-110

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Biginelli dihydropyrimidinone derivatives with various Substituents on aluminum-planted mesoporous silica catalyst2010

    • Author(s)
      H.Murata, H.Ishitani, M.Iwamoto
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 8 Pages: 1202-1211

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect Pore Structure on the Nitridation of Mesoporous Silica with Ammonia2010

    • Author(s)
      F.Hayashi, K.Ishizu, M.Iwamoto
    • Journal Title

      Eur.J.Inorg.Chem

      Volume: 15 Pages: 2235-2243

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Almost Complete Nitridation of Mesoporous Silica to Mesoporous Silicon (Oxy)Nitiride with Ammonia2010

    • Author(s)
      F.Hayashi, M.Iwamoto
    • Journal Title

      Adv.Sci.Tech

      Volume: 68 Pages: 159-164

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly ordered aluminum-planted mesoporous silica as active catalyst for Biginelli reaction and formyl C-H insertion reaction with diazo ester2010

    • Author(s)
      H.Murata, H.Ishitani, M.Iwamoto
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 12 Pages: 14452-14455

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Potential for Fixation of N2 at Room Temperature Utilizing a Copper-Ion-Exchanged MFI-Type Zeolite As an Adsorbent : Evaluation of the Bond Dissociation Energy of Adsorbed N≡N and the Bond Strength of the Cu+-N(≡N) Species2010

    • Author(s)
      Atsushi Itadani, Masashi Tanaka, Toshinori Mori, Hiroe Torigoe, Hisayoshi Kobayashi, Yasushige Kuroda
    • Journal Title

      J.Phys.Chem.Lett.

      Volume: 1 Pages: 2385-2390

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ナノ空間触媒化学2010

    • Author(s)
      岩本正和
    • Journal Title

      化学経済

      Volume: 57(3) Pages: 24-27

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 次世代型バイオリファイナリーの提案2010

    • Author(s)
      岩本正和
    • Journal Title

      化学経済

      Volume: 57(6) Pages: 42-48

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ナノ多孔体の新しい機能を求めて2010

    • Author(s)
      岩本正和
    • Journal Title

      ペトロテック

      Volume: 33(8) Pages: 613-617

    • NAID

      10027627496

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 今だからこそ2010

    • Author(s)
      岩本正和
    • Journal Title

      ペトロテック

      Volume: 35(11) Pages: 831-831

    • NAID

      10027974844

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric S-O Bond Formation by Oxidation

    • Author(s)
      H.Ishitani, M.Iwamoto
    • Journal Title

      Elsevier

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and Simulation Including Mass-Transfer Processes of Direct H2 O2 Synthesis from H2 and O2 over Pd/C Catalyst in Water Containing H+ and Br- Ions

    • Author(s)
      T. Deguchi, M.Iwamoto
    • Journal Title

      Ind.Eng.Chem.Res

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction mechanism of direct H2O2 synthesis from H2 and O2 over Pd/C catalyst in water with H+ and Br- ions

    • Author(s)
      T.Deguchi, M.Iwamoto
    • Journal Title

      J.Catal.

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia Synthesis over Rhenium Supported on Mesoporous Silica MCM-41

    • Author(s)
      F.Hayashi, M.Iwamoto
    • Journal Title

      Micro.Meso.Mater.

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Roles of Entropy in Supramolecular Photochirogenesis : Enantiodifferentiating Photoisomerization of Cyclooctenes in Chiral Sensitizer-Immobilized MCM-41 Cavity

    • Author(s)
      R.Maeda, T.Wada, A.Kusaka, T.Mori, M.Iwamoto, Y.Inoue
    • Journal Title

      Photochem.Photobiol.Sci.

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast and Quantitative Dehydration of Lower Alcohols to Corresponding Olefins on Mesoporous Silica Catalyst

    • Author(s)
      T.Hishi, K Kasai, M.Iwamoto
    • Journal Title

      Chem.Lett.

