Development of water-soluble super lubrication system using hyperbranced polymer

• Project/Area Number: 22350096
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Hokkaido University
• Principal Investigator: SATOH Toshifumi 北海道大学, 大学院・工学研究院, 教授 (80291235)
• Co-Investigator(Kenkyū-buntansha): KAKUCHI Toyoji 北海道大学, 大学院・工学研究院, 教授 (80113538) ; 堺井 亮介 旭川工業高等専門学校, 物質化学工学科, 准教授 (90507196)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000); Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2011: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2010: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
• Keywords: 高分子材料物性 / 化学物理 / 環境材料 / 高分子合成 / 高分子構造・物性 / ナノ材料

Research Abstract

In this study, in order to develop novel water-soluble super lubrication system, new water-soluble branched polymers such as hyperbranced polymerｓ were synthesized, and the relationship between polymer structure and viscosity was discussed. The obtained polymers in water showed very lowviscosity, therefore, the solution was useful as water-soluble lubricant agent. The lubrication property is due to the globular structure of the polymer in water.

Research Products

• [Journal Article] Synthesis of miktoarm star copolymer Ru(II) complexes by click-to-chelate approach (2013)
  • Author(s): Xiao, N., Chen, Y., Shen, X., Zhang, C., Yano, S. Gottschaldt, M., Schubert, U. S., Kakuchi, T., Satoh, T
  • Journal Title: Polym. J Volume: 45 (2) Issue: 2 Pages: 216-225
  • DOI: 10.1038/pj.2012.100
  • NAID: 10031155025
  • Peer Reviewed
• [Journal Article] Synthesis of hyperbranched polymer using slow monomer addition method (2012)
  • Author(s): Satoh, T
  • Journal Title: Int.J. Polym. Sci Volume: 816163 Pages: 8-8
  • DOI: 10.1155/2012/816163
  • Peer Reviewed
• [Journal Article] Synthesis of Syndiotactic-Rich Star-Shaped Poly(methyl methacrylate) by Core-First Group Transfer Polymerization Using N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide (2012)
  • Author(s): 陳友根
  • Journal Title: J. Polym. Sci., Part A : Polym. Chem. Volume: 50 Issue: 16 Pages: 3277-3285
  • DOI: 10.1002/pola.26123
  • Peer Reviewed
• [Journal Article] Precise Synthesis of Clickable Poly(n-hexyl isocyanate) (2012)
  • Author(s): Satoh, T., Ihara, R., Kawato, D.,Nishikawa, N., Suemasa, D., Kondo,Y., Fuchise, K., Sakai, R., Kakuchi,T
  • Journal Title: Macromolecules Volume: 45(9) Issue: 9 Pages: 3677-3686
  • DOI: 10.1021/ma300555v
  • Peer Reviewed
• [Journal Article] Selective synthesis of 1,6- anhydro-β-D-mannopyranose and-mannofuranose using microwave-assisted heating (2011)
  • Author(s): Hoai, N. T., Sasaki, A., Sasaki, M., Kaga, H., Kakuchi, T., Satoh, T
  • Journal Title: Carbohydr. Res Volume: 346 (13) Issue: 5 Pages: 1747-1751
  • DOI: 10.1021/bm2002413
  • Peer Reviewed
• [Journal Article] Synthesis of Novel Hyperbranched Polymer Through Cationic Ring-Opening Multibranching Polymerization of 2-Hydroxymethyloxetane (2011)
  • Author(s): Hideki Misaka
  • Journal Title: Journal of Folymer Science Part A : Polymer Chemistry Volume: 49 Issue: 11 Pages: 2353-2365
  • DOI: 10.1002/pola.24664
  • Peer Reviewed
