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Development of High-performance Electrocatalysts for Direct Ethanol Fuel Cells

Research Project

Project/Area Number 22360310
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionOsaka Prefecture University

Principal Investigator

INOUE Hiroshi  大阪府立大学, 工学(系)研究科(研究院), 教授 (00213174)

Co-Investigator(Kenkyū-buntansha) HIGUCHI Eiji  大阪府立大学, 大学院・工学研究科, 助教 (80402022)
Co-Investigator(Renkei-kenkyūsha) CHIKU Masanobu  大阪府立大学, 大学院・工学研究科, 助教 (20582399)
Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords直接型エタノール燃料電池 / エタノール酸化 / 電極触媒 / アンダーポテンシャル析出 / 二酸化炭素 / 白金 / ロジウム / 酸化スズ / 直接形エタノール燃料電池 / ナノ粒子
Research Abstract

A direct ethanol fuel cell in which cheap, nontoxic and carbon-neutral bioethanol is used as a fuel is a significant power source for realizing a safe and eco-friendly society. However it is hard to break the carbon-carbon bond in an ethanol molecule, and therefore the development of a new active cathode catalyst for complete ethanol oxidation reaction to carbon dioxide is urgent. In this study we clarified with a model electrode that the selective and catalytic complete ethanol oxidation reaction was realized by not simple mixing but the controlled atomic arrangement of platinum/rhodium/tin oxides where platinum and tin oxides were not neighboring. Moreover we succeeded in synthesis of a nanoparticle catalyst with the controlled atomic arrangement.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (34 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (25 results) Remarks (5 results)

  • [Journal Article] Preparation of Ternary Anode Catalysts for Use in Direct Ethanol Fuel Cells and Their Electrocatalytic Activity for Ethanol Oxidation Reaction2014

    • Author(s)
      Eiji Higuchi, Tomonori Takase, Masanobu Chiku, Hiroshi Inoue
    • Journal Title

      J.Power Sources

      Volume: (in press) Pages: 280-287

    • DOI

      10.1016/j.jpowsour.2014.04.056

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Ternary Anode Catalysts for Use in Direct Ethanol Fuel Cells and Their Electrocatalytic Activity for Ethanol Oxidation Reaction2014

    • Author(s)
      Eiji Higuchi, Tomonori Takase, Masanobu Chiku, Hiroshi Inoue
    • Journal Title

      Journal of Power Sources

      Volume: 印刷中

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrocatalytic Ethanol Oxidation Reaction at Rh and SnO_2 Monolayer-Modified Pt Electrodes2011

    • Author(s)
      Akinori Haze, Masanobu Chiku, Eiji Higuchi, Hiroshi Inoue
    • Journal Title

      ECS Transactions

      Volume: Vol.41, No.1 Issue: 1 Pages: 2277-2282

    • DOI

      10.1149/1.3635760

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrocatalytic Ethanol Oxidation Reaction at Rh and SnO_2 Monolayer-Modified Pt Electrodes2011

    • Author(s)
      Akinori Haze
    • Journal Title

      ECS Transactions

      Volume: 41 Pages: 2277-2282

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Structure-controlled Ternary Electrocatalysts for Selective Ethanol Oxidation to CO_22013

    • Author(s)
      Hiroshi Inoue
    • Organizer
      The 224th ECS Meeting
    • Place of Presentation
      Hilton San Francisco, USA
    • Year and Date
      2013-10-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Structure-controlled Ternary Electrocatalysts for Selective Ethanol Oxidation to CO22013

    • Author(s)
      Hiroshi Inoue, Akinori Haze, Masanobu Chiku, Eiji Higuchi
    • Organizer
      The 224th ECS Meeting
    • Place of Presentation
      Hilton San Francisco, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面構造を制御したPt/Rh/SnO_x電極のエタノール酸化活性の評価および反応機構の解析2012

    • Author(s)
      井上博史(代表)
    • Organizer
      電気化学会関西支部第3回関西電気化学研究会
    • Place of Presentation
      京大
    • Year and Date
      2012-12-01
    • Related Report
      2013 Final Research Report
  • [Presentation] タンデム型 Pt/Rh/SnO_x電極触媒のエタノール酸化活性ならびに反応機構2012

    • Author(s)
      井上博史(代表)
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク
    • Year and Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 表面構造を制御したPt/Rh/SnO_x電極上でのエタノール酸化反応生成物の赤外反射吸収分光法による解析2012

    • Author(s)
      井上博史(代表)
    • Organizer
      第36回電解技術討論会
    • Place of Presentation
      滋賀県立大
    • Year and Date
      2012-10-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 構造制御した電極触媒を用いるエタノールの完全酸化2012

