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Measurement of spin transport properties and spin coherence in molecular semiconductors

Research Project

Project/Area Number 22360008
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University

Principal Investigator

SHIRAISHI Masashi  大阪大学, 基礎工学研究科, 教授 (30397682)

Co-Investigator(Renkei-kenkyūsha) DR. VALENTIN Alek Dediu  イタリア ISMN-CNR研究所
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2012: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2011: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2010: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywordsスピントロニクス / 分子性半導体 / スピンコヒーレンス / 酸化物強磁性 / スピン緩和 / スピン輸送 / スピン / ショットキー障壁 / TMR効果
Research Abstract

The purpose of this project is to estimate spin coherence in molecular semiconductors precisely. In the first stage of the project, I was provided a molecular spin valve device from a collaborator in Italy (Dr. V. Dediu) and tried to measure spin precession of propagating spins in molecular semiconductors, which is called as Hanle effect. However, no such effect was observed due to less reliability of spin injection into molecules in the device. He nce, in the second stage, experimental investigations of an interfacial electronics structures between molecular semiconductor single crystal and ferromagnetic metals and modulation of the electronic structure were implemented, in addition to a search for a new oxide ferromagnet as a good spin source for molecular semiconductors. Both were successfully carried out. In the final stage, a new spin injection method, dynamical spin pumping, was introduced, and spin injection into a zero-gap molecular semiconductor, single-layer graphene, was successfully demonstrated and spin coherence was precisely measured. This project revealed serious problems in earlier studies of molecular spintronics, and enabled an establishment of a novel spin injection method into molecular semiconductors.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 3 results) Presentation (14 results) (of which Invited: 6 results)

  • [Journal Article] Dynamically-generated pure spin current in graphene2013

    • Author(s)
      Z. Tang, H. Ago, E. Shikoh, Y. Ando, T. Shinjo and M. Shiraishi
    • Journal Title

      Phys. Rev

      Volume: B87 Pages: 140401-140401

    • Related Report
      2012 Final Research Report
  • [Journal Article] Vertical spin transport in Al with Pd/Al/Ni80Fe20 trilayer films at room temperature by spin pumping2013

    • Author(s)
      Y. Kitamura, Y. Ando, E. Shikoh, T. Shinjo and M. Shiraishi
    • Journal Title

      Scientific Reports

      Volume: in press

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamically generated pure spin current in single-layer graphene2013

    • Author(s)
      Zhenyao Tang,
    • Journal Title

      PHYSICAL REVIEW B RAPID COMMUNICATIONS

      Volume: 87 Issue: 14 Pages: 140401-140401

    • DOI

      10.1103/physrevb.87.140401

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Realization of ohmic-like contact between ferromagnet and rubrene single crystal2012

    • Author(s)
      Y. Kitamura, E. Shikoh, K. Sawabe, T. Takenobu and M. Shiraishi
    • Journal Title

      Appl. Phys. Lett

      Volume: 101 Pages: 73501-73501

    • Related Report
      2012 Final Research Report
  • [Journal Article] Realization of ohmic-like contact between ferromagnet and rubrene single crystal2012

    • Author(s)
      Y. Kitamura, E. Shikoh, K. Sawabe, T. Takenobu and M. Shiraishi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 101 Issue: 7 Pages: 73501-73501

    • DOI

      10.1063/1.4745778

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical investigation of an interface band structure in a rubrene single-crystal/nickel junction2011

    • Author(s)
      Y. Kitamura, E. Shikoh, T. Shinjo, S.Z. Bisri, T. Takenobu and M. Shiraishi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 99 Pages: 43505-43505

    • Related Report
      2012 Final Research Report
  • [Journal Article] Observation of a tunneling magnetoresistance effect in magnetic tunnel junctions with a high resistance magnetic oxide Fe_2.5Mn_0.5O electrode2011

    • Author(s)
      E. Shikoh, T. Kanki, H. Tanaka, T. Shinjo and M. Shiraishi
    • Journal Title

      Solid State Comm

      Volume: 151 Pages: 1296-1296

    • Related Report
      2012 Final Research Report
  • [Journal Article] Molecular spintronics2011