• [Journal Article] A hydrophilic unimolecular nanocapsule with cyclodextrin moieties in the core: chemically triggered on-demand release and pH-response (2011)
  • Author(s): Wan, D., Ohta, S., Kakuchi, T., Satoh, T
  • Journal Title: Soft Matter Volume: 7(14) Issue: 14 Pages: 6422-6425
  • DOI: 10.1039/c1sm05640a
  • Peer Reviewed
• [Journal Article] Synthesis, characterization, and lectin recognition of hyperbranched poly saccharide obtained from 1,6-anhydro-D-hexofuranose (2011)
  • Author(s): Hoai N.H., Sasaki A., Sasaki M., Kaga H., Kakuchi T., Satoh T.
  • Journal Title: Biomacromolecules, dx.doi.org/10.1021/bm2002413. Volume: in press
  • Peer Reviewed
• [Journal Article] Synthesis of Novel Hyperbranched Polymer through Cationic Ring-opening Multibranching Polymerization of 2-Hydroxymethyloxetane (2011)
  • Author(s): Satoh T., Tamaki M., Taguchi T., Misaka H., Hoai N.T., Sakai R., Kakuchi T.
  • Journal Title: Journal of Polymer Science, Part A : Polymer Chemistry, DOI:10.1002/pola.24664 Volume: in press
  • Peer Reviewed
• [Presentation] Synthesis and Characteristic of Hyperbranched Carbohydrate Polymer (2012)
  • Author(s): Satoh, T
  • Organizer: 17th Malaysian Chemical Congress (17MCC) 2012
  • Place of Presentation: Putra World Trade Center (Malaysia)
  • Year and Date: 2012-10-16
• [Presentation] 1,6-アンヒドロヘキソースから得られたハイパーブランチ多糖の構造とレクチン認識能 (2011)
  • Author(s): 佐藤敏文、覚知豊次
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学,岡山
  • Year and Date: 2011-09-28
• [Presentation] 1,6-アンヒドロヘキソースから得られたハイパーブランチ多糖の構造とレクチン認識能 (2011)
  • Author(s): 佐藤敏文、覚知豊次
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学(岡山市)(招待講演)
  • Year and Date: 2011-09-28
• [Presentation] ハイパーブランチポリ(2-ヒドロキシメチル環状エーテル)の合成と特性 (2010)
  • Author(s): 佐藤敏文・田巻匡貴・田口圭・加我晴生・堺井亮介・覚知豊次
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学,札幌
  • Year and Date: 2010-09-15
• [Presentation] ハイパーブランチポリ(2-ヒドロキシメチル環状エーテル)の合成と特性 (2010)
  • Author(s): 佐藤敏文・田巻匡貴・田口圭・加我晴生・堺井亮介・覚知豊次
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学、札幌
  • Year and Date: 2010-09-15
• [Presentation] Synthesis and Characteristic of Hyperbranched Carbohydrate Polymer
  • Author(s): Toshifumi Satoh
  • Organizer: 17th Malaysian Chemical Congress (17MCC) 2012
  • Place of Presentation: Putra World Trade Center (Malaysia)
• [Book] Tunable Encapsulation Property of Amphiphilic Polymer Based on Hyperbranched Polyethylenimine (2013)
  • Author(s): Wan, D., Satoh, T
  • Publisher: Encapsulation Technologies, Scrivener Publishing LLC(in press)
• [Book] Tunable Encapsulation Property of Amphiphilic Polymer Based on Hyperbranched Polyethylenimine/chap 8, Encapsulation Technologies (2013)
  • Author(s): Decheng Wan, Toshifumi Satoh
  • Publisher: Scrivener Publishing LLC
• [Book] Hyperbranched Glyco-Conjugated Polymers in "Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly (2012)
  • Author(s): Satoh, T., Kakuchi, T
  • Publisher: Wiley
• [Book] Hyperbranched Glyco-Conjugated Polymers in "Complex Macromolecular Architectures : Synthesis, Characterization, and Self-Assembly" (2011)
  • Author(s): Satoh T., Kakuchi T.
  • Publisher: Wiley