    • Author(s)
      井上博史(代表)
    • Organizer
      第2回CSJ 化学フェスタ
    • Place of Presentation
      東工大
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Ethanol Oxidation Reaction on Tandem-type Pt/Rh/SnO_x Electrocatalysts2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME2012)
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Mechanism of Ethanol Oxidation Reaction on Pt/Rh/SnO_x Electrocatalysts2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      The 6th Kyoto International Forum for Environmental and Energy (KIFEE)
    • Place of Presentation
      NTNU, Norway
    • Year and Date
      2012-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Mechanism of Ethanol Oxidation Reaction at Rh and/or SnO_x Monolayers-Modified Pt Electrodes2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      10th Spring Meeting of the ISE
    • Place of Presentation
      University of Western Australia, Australia
    • Year and Date
      2012-04-18
    • Related Report
      2013 Final Research Report
  • [Presentation] 赤外反射吸収分光法によるPt/Rh/Sn電極上でのエタノール酸化反応機構の解析2012

    • Author(s)
      井上博史(代表)
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松
    • Year and Date
      2012-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 赤外反射吸収分光法によるPt/Rh/Sn電極上でのエタノール酸化反応機構の解析2012

    • Author(s)
      井上博史
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松(静岡県)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Mechanism of Ethanol Oxidation Reaction at Rh and/or SnOx Monolayers-Modified Pt Electrodes2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      10th Spring Meeting of the International Society  of Electrochemistry
    • Place of Presentation
      Univ. Western Australia (Perth, Australia)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Mechanism of Ethanol Oxidation Reaction on Pt/Rh/SnOx Electrocatalysts2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      The 6th Kyoto Interational Forum for Environmental and Energy
    • Place of Presentation
      NTNU (Trondheim, Norway)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ethanol Oxidation Reaction on Tandem-type Pt/Rh/SnOx Electrocatalysts2012

    • Author(s)
      Hiroshi Inoue
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Hilton Hawaiian Villege (Honolulu, USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 構造制御した電極触媒を用いるエタノールの完全酸化2012

    • Author(s)
      井上博史
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 表面構造を制御したPt/Rh/SnOx電極上でのエタノール酸化反応生成物の赤外反射吸収分光法による解析2012

    • Author(s)
      井上博史
    • Organizer
      第36回電解技術討論会
    • Place of Presentation
      滋賀県立大学(彦根)
    • Related Report
      2012 Annual Research Report
  • [Presentation] タンデム型Pt/Rh/SnOx電極触媒のエタノール酸化活性ならびに反応機構2012

    • Author(s)
      井上博史
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡ヒルトンシーホーク(福岡)
    • Related Report
      2012 Annual Research Report
  • [Presentation] アンダーポテンシャルデポジション法を用いてRhおよびSnを修飾したPt/Rh/Sn電極のエタノール酸化活性2011

    • Author(s)
      井上博史(代表)
    • Organizer
      第35回電解技術討論会
    • Place of Presentation
      京大会館
    • Year and Date
      2011-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] アンダーポテンシャルデポジション法を用いてRhおよびSnを修飾したPt/Rh/Sn電極のエタノール酸化活性2011

    • Author(s)
      井上博史
    • Organizer
      第35回電解技術討論会
    • Place of Presentation
      同志社大学(京都府)
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electro- catalytic Ethanol Oxidation Reaction at Ru and SnO_2 Monolayer-Modified Pt Electrodes2011

    • Author(s)
      Hiroshi Inoue(代表)
    • Organizer
      The 220th ECS Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrocatalytic Ethanol Oxidation Reaction at Rh and SnO_2 Monolayer-Modified Pt Electrodes2011

    • Author(s)
      Hiroshi Inoue
    • Organizer
      The 220th ECS Meeting
    • Place of Presentation
      Westin Boston Waterfront (Boston, USA)
    • Year and Date
      2011-10-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] アンダーポテンシャルデポジション法を用いる新規エタノール酸化触媒の作製およびキャラクタリゼーション2011

    • Author(s)
      井上博史(代表)
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国大
    • Year and Date
      2011-03-31
    • Related Report
      2013 Final Research Report
  • [Presentation] アンダーポテンシャルデポジション法を用いる新規エタノール酸化触媒の作製およびキャラクタリゼーション2011

    • Author(s)
      枦晃法
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2011-03-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pt/Rh/SnO_2ナノ粒子担持カーボンブラック触媒のエタノール電解酸化活性2010

    • Author(s)
      井上博史(代表)
    • Organizer
      第34回電解技術討論会
    • Place of Presentation
      横浜国大
    • Year and Date
      2010-11-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Pt/Rh/SnO_2ナノ粒子担持カーボンブラック触媒のエタノール電解酸化活性2010

    • Author(s)
      高瀬智教
    • Organizer
      第34回電解技術討論会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka4/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] Rh原子層やSnOx原子層で修飾したPt電極上でのエタノール酸化反応機構の解析

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka4/research.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 大阪府立大学大学院工学研究科物質・化学系専攻応用化学分野電気化学研究グループ

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka4/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka4/index-e.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka4/index-e.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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