    • Author(s)
      M. Shiraishi and T. Ikoma
    • Journal Title

      Physica E

      Volume: 43 Pages: 1295-1295

    • NAID

      40017345414

    • Related Report
      2012 Final Research Report
  • [Journal Article] Tunneling magnetoresistance effect in magnetic tunneling junctions with a high resistance ferromagnetic oxide Fe2.5Mn0.5O4 electrode2011

    • Author(s)
      E.Shikoh, M.Shiraishi, et al.
    • Journal Title

      Applied Physics Letters

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Vertical spin transport in Al with Pd/Al/Ni_80Fe_20 trilayer films at room temperature by spin pumping

    • Author(s)
      Y.Kitamura, Y. Ando, E. Shikoh, T. Shinjo and M. Shiraishi
    • Journal Title

      Scientific Reports

      Volume: (in press)

    • Related Report
      2012 Final Research Report
  • [Presentation] 純スピン流を用いたグラフェン中の低消費電力スピン情報伝播に向けて2013

    • Author(s)
      白石誠司
    • Organizer
      応用物理学会シンポジウム
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 分子を介した電気的・動力学的スピン輸送2013

    • Author(s)
      白石誠司
    • Organizer
      日本化学会・先端ウォッチングシンポジウム
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ルブレン単結晶と強磁性Ni界面への電子受容体挿入によるショットキーバリアの低減2012

    • Author(s)
      北村雄太
    • Organizer
      2012年春季応用物理学会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] グラフェンへの電気的・動力学的スピン注入2012

    • Author(s)
      白石誠司
    • Organizer
      グラフェンの材料応用にむけた基礎と応用研究会
    • Place of Presentation
      筑波大
    • Related Report
      2012 Final Research Report
  • [Presentation] 分子を介したスピン依存伝導と巨大磁気抵抗効果の発現2012

    • Author(s)
      白石誠司
    • Organizer
      日本化学会・特別企画講演
    • Place of Presentation
      慶應義塾大
    • Related Report
      2012 Final Research Report
  • [Presentation] Recent Progress on Group-IV Spintronics2012

    • Author(s)
      M. Shiraishi
    • Organizer
      Japan-Germany Joint Workshop
    • Place of Presentation
      Dresden, Germany
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ユビキタス元素を用いた純スピン流エレクトロニクス2012

    • Author(s)
      白石誠司
    • Organizer
      京都大学量子理工学教育研究セン ター第13回シンポジウム
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ラフェンへの電気的・動力学的スピン注入2012

    • Author(s)
      白石誠司
    • Organizer
      グラフェンの材料応用にむけた基礎と応用研究会
    • Place of Presentation
      筑波大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 電気的・動力学的手法を用いたナノカーボンへのスピン注入2012

    • Author(s)
      白石誠司
    • Organizer
      ニューダイヤモンドフォーラ ム
    • Place of Presentation
      東大駒場キャンパス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Spin-pumping in Single Layer Graphene2011

    • Author(s)
      Z.Tang
    • Organizer
      International Symposium on Terahertz Nanoscience (Tera Nano 2011)
    • Place of Presentation
      中之島センター(大阪府)
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrical Investigation of the Interface Band Structure in Rubrene Single-Crystal/Nickel Junction2011

    • Author(s)
      Yuta Kitamura
    • Organizer
      7th Handai Nanoscience and nanotechnology International Symposium-Nanoscience and nanotechnology in the Next Ten Years-
    • Place of Presentation
      大阪大学吹田キャンパス銀杏会館(大阪府)
    • Year and Date
      2011-11-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 新規高抵抗酸化物電極を有する強磁性トンネル接合の作製と特性評価2011

    • Author(s)
      仕幸英治, 白石誠司, ほか
    • Organizer
      第58回応用物理学関連講演会
    • Place of Presentation
      神奈川工科大
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Spin-transport-induced phenomena in molecules2011

    • Author(s)
      M. Shiraishi
    • Organizer
      International workshop of Carbon-based spintronics
    • Place of Presentation
      MPI-PKS Dresden
    • Related Report
      2012 Final Research Report
  • [Presentation] Spintronics using group-IV elements2011

    • Author(s)
      M. Shiraishi
    • Organizer
      International Workshop on Spin Currents 2011
    • Place of Presentation
      Sendai
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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