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Thin film preparation and its extension to photofunctional devices of low-density organic polymer with transparency

Research Project

Project/Area Number 22350099
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

NAGAI Keiji  東京工業大学, 資源化学研究所, 准教授 (30280803)

Co-Investigator(Renkei-kenkyūsha) IYODA Tomokazu  東京工業大学, フロンティア研究機構, 教授 (90168534)
HADANO Shingo  高知大学, 理学部, 助教 (70397157)
ABE Toshiyuki  弘前大学, 大学院・理工学研究科, 准教授 (20312481)
NORIMATSU Takayoshi  大阪大学, レーザーエネルギー学研究センター, 教授 (50135753)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2011: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2010: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Keywords高分子機能材料 / エアロゲル / フェノール樹脂 / 有機半導体 / 光触媒 / 低密度材料 / ゲル / 透明 / センサー
Research Abstract

Low density plastic materials have long history and reaches to transparency based on its small pore size less than wavelength of light. In comparison to inorganic aeregel, organic one has small example numbers. In the present project, the size of pore has been minimized to 10 nm. The control of the pore size was investigated from the view point of the gelation to form precursor.As for the photo functionalization, visible light responsive photoctalyst was incorporated to the aerogel. The evaluation of the photocatalysis was done for the oxidation of aldehyde, amine, thiol, and amide, to carbondioxide.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (47 results)

All 2013 2012 2011 2010 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (26 results) (of which Invited: 2 results) Book (2 results) Remarks (2 results)

  • [Journal Article] 有機太陽電池の活 性層を用いた全可視光応答光触媒-汚濁物質分解・水分解へむけて?"(Full-spectrum-visible-light photocatalyst based on the active layer of an organic solar cell-towards water splitting and volatile molecule degradation-)2013

    • Author(s)
      長井圭治,阿部敏之
    • Journal Title

      高分子論文集KOBUNSHI RONBUNSHU Japanese Journal of Polymer Science and Technology

      Volume: (in press) Pages: 70-70

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrode Characteristics of Partially Hydrolyzed Aluminum Phthalocyanine Chloride/Fullerene C60 Composite Nanoparticles Working in a Water Phase2012

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      Molecules

      Volume: 17(9) Pages: 10801-10815

    • NAID

      120006559343

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Decomposition ofN-methyl-2-pyrrolidone, Aldehydes, and Thiol by Biphase and p/n Junction-like Organic Semiconductor Composite Nanoparticles Responsive to Full Spectrum of Visible Light2012

    • Author(s)
      Shuai Zhang, Prabhakarn Arunachalam, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      J. Photochem. Photobiol. Part A Photochem

      Volume: 244 Pages: 18-23

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of Biphasic Vanadyl phthalocyanine and C60 composite nanoparticles through a reprecipitation process2012

    • Author(s)
      Arunachalam Prabhakarn, Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 37[2] Pages: 205-208

    • NAID

      130003399084

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Site-Selective Self-Assembly of Fullerene Nanoparticles on Amphiphilic Block Copolymer Thin Film from Water Suspension2012

    • Author(s)
      Tianyu Yang, Shuai Zhang, Motonori Komura, Tomokazu Iyoda, and Keiji Nagai
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51 Issue: 7R Pages: 70201-70201

    • DOI

      10.1143/jjap.51.070201

    • NAID

      210000140840

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Decomposition of N-methyl-2-pyrrolidone, Aldehydes, and Thiol by Biphase and p/n Junction-like Organic Semiconductor Composite Nanoparticles Responsive to Nearly Full Spectrum of Visible Light2012

    • Author(s)
      Shuai Zhang, Prabhakarn Arunachalam, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai
    • Journal Title

      J. Photochem. Photobiol. A: Chem

      Volume: 244 Pages: 18-23

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of Biphasic Vanadyl phthalocyanine and C60 composite nanoparticles through a reprecipitation process2012

    • Author(s)
      Arunachalam Prabhakarn, Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai
    • Journal Title

      Trans. Mat. Res. Soc. Japan

      Volume: 37 Pages: 205-208

    • NAID

      130003399084

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrode Characteristics of Partially Hydrolyzed Aluminum Phthalocyanine Chloride/Fullerene C60 Composite Nanoparticles Working in a Water Phase2012

