| Project/Area Number |
22360006
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Applied materials science/Crystal engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
YAMADA Akira 東京工業大学, 大学院・理工学研究科, 教授 (40220363)
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| Co-Investigator(Kenkyū-buntansha) |
KUROKAWA Yasuyoshi 東京工業大学, 理工学研究科, 助教 (00588527)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2010: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
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| Keywords | 光物性 / 太陽電池 / ナノ粒子 / 化合物薄膜 / 半導体 / Cu(InGa)Se_2 |
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| Research Abstract |
In the research work, the fabrication process for Cu(InGa)Se2 (CIGS) solar cells has been developed by using a non-vacuum process, aiming at a realization of low-cost fabrication process for CIGS solar cells. In the process, nanoparticles were chemically synthesized, and then they were spray-printed/sintered to produce CIGS thin films. It was found that the Cu-In-Ga-Se nanoparticles caused small grain size and low crystallinity, resulting in low-efficiency solar cells. The crystallization velocity was increased and the large grain size was obtained when the Cu-Se and In-Se nanoparticles were used as the starting materials. Furthermore, a new approach for the quality improvement of CIS film has been developed, that is, thiourea has been applied as a binding agent and a sintering additive for the fabrication of high-quality CIS film. The fabricated CIS film exhibited a denser and larger-grain-size layer compared with the CIGS film fabricated using Cu-In-Ga-Se nanoparticles. Finally,a CIS solar cell with an efficiency of 3.5% has been successfully fabricated.
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