      Volume: (in press)

    • NAID

      10028243974

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] In2O3触媒上でのエタノールのプロピレンへの選択的変換2012

    • Author(s)
      田中大士
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 銅担持シリカメゾ多孔体上を触媒とするジアゾエステルの不斉インドールC-H結合挿入反応2012

    • Author(s)
      陳ドゥ
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Cu-MCM-41による配位子・Pdフリーな薗頭カップリング反応2012

    • Author(s)
      鈴木達也
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属水酸化物および酸化物による杉の水熱分解反応2012

    • Author(s)
      森田純平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 亜臨界水中での杉の接触水素化分解2012

    • Author(s)
      橋爪大輔
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Pt/MCM-41触媒上でのNO選択還元反応に対するNbの添加効果2012

    • Author(s)
      小松原優
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 壁イオン交換法により調製したW-Zr複合酸化物ナノ多孔体の酸触媒特性2012

    • Author(s)
      壁谷宏平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Cu担持MCM-41触媒上での不斉シクロプロパン化を利用したβ-シロキシシクロプロパンカルボン酸エステルの合成2012

    • Author(s)
      加藤弘基
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高純度シリカから調製したMCM-41によるカルボニルEne反応2012

    • Author(s)
      杉内拓実
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 壁イオン交換法により調製したメソポーラスCr-Ti複合酸化物中のクロム種の存在状態の検討2012

    • Author(s)
      徐寅碩
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 直接過酸化水素合成におけるパラジウム触媒への微量貴金属添加効果2012

    • Author(s)
      山野仁詩
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] バイオマス資源活用の現状と今後2012

    • Author(s)
      岩本正和
    • Organizer
      東洋紡PPS特別セミナー
    • Place of Presentation
      日本橋社会教育会館(東京都)(招待講演)
    • Year and Date
      2012-02-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 触媒の力でサトウキビやトウモロコシをバイオプラスチックに変える2012

    • Author(s)
      岩本正和
    • Organizer
      東京工業大学公開講演会-東工大の最先端研究
    • Place of Presentation
      東京工業大学田町キャンパス(東京都)(招待講演)
    • Year and Date
      2012-01-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] One-step Conversion of Bio- Ethanol to Propene on Ni-ion Loaded Mesoporous Silica and Sc-Modified In2O3 Catalysts2012

    • Author(s)
      M. Iwamoto, S. Mizuno, M. Kurosawa, M. Tanaka
    • Organizer
      International Conference on Emerging Advanced Nanomaterials–2012
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] エタノールからのプロピレン製造2011

    • Author(s)
      岩本正和
    • Organizer
      石油学会触媒シンポジウム
    • Place of Presentation
      工学院大学(東京都)(招待講演)
    • Year and Date
      2011-12-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Selective Carbon-Carbon Bond Forming Reactions on Copper-Planted Mesoporous Silica Catalyst2011

    • Author(s)
      H.Ishitani
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2011
    • Place of Presentation
      Nara Prefectural new Public Hall(奈良県)(招待講演)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] A Computational Study of Ethylene to Propylene Conversion on Nickel Ion-Loaded Silica2011

    • Author(s)
      A.Shiga
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2011
    • Place of Presentation
      Nara Prefectural new Public Hall(奈良県)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Copper-Planted Mesoporous Silica as A More Active Catalyst than Homogeneous ones for Asymmetric C-H Bond Insertion Reaction of Indole with Diazo Ester2011

    • Author(s)
      D.Chen
    • Organizer
      3rd Asia-Oceania Conference on Green & Sustainable Chemistry
    • Place of Presentation
      Melbourne Convention And Exhibition Centre (Australia)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Carbon-Carbon Bond Forming Reactions Using Very Weak Acidic Property of Mesoporous Silica MCM-412011

    • Author(s)
      T.Sugiuchi
    • Organizer
      3rd Asia-Oceania Conference on Green & Sustainable Chemistry
    • Place of Presentation
      Melbourne Convention And Exhibition Centre (Australia)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] 亜臨界水中での杉の接触水素化分解2011

    • Author(s)
      橋爪大輔
    • Organizer
      石油学会山口大会(第41回石油・石油化学討論会)
    • Place of Presentation
      山口県教育会館(山口県)
    • Year and Date
      2011-11-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 銅担持シリカメゾ多孔体上での不斉シクロプロパン化反応-含有A1イオンが活性種形成に与える効果-2011

    • Author(s)
      石谷暖郎
    • Organizer
      石油学会山口大会(第41回石油・石油化学討論会)
    • Place of Presentation
      山口県教育会館(山口県)
    • Year and Date
      2011-11-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属水酸化物および酸化物による杉の水熱分解反応2011

