In situ evaluation of potential distribution in high temperature electrochemical devices
| Project/Area Number |
22360286
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Structural/Functional materials
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| Research Institution | Tohoku University |
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Principal Investigator |
AMEZAWA Koji 東北大学, 多元物質科学研究所, 教授 (90263136)
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| Co-Investigator(Kenkyū-buntansha) |
KAWADA Tatsuya 東北大学, 環境科学研究科, 教授 (10271983)
IGUCHI Fumitada 東北大学, 工学研究科, 准教授 (00361113)
HASHIMOTO Shin-ichi 東北大学, 工学研究科, 准教授 (60598473)
YASHIRO Keiji 東北大学, 多元物質科学研究所, 講師 (20323107)
UNEMOTO Atsushi 東北大学, 多元物質科学研究所, 助教 (10551525)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2011: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2010: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
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| Keywords | 高温電気化学 / その場計測 / ポテンシャル分布 / 燃料電池 / X線吸収分光 / ラマン分光 |
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| Research Abstract |
The chemical potential distribution of the reactive atomic species in high temperature electrochemical devices, such as the oxygen chemical potential in solid oxide fuel cells (SOFCs), was experimentally evaluated under device operating conditions. As results, we succeeded for the first time to clarify the oxygen potential distribution and the effective reaction area in the SOFC mixed-conducting porous cathode. Influences of such a chemical potential distribution on the device performance and durability were also investigated from the thermodynamic and kinetic points of view, taking the SOFC porous cathode as a model case.
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Report
(4 results)
Research Products
(91 results)
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[Journal Article] Compositional and Mechanical Stabilities of a (La,Sr)(Co,Fe)O^<3-δ> Cathode under SOFC Operation2012
Author(s)
Tatsuya Kawada, Mi Young Oh, Hidetaka Watanabe, Yuta Kimura, Yoshinobu Fujimaki, Tomohisa Masumitsu, Satoshi Watanabe, Shinichi Hashimoto, Koji Amezawa
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Journal Title
Electrochem. Soc. Trans
Volume: Vol.45, No. 1
Pages: 307-312
Related Report
Peer Reviewed
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[Journal Article] Compositional and Mechanical Stabilities of a (La,Sr)(Co,Fe)O3-δ Cathode under SOFC Operation2012
Author(s)
Tatsuya Kawada, Mi Young Oh, Hidetaka Watanabe, Yuta Kimura, Yoshinobu Fujimaki, Tomohisa Masumitsu, Satoshi Watanabe, Shin-ichi Hashimoto, Koji Amezawa
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Journal Title
Electrochemical Society Transactions
Volume: 45(1)
Pages: 307-312
Related Report
Peer Reviewed
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