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai
    • Journal Title

      Molecules

      Volume: 17 Issue: 9 Pages: 10801-10815

    • DOI

      10.3390/molecules170910801

    • NAID

      120006559343

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Semiconductor Nanoparticles with Heterojunctions Composed of Fullerene C60 and Zinc Phthalocyanine and Their Application to Visible-Light-Responsive Photocatalysts2011

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, Takayoshi Norimatsu, and Keiji Nagai*
    • Journal Title

      Transactions of the Materials ResearchSociety of Japan

      Volume: 36[2] Pages: 177-181

    • NAID

      130005004122

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Nd:YAG Laser Energy on Multilayer Hollow Nanofiber Target's Extreme Ultraviolet Conversion Efficiency2011

    • Author(s)
      Liqin Ge*, Jianyu Ji, Lingling Bai, Teng Fei, Weichen Wang, Keiji Nagai, Hiroaki Nishimura, Yasukazu Izawa, Kunioki Mima& Takayoshi Norimatsu
    • Journal Title

      J. Macromol. Sci. Part B Phys.

      Volume: 50(9) Pages: 1761-1770

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrochemical and Photocatalytic Properties of Biphasic Organic p- and n-Type Semiconductor Nanoparticles Fabricated by a Reprecipitation Process2011

    • Author(s)
      Shuai Zhang, Ryohei Sakai, Toshiyuki Abe, Tomokazu Iyoda,Takayoshi Norimatsu,and Keiji Nagai*
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 3 (6) Pages: 1902-1909

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Monolithic and Low-Density (<50 mg/cm3) Metal Oxides Fabricated Using Electrospinning: Vanadium Oxide and Copper Oxide Examples2011

    • Author(s)
      Keiji Nagai*, Kohei Miyamoto, To mokazu Iyoda, Cao Pan, Zhongze Gu
    • Journal Title

      Fusion Sci. Technol

      Volume: 59 (1) Pages: 216-220

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrochemical and Photocatalytic Properties of Biphasic Organic p-and n-Type Semiconductor Nanoparticles Fabricated by a Reprecipitation Process2011

    • Author(s)
      Shuai Zhang, Ryohei Sakai, Toshiyuki Abe, Tomokazu Iyoda, Takayoshi Norimatsu, Keiji Nagai
    • Journal Title

      ACS Appl.Mater.Interfaces

      Volume: 3(6) Pages: 1902-1909

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Nd : YAG Laser Energy on Multilayer Hollow Nanofiber Target's Extreme Ultraviolet Conversion Efficiency2011

    • Author(s)
      Liqin Ge, Jianyu Ji, Lingling Bai, Teng Fei, Weichen Wang, Keiji Nagai, Hiroaki Nishimura, Yasukazu Izawa, Kunioki Mima, Takayoshi Norimatsu
    • Journal Title

      J.Macromol.Sci.Part B Phys.

      Volume: 50(9) Pages: 1761-1770

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Semiconductor Nanoparticles with Heterojunctions Composed of Fullerene C60 and Zinc Phthalocyanine and Their Application to Visible-Light-Responsive Photocatalysts2011

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, Takayoshi Norimatsu, Keiji Nagai
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 36[2] Pages: 177-181

    • NAID

      130005004122

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Monolithic and Low-Density (<50 mg/cm3) Metal Oxides Fabricated Using Electrospinning : Vanadium Oxide and Copper Oxide Examples2011

    • Author(s)
      Keiji Nagai, Kohei Miyamoto, Tomokazu Iyoda, Cao Pan, Zhongze Gu
    • Journal Title

      Fusion Sci.Technol

      Volume: 59(1) Pages: 216-220

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Degradation of Organic Compounds Using an Organophotocatalyst with p-n Junction Responsive to the Whole Spectrum of Vsible Light, Hot topics, 11692011

    • Author(s)
      Keiji Nagai
    • Journal Title

      Polymer Preprints, Japan

      Volume: 59(1) Pages: 3-3

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis, characterization and Visible-light phtocatalytic properties of biphasic cobalt cobalt phthalocyanine and fulleren through areprecipitation process2012

    • Author(s)
      ArunacharamPrabhakarn, Shuai Zhang, Toshiyuki Abe, Tomokazu iyoda, Keiji Nagai
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] FULL-SPECTRUM VISIBLE-LIGHT-RESPONSIVE ORGANOPHOTOCATALYST FILM2012