    • Author(s)
      森田純平
    • Organizer
      石油学会山口大会(第41回石油・石油化学討論会)
    • Place of Presentation
      山口県教育会館(山口県)
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] 壁イオン交換法によるW-Zr複合酸化物ナノ多孔体の調製とその酸触媒特性2011

    • Author(s)
      壁谷宏平
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 銅担持シリカメゾ多孔体上を触媒とするジアゾエステルの不斉インドールC-H結合挿入反応2011

    • Author(s)
      陳ドゥ
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Cu-MCM-41による配位子・パラジウムフリーな薗頭カップリング反応2011

    • Author(s)
      鈴木達也
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] ヘテロDiels-Alder反応活性に対するシリカメゾ多孔体の触媒作用2011

    • Author(s)
      杉内拓実
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Nb添加Pt/MCM-41上での水素によるNO選択還元2011

    • Author(s)
      小松原優
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] In2O3触媒によるエタノールのプロピレンへの選択的転換2011

    • Author(s)
      水野翔太
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 酸化インジウム結晶表面上でのエタノールからプロピレンの生成に関する計算化学的研究2011

    • Author(s)
      志賀昭信
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 直接H2O2合成におけるパラジウム触媒のイオウ被毒の影響2011

    • Author(s)
      出口隆
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] パラジウム触媒上でのH2O2直接合成反応に対する担体の効果2011

    • Author(s)
      山野仁詩
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Kinetics of H2O2 synthesis on Pd- and Pt-PVP colloidal catalysts and unusual addition effect of Pt on Pd-PVP2011

    • Author(s)
      H.Yamano
    • Organizer
      EuropaCat X
    • Place of Presentation
      University of Glasgow (Scotland)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Selectivie Conversion Of Ethanol to propene On In2O3 Based Catalysts2011

    • Author(s)
      S.Mizuno
    • Organizer
      EuropaCat X
    • Place of Presentation
      University of Glasgow (Scotland)
    • Year and Date
      2011-08-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Collection of Phosphate Ion in Water and Its Recovery through Wall-Ion Exchange of Zirconium Sulfate-Surfactant Mesostructured Materials2011

    • Author(s)
      M.Tanaka
    • Organizer
      Nanoporous Materials VI
    • Place of Presentation
      Banff Park Lodge (Canada)
    • Year and Date
      2011-08-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Preparation of Mesoporous W-Zr Mixed Oxides through Wall-Ion Exchange and Their Catalytic Activities for Friedel-Crafts Alkylation2011

    • Author(s)
      K.Kabeya
    • Organizer
      Nanoporous Materials VI
    • Place of Presentation
      Banff Park Lodge (Canada)
    • Year and Date
      2011-08-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] Enhancement of Catalytic Activity of Pt/MCM-41 with Addition of Nb or Ce for Selective Catalytic Reduction of NO with Hydrogen2011

    • Author(s)
      M.Komatsubara
    • Organizer
      Nanoporous Materials VI
    • Place of Presentation
      Banff Park Lodge (Canada)
    • Year and Date
      2011-08-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] エチレン/プロピレン転換からバイオマスリファイナリーへ2011

    • Author(s)
      岩本正和
    • Organizer
      第11回グリーンサステイナブルケミストリシンポジウム
    • Place of Presentation
      早稲田大学国際会議場(東京都)(招待講演)
    • Year and Date
      2011-06-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] バイオマスリファイナリーの全触媒化を目指して2011

    • Author(s)
      岩本正和
    • Organizer
      高分子同友会総合講演会
    • Place of Presentation
      総評会館(東京都)(招待講演)
    • Year and Date
      2011-04-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] Efficient dissolving of Japanese cedar into water by treatment with alkali metal hydroxides at 493 K2011

    • Author(s)
      J.Morita
    • Organizer
      The 13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Seogwipo KAL Hotel (Korea)
    • Year and Date
      2011-04-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] MCM-41調製時に導入したアルミニウムによる銅イオン担持状態の制御2011

    • Author(s)
      用瀬英順, 竹中久美, 田中大士, 石谷暖郎, 岩本正和
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] シリカメゾ多孔体のAlイオン量および細孔構造がヘテロDiels-Alder反応活性に与える効果2011

