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Development of a single spin-rotational state-selected O2 beam and its application to the surface reaction analysis

Research Project

Project/Area Number 22360021
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

KURAHASHI Mitsunori  独立行政法人物質・材料研究機構, 極限計測ユニット, 主幹研究員 (10354359)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2010: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Keywords表面 / 酸素分子 / 立体 / スピン / 表面・界面物性 / 化学物理 / 原子・分子物理 / 磁性
Research Abstract

O2 is a magnetic molecule with an anisotropic shape, and its interaction with surfaces is important technologically. In this study, we prepared a state-selected O2 beam, for which both the spin and the rotational angular momentum are well defined, by using magnetic hexapolar field technique. In O2 sticking on Si(100), we have found that molecules parallel to surfaces are much more reactive than those perpendicular to the surface. We also clarified the dynamical process of O2 adsorption on Al(111), which has been disputed for more than 20 years.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (33 results)

All 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (17 results) Remarks (3 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Steric Effect in O2 Sticking on Al(111): Preference for Parallel Geometry2013

    • Author(s)
      M. Kurahashi and Y. Yamauchi
    • Journal Title

      Phys. Rev. Lett.

      Volume: 110 Pages: 4-4

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Huge steric effects in surface oxidation of Si(100)2012

    • Author(s)
      M. Kurahashi and Y. Yamauchi
    • Journal Title

      Phys. Rev. B

      Volume: 85[16] Pages: 4-4

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of O2 adsorbed on Cu(100): A spin-polarized metastable He beam study2012

    • Author(s)
      M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Phys. Rev. B

      Volume: 86[24] Pages: 6-6

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of O2 adsorbed on Cu(100): A spin-polarized metastable He beam study2012

    • Author(s)
      M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Physical Review B

      Volume: 86 Issue: 24

    • DOI

      10.1103/physrevb.86.245421

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Huge steric effects in surface oxidation of Si(100)2012

    • Author(s)
      Mitsunori Kurahashi, Yasushi Yauauchi
    • Journal Title

      Physical Review B (rapid communication)

      Volume: 85 Issue: 16 Pages: 1613021-1613024

    • DOI

      10.1103/physrevb.85.161302

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin polarization of the Si(111)-7 x 7 surface: A study with a spin-polarized metastable helium atom beam2011

    • Author(s)
      M. Kurahashi, A. Pratt, Y. Yamauchi
    • Journal Title

      Surf. Sci.

      Volume: 605 Pages: 612-615

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin-polarized metastable He study of surface magnetic order in Ho thin films2011

    • Author(s)
      A. Pratt, M. Kurahashi, Y. Yamauchi
    • Journal Title

      J. Appl. Phys.

      Volume: 109 Pages: 3-3

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin polarization of the Si(111)-7 x 7 surface : A study with a spin-polarized metastable helium atom beam2011

    • Author(s)
      M.Kurahashi, A.Pratt, Y.Yamauchi
    • Journal Title

      Surface Science

      Volume: 605 Pages: 612-615

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-polarized metastable He study of surface magnetic order in Ho thin films2011

    • Author(s)
      A.Pratt, M.Kurahashi, Y.Yamauchi
    • Journal Title

      Journal of Applied Physics

      Volume: 109

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 六極磁子による酸素分子の単一スピン・回転状態選別2010

    • Author(s)
      倉橋光紀、山内泰
    • Journal Title

      J. Vac. Soc. Of Japan

      Volume: 53 Pages: 681-685

    • NAID

      10027498966

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 六極磁子による酸素分子の単一スピン・回転状態選別2010

    • Author(s)
      倉橋光紀、山内泰
    • Journal Title

      Journal of Vacuum Society of Japan

      Volume: 53 Pages: 681-685

    • NAID

      10027498966

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Al(111)表面初期酸化における立体効果の観測2013

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Al(111)表面初期酸化における立体効果の観測2013

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] State-selected O2 beam andsteric effects in the initial oxidation ofSi(100)2012

    • Author(s)
      M. Kurahashi
    • Organizer
      Seminar at FOM institute DIFFER
    • Place of Presentation
      Nieuwegein, the Netherlands
    • Year and Date
      2012-08-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Si(100)表面初期酸化における立体効果の観測2012

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Si(100)表面酸化における立体異方性:面内方位依存性の観測2012

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Observation of a large steric effect in the initial oxidation of Si(100)2012

    • Author(s)
      M. Kurahashi, Y. Yamauchi
    • Organizer
      The 24th conference of the EPS condensed matter division
    • Place of Presentation
      Edinburgh convention center, Edinburgh, UK
    • Related Report
      2012 Final Research Report
  • [Presentation] Observation of large steric effects in O2 adsorption on Si(100)2012

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      第28回化学反応討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Si(100)表面初期酸化における立体効果の観測2012

    • Author(s)
      倉橋光紀, 山内泰:
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Si(100)表面酸化における立体異方性:面内方位依存性の観測2012

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      日本物理学会 2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Observation of a large steric effect in the initial oxidation of Si(100)2012

    • Author(s)
      M.Kurahashi and Y. Yamauchi
    • Organizer
      The 24th conference of the EPS condensed matter division
    • Place of Presentation
      Edinburgh convention center
    • Related Report
      2012 Annual Research Report
  • [Presentation] 状態選別酸素分子ビームによる表面反応立体異方性の観測2011

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      2011年日本物理学会秋季大会
    • Place of Presentation
      富山大学(冨山県)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of a velocity variable state-selected O2 beam2011

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2011-06-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 速度可変単一スピン・回転状態選別酸素分子ビームの開発(I)2011

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      応用物理学会
    • Place of Presentation
      (震災のため講演中止(予稿集))
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 状態選別酸素分子ビームによる表面反応立体異方性の観測2011

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      2011年日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Production of a single spin-rotational-state-selected O2 beam by a hexapole magnet2011

    • Author(s)
      M. Kurahashi
    • Organizer
      special seminar in Department of Chemistry
    • Place of Presentation
      National aiwan University, Taipei, Taiwan
    • Related Report
      2012 Final Research Report
  • [Presentation] Development of a elocity variable state-selected O2 beam2011

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Final Research Report
  • [Presentation] 速度可変単一スピン・回転状態選別酸素分子ビームの開発(I)2011

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      応用物理学会春季大会
    • Place of Presentation
      神奈川工科大学(震災のため中止)
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 永久磁石型多段六極磁子装置及び六極磁子焦点距離可変方法2011

    • Inventor(s)
      倉橋光紀、山内泰
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Patent Publication Number
      2013-020855
    • Filing Date
      2011-07-13
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 永久磁石型多段六極磁子装置及び六極磁子焦点距離可変方法2011

    • Inventor(s)
      倉橋光紀、山内泰
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Number
      2011-154995
    • Filing Date
      2011-07-13
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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