    • Author(s)
      Keiji Nagai, Prabhakarn Arunachalam, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      International Symposium on Polymer Chemistry (PC2012)
    • Place of Presentation
      ChangChun
    • Related Report
      2012 Final Research Report
  • [Presentation] Photocatalytic Decomposition of N-methyl-2-pyrrolidone, Aldehydes, and Thiol by Biphase and p/n Junction-like Organic Semiconductor Composite Nanoparticles Responsive to Nearly Full Spectrum of Visible Light2012

    • Author(s)
      Shuai Zhang
    • Organizer
      The 9th SPSJ International Polymer Conference (IPC 2012)
    • Place of Presentation
      神戸国際会館(兵庫県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Full-spectrum visible-light-responsive organophotocatalyst based on p-n junction2012

    • Author(s)
      Keiji Nagai, Prabhakarn Arunachalam, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      9th International Conference on the Conversion and Storage of Solar Energy (IPS 19)
    • Place of Presentation
      Caltech(米国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] FULL-SPECTRUM VISIBLE-LIGHT-RESPONSIVE ORGANOPHOTOCATALYST FILM2012

    • Author(s)
      Keiji Nagai, Prabhakarn Arunachalam, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      International Symposium on Polymer Chemistry (PC2012)
    • Place of Presentation
      ChangChun(中国)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Low density plastics target fabrication and its deuteration for laser-induced D-D reaction2011

    • Author(s)
      Keiji Nagai, Ayumi Hatano
    • Organizer
      Workshop on Ashura (Asia laser plasma) Project 2011
    • Place of Presentation
      Kanazawa(招待講演)
    • Year and Date
      2011-11-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] セルソース誘導体エアロゲルによるホルムアルデヒドの吸着2011

    • Author(s)
      荒井理沙、彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2012 Final Research Report
  • [Presentation] フロログルシノールとフロログルシノールカルボン酸を用いたフェノール樹脂由来エアロゲルの合成とそのナノ構造に関する研究2011

    • Author(s)
      幡野亜由美,波多野慎悟, 彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] セルロース誘導体由来エアロゲルによるホルムアルデヒドの吸着2011

    • Author(s)
      荒井理沙、彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photoelectrochemical and Photocatalytic Properties of cobalt Phtharocyanine and fullerene composite nanoparticles fabricated by Repreciptation Process2011

    • Author(s)
      ArunacharamPrabhakarn, Shuai Zhang, Toshiyuki Abe, Tomokazu iyoda, Keiji Nagai
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] PHOTOCATALYTIC DEGRADATION OF VOLATILE ORGANIC CCOMPOUNDS BY ORGANIC SEMICONDUCTORS WITH P-N JUNCTION RESPONSIVE TO FULL-SPECTRUM VISIBLE LIGHT2011

    • Author(s)
      Keiji Nagai
    • Organizer
      The 14th Asian Chemical Congress 2011 (14ACC)2011
    • Place of Presentation
      Bangkok(招待講演)
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Effect of solvent exchange in preparation of aerogels consisting of resorcinol and phlorogucionol carboxylic acid2011

    • Author(s)
      Ayumi Hatano, Shingo Hadano, Tomokazu Iyoda, Keiji Nagai
    • Organizer
      International Symposium on Integrated Molecular/Materials Engineering (ISIMME-6)
    • Place of Presentation
      北京
    • Year and Date
      2011-06-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Transparent adsorbent materials consisting of cellulose derivatives2011

    • Author(s)
      Risa Arai, Keiji Nagai
    • Organizer
      International Symposium on Integrated Molecular/Materials Engineering (ISIMME-6)
    • Place of Presentation
      北京
    • Year and Date
      2011-06-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] フロログルシノールとフロログルシノールカルボン酸を用いたフェノール樹脂由来多孔質ゲルの合成と化学構造解析2011

    • Author(s)
      幡野亜由美、波多野慎悟、彌田智一、Wigen NAZAROV、長井圭治
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] フロログルシノールとフロログ ルシノールカルボン酸を用いたフェノー ル樹脂由来多孔質ゲルの合成とナノ構造に関する研究2011

    • Author(s)
      幡野亜由美、波多野慎悟、彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Low density plastics target fabrication and its deuteration for laser-induced D-D reaction2011

    • Author(s)
      Keiji Nagai, Ayumi Hatano
    • Organizer
      Workshop on Ashura (Asia laser plasma) Project 2011
    • Place of Presentation
      Kanazawa ANA Crown hotel
    • Related Report
      2012 Final Research Report
  • [Presentation] Influences of the affinity between exchange solvents and organic aerogels consisting of phenols and formaldehyde2011