    • Author(s)
      杉内拓実, 石谷暖郎, 岩本正和
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 貴金属ナノ上コロイド触媒によるキシランおよびセルロースの水素化2011

    • Author(s)
      逢坂有里子、秋山勝宏、岩本正和
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Catalytic Conversion of (bio-)Ethanol into Ingredients of Polyolefins and Its Reaction Pathways2011

    • Author(s)
      M.Iwamoto
    • Organizer
      JSPS-NTU Joint Seminar 2011
    • Place of Presentation
      Singapore(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Correlation among copper ion states in MCM-41, preparation methods, and catalytic activity for cyclopropanation reaction2010

    • Author(s)
      M.Tanaka, K.Takenaka,H.Ishitani, M.Iwamoto
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      アメリカ・ハワイ
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Heterogeneous enantioselective cyclopropanation on Cu-MCM-41 with C2- or C1-symmetric chiral modifiers2010

    • Author(s)
      H.Ishitani, H.Oosawa M.Iwamoto
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      アメリカ・ハワイ
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement of Al-planted mesoporous silica catalyst active for Biginelli reaction2010

    • Author(s)
      H.Murata, H.Ishitani, M.Iwamoto
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      アメリカ・ハワイ
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] シリカナノ多孔体の新しい機能を求めて2010

    • Author(s)
      岩本正和
    • Organizer
      日本技術士会講演会
    • Place of Presentation
      日本技術士会(港区)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Novel Porous Titanium-Chromium Mixed Oxides through the Wall Ion Exchange Method2010

    • Author(s)
      I.Suh, M.Tanaka, M.Iwamoto
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      アメリカ・ハワイ
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高規則性Al担持シリカメゾ多孔体の調製とその酸触媒能2010

    • Author(s)
      村田宏朗, 石谷暖郎, 岩本正和
    • Organizer
      石油学会 第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場(神戸市)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジルコニウム系メゾ構造体による水中リン酸イオンの捕集およびその放出2010

    • Author(s)
      徐磊, 高田仁, 田中大士, 岩本正和
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場(神戸市)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] ナノ多孔体の新しい機能を求めて2010

    • Author(s)
      岩本正和
    • Organizer
      有機合成化学協会講演会
    • Place of Presentation
      日本薬学会長井記念ホール(渋谷区)
    • Year and Date
      2010-11-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] バイオマスリファイナリーの全触媒化を目指して2010

    • Author(s)
      岩本正和
    • Organizer
      高分子学会同友会研究会
    • Place of Presentation
      高分子学会本部事務局(中央区)
    • Year and Date
      2010-10-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジルコニウム-硫酸イオンメゾ構造体の壁イオン交換によるリン酸イオンの捕集2010

    • Author(s)
      徐磊, 高田仁, 田中大士, 岩本正和
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      ベルクラシック甲府・山梨大学(甲府)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] シリカメゾ多孔体に担持した銅イオンの状態と不斉シクロプロパン化活性の関連2010

    • Author(s)
      田中大士, 竹中久実, 石谷暖郎, 岩本正和
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      ベルクラシック甲府・山梨大学(甲府)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Hydrothermal Reactions of Glucose on Pt-nanoparticle Catalysts under Hydrogen Atmosphere2010

    • Author(s)
      Y.Kanie, K.Akiyama, M.Iwamoto
    • Organizer
      The 25th International Carbohydrate Symposium (ICS2010)
    • Place of Presentation
      幕張メッセ(千葉市)
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Copper-planted mesoporous silica modified with chiral organic molecule as a catalyst for heterogeneous enantioselective cyclopropanation2010

    • Author(s)
      H.Ishitani, H.Oosawa M.Iwamoto
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2010-07-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of highly ordered aluminum-planted mesoporous silica catalyst active for Biginelli reaction2010

    • Author(s)
      H.Murata, H.Ishitani, M.Iwamoto
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2010-07-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Novel Porous Titanium-Chromium Mixed Oxides through the Wall Ion Exchange Method2010

    • Author(s)
      I.Suh, M.Tanaka, M.Iwamoto
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2010-07-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Metal-catalyzed Hydrogenolysis of Cellulose to Alcohols and Diols2010

    • Author(s)
      Y.Ikeda, K.Akiyama, M.Iwamoto
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 固体触媒化学からバイオリファイナリーへ-発想と挑戦-2010

    • Author(s)
      岩本正和
    • Organizer
      松籟科学技術振興財団講演会
    • Place of Presentation
      ハリマ化成加古川製造所(加古川市)
    • Year and Date
      2010-07-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅担持シリカメゾ多孔体上でのジアゾエステルによる芳香族化合物へのC-H結合挿入反応2010

    • Author(s)
      石谷暖郎, 佐藤大輔, 岩本正和
    • Organizer
      石油学会第59回研究発表会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2010-05-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nb添加によるPt/MCM-41のNO選択還元活性の向上2010

    • Author(s)
      八木下将史, 古賀晃子, 田中大士, 岩本正和
    • Organizer
      石油学会第59回研究発表会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2010-05-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] セルロースの触媒的水素化分解によるアルコール・ジオールへの直接変換2010

    • Author(s)
      池田陽一、秋山勝宏、岩本正和
    • Organizer
      石油学会第59回研究発表会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2010-05-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 白金ナノコロイドを触媒とするグルコースとフルクトースの水素化分解2010

    • Author(s)
      蟹江善美、秋山勝宏、岩本正和
    • Organizer
      石油学会第59回研究発表会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2010-05-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] ナノ多孔体の新しい機能を求めて2010

    • Author(s)
      岩本正和
    • Organizer
      石油学会第53回年会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2010-05-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] One-step and Selective Conversion of Bio-ethanol to Propene on Scandium-Loaded In2O3 Catalysts

    • Author(s)
      M. Iwamoto, S. Mizuno, M. Tanaka
    • Organizer
      The 14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      Nagoya
    • Related Report
      2012 Annual Research Report
  • [Presentation] Mesoporous Tungsten-Zirconium Composite Oxides-Preparation with a Wall Ion-Exchange Method and Activity for Acidic Catalysis

    • Author(s)
      M. Tanaka, K.kabeya, I. Suh, H. Ishitani, M. Iwamoto
    • Organizer
      17th International Zeolite Conference
    • Place of Presentation
      Moscow, Russia
    • Related Report
      2012 Annual Research Report
  • [Presentation] Selective Production of Propene from Bio-Ethanol on Scandium-Loaded Indium Oxide Catalysts and Its Raction Mechanism

    • Author(s)
      M. Iwamoto, M. Tanaka, S. Mizuno, S. Hirakawa
    • Organizer
      The 6th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Catalytic Castro-Stephens Coupling on Cu-planted Mesoporous Silica

    • Author(s)
      H. Ishitani, T. Suzuki, M. Iwamoto
    • Organizer
      Catalysis & Fine Chemicals Pre-symposium
    • Place of Presentation
      Himeji
    • Related Report
      2012 Annual Research Report
  • [Presentation] Novel Strategies for Propene Production from Natural Gases or Bio-ethanol

    • Author(s)
      M. Iwamoto
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials、Matsuyama
    • Place of Presentation
      Ehime
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 一酸化窒素除去における銅イオン交換ゼオライト触媒の過去、現在、未来

    • Author(s)
      岩本正和
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 過酸化水素の直接合成におけるAu-Pt相乗効果

    • Author(s)
      竹之内翔、山野仁詩、出口隆、岩本正和
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] Sc/In2O3触媒上でのエタノールからプロピレン生成経路-パルス法による検討-

    • Author(s)
      平川翔太、水野翔太、田中大士、岩本正和
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅担持MCM-41を用いる高効率不均一系C-Hアリール化反応

    • Author(s)
      臼井隆、石谷暖郎、岩本正和
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高純度シリカメゾ多孔体の細孔径および細孔形状が酸触媒特性に与える効果

    • Author(s)
      熊谷和人、杉内拓実、石谷暖郎、岩本正和
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Annual Research Report
  • [Presentation] エタノール‐プロピレン反応に高い活性を示す酸化インジウム触媒の調製

    • Author(s)
      村上麻希、田中大士、岩本正和
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] 過熱水蒸気法によるセルロースのレボグルコサンへの選択的転換

    • Author(s)
      島袋亜沙美、玉城志博、岩本正和
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ptの水素活性化能を活かしたH2O2直接合成触媒 (1) -水溶液中に添加した成分の効果-