    • Author(s)
      Ayumi Hatano, Shingo Hadano, Tomokazu Iyoda, and Keiji Nagai
    • Organizer
      The 18th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'18) 2011
    • Place of Presentation
      Tianjin
    • Related Report
      2012 Final Research Report
  • [Presentation] Full-Spectrum Visible-Light-Responsive Organophotocatalyst Film for Removal and Degradation of Low Concentration Volatile molecules2011

    • Author(s)
      Keiji Nagai, Yuzuri Yasuda, Ichirou Kimishima, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      The 18th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'18) 2011
    • Place of Presentation
      Tianjin
    • Related Report
      2012 Final Research Report
  • [Presentation] PHOTOCATALYTIC DEGRADATION OF VOLATILE ORGANIC CCOMPOUNDS BY ORGANIC SEMICONDUCTORS WITH P-N JUNCTION RESPONSIVE TO FULL-SPECTRUM VISIBLE LIGHT2011

    • Author(s)
      Keiji Nagai
    • Organizer
      INV-S13-11, The 14th Asian Chemical Congress 2011 (14 ACC) 2011
    • Place of Presentation
      Bangkok
    • Related Report
      2012 Final Research Report
  • [Presentation] Transparent adsorbent materials consisting of cellulose derivatives2011

    • Author(s)
      Risa Arai and Keiji Nagai
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering (ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Related Report
      2012 Final Research Report
  • [Presentation] Degradation of Organic Compounds Using Organophotocatalyst with p-n Junction Responsive to Full-Spectrum Visible Light2011

    • Author(s)
      Keiji Nagai, Shuai Zhang,Yuzuri Yasuda, Ichirou Kimishima, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering(ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Related Report
      2012 Final Research Report
  • [Presentation] Effect of solvent exchange in preparation of aerogels consisting of resorcinol and phloroglucinol carboxylic acid2011

    • Author(s)
      Ayumi HATANO, Shingo HADANO, Tomokazu IYODA, Keiji NAGAI
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering (ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Related Report
      2012 Final Research Report
  • [Presentation] フロログルシノールとフロログルシノールカルボン酸を用いたフェノール樹脂由来多孔質ゲルの合成と化学構造解析2011

    • Author(s)
      幡野亜由美、波多野慎悟、彌田智一、長井圭治
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2012 Final Research Report
  • [Presentation] Visible Light Photocatalyst Composed of Organic Semicon ductor s p-n Junction Fabricated by a Wet Process2010

    • Author(s)
      Keiji Nagai, Zhang Shuai, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      The 17th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'16) 2010
    • Place of Presentation
      Beijing
    • Year and Date
      2010-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Visible Light Photocatalyst Consisiting of Phthalocyanine and p-n junction2010

    • Author(s)
      K.Nagai, Y.Yasuda, S.Zhang, I.Kimisiima, T.Iyoda, T.Abe
    • Organizer
      International Conference on Synthetic Metals 2010
    • Place of Presentation
      Kyoto
    • Year and Date
      2010-07-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Degradation of organic compounds using organophotocatalyst responsive to whole visible light (<780 nm) with p-n junction2010

    • Author(s)
      Keiji NAGAI, Yuzuri Yasuda, Shuai Zhang, Ichiro Kimishima, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      59th SPSJ Annual Meeting
    • Place of Presentation
      Yokohama
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Book] The 4th Japan-China Bilateral Workshop on IFE Target Materials & Fabrication Technology2012

    • Author(s)
      Keiji Nagai ed.
    • Total Pages
      30
    • Publisher
      Tokyo Institute of Technology and Osaka University
    • Related Report
      2012 Annual Research Report
  • [Book] Encyclopedia of Nanoscience and Nanotechnology, Volume 18, pp.75-83, "Nanomaterials to Generate Extreme Ultraviolet light" (2011)2011

    • Author(s)
      Keiji Nagai, Ed.E.H.Nalwa
    • Total Pages
      9
    • Publisher
      American Scientific Publishers, Stevenson Ranch CA
    • Related Report
      2011 Annual Research Report
  • [Remarks] 東京工業大学彌田・長井研究室ホームページ

    • URL

      http://ime.res.titech.ac.jp/

    • Related Report
      2012 Final Research Report
  • [Remarks] 東京工業大学 彌田・長井研究室

    • URL

      http://ime.res.titech.ac.jp/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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