    • Author(s)
      竹之内翔、出口隆、岩本正和
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ptの水素活性化能を活かしたH2O2直接合成触媒 (2) Pd-、Au-、およびAg-PVP触媒に対するPt添加効果のDFT計算

    • Author(s)
      出口隆、竹之内翔、岩本正和
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Presentation] キュービック細孔を持つ高純度シリカメゾ多孔体が示す特異な酸触媒特性

    • Author(s)
      熊谷和人、杉内拓実、石谷暖郎、岩本正和
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Annual Research Report
  • [Book] Handbook of Mesoporous Materials2014

    • Author(s)
      Masakazu Iwamoto, Masashi. Tanaka
    • Total Pages
      34
    • Publisher
      NOVA press
    • Related Report
      2012 Annual Research Report
  • [Book] 触媒技術の動向と展望20132013

    • Author(s)
      水野翔太、黒沢美佳、田中大士、岩本正和
    • Total Pages
      2
    • Publisher
      触媒学会
    • Related Report
      2012 Annual Research Report
  • [Book] Comprehensive Chirality (Asymmetric S.O Bond Formation by Oxidation)(Ed.by H.Yamamoto)2012

    • Author(s)
      H.Ishitani, M.Iwamoto
    • Publisher
      Elsevier(in press)
    • Related Report
      2011 Annual Research Report
  • [Book] 「革新的な多孔質材料」第14章「ナノ空間の特性を活かした新しい触媒化学」2010

    • Author(s)
      岩本正和
    • Publisher
      化学同人
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.chuo-u.ac.jp/~iwamotolab/index.html

    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 国際出願2013

    • Inventor(s)
      岩本正和
    • Industrial Property Rights Holder
      岩本正和
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-26
    • Related Report
      2012 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 国内出願2013

    • Inventor(s)
      岩本正和、村上麻希
    • Industrial Property Rights Holder
      岩本正和、村上麻希
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-116304
    • Filing Date
      2013-05-31
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] オレフィンの製造方法およびオレフィ ン製造用触媒2012

    • Inventor(s)
      岩本正和,大橋 洋,柿沼卓宏
    • Industrial Property Rights Holder
      東京工業大学,出光興産株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-115088
    • Filing Date
      2012-05-18
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 炭素数3以上の含酸素化合物の製造方法2011

    • Inventor(s)
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Rights Holder
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Number
      2011-108832
    • Filing Date
      2011-05-13
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] プロピレンの製造方法2011

    • Inventor(s)
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Rights Holder
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Number
      2011-108830
    • Filing Date
      2011-05-13
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] プロピレンの製造方法2011

    • Inventor(s)
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Rights Holder
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Number
      2011-108836
    • Filing Date
      2011-05-13
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] オレフィン製造用触媒及びオレフィンの製造方法2011

    • Inventor(s)
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Rights Holder
      岩本正和、柿沼卓宏、大橋洋
    • Industrial Property Number
      2011-114217
    • Filing Date
      2011-05-20
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] オレフィンの製造方法及びオレフィン製造用触媒2011

    • Inventor(s)
      岩本正和、水野翔太、柿沼卓宏、大橋洋
    • Industrial Property Rights Holder
      岩本正和、水野翔太、柿沼卓宏、大橋洋
    • Industrial Property Number
      2011-114218
    • Filing Date
      2011-05-20
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] オレフィン製造触媒およびオレフィンの製造方法2010

    • Inventor(s)
      岩本正和、大橋洋
    • Industrial Property Rights Holder
      岩本正和、大橋洋
    • Industrial Property Number
      2010-156951
    • Filing Date
      2010-07-09
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] プロピレン製造用触媒およびプロピレンの製造方法2010

    • Inventor(s)
      岩本正和、鈴木哲生
    • Industrial Property Rights Holder
      岩本正和、鈴木哲生
    • Industrial Property Number
      2010-273649
    • Filing Date
      2010-12-08
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] オレフィン製造用触媒およびオレフィンの製造方法2010

    • Inventor(s)
      岩本正和、鈴木哲生、大橋洋、柿沼卓宏
    • Industrial Property Rights Holder
      岩本正和、鈴木哲生、大橋洋、柿沼卓宏
    • Industrial Property Number
      2010-273663
    • Filing Date
      2010-12-08
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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