Preparation of porous materials from water-particle based colloidal solutions by one-directional freezing and drying

• Project/Area Number: 22360323
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Properties in chemical engineering process/Transfer operation/Unit operation
• Research Institution: Kyoto University
• Principal Investigator: OSHIMA Masahiro 京都大学, 大学院・工学研究科, 教授 (60185254)
• Co-Investigator(Kenkyū-buntansha): NAGAMINE Shinsuke 京都大学, 大学院・工学研究科, 准教授 (30335583)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥15,340,000 (Direct Cost: ¥11,800,000、Indirect Cost: ¥3,540,000); Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2011: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2010: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
• Keywords: 一方向凍結 / 多孔構造体 / コロイド溶液 / 凍結乾燥 / 多孔性物質 / 配向構造 / 混合溶媒 / 連通構造 / 多孔体 / ハニカム構造体 / 多孔質セラミック / 過冷却度 / 凝固 / ファイバー

Research Abstract

Unidirectional freezing is a simple and environmentally friendly method for preparing porous materials from polymer solutions or inorganic colloidal solutions. We investigated the controllability of cell structures in binary systems and diversification of porous (cell) structures in multi-components systems.

Research Products

• [Journal Article] Preparation of a unique, multihollow-core honeycomb structure via the unidirectional freezing of a binary solvent system (2013)
  • Author(s): Rika Okaji, Kentaro Taki, Shinsuke Nagamine, Masahiro Ohshima
  • Journal Title: Journal of Applied Polymer Science Volume: 130 Issue: 1 Pages: 1-9
  • DOI: 10.1002/app.39201
  • Peer Reviewed
• [Journal Article] Interconnected pores on the walls of a polymeric honeycomb monolith structure created by the unidirectional freecing of a binary polymer solution (2013)
  • Author(s): Okaji.R., Sakashita, S., Tazumi, K. Taki, K., Nagamine, S., Ohshima, M
  • Journal Title: Journal of Materials Science Volume: Vol.48, No.5 Issue: 5 Pages: 2038-2045
  • DOI: 10.1007/s10853-012-6973-2
  • Peer Reviewed
• [Journal Article] Preparation of porous honeycomb monolith from UV-curable monomer/dioxane solution via unidirectional freezing and UV irradiation (2012)
  • Author(s): Okaji.R., Taki, K., Nagamine, S., Ohshima, M
  • Journal Title: Journal of Apllied Polymer Science Volume: Vol.125, No.4 Issue: 4 Pages: 2874-2881
  • DOI: 10.1002/app.36443
  • Peer Reviewed
• [Presentation] 溶媒2成分高分子溶液の一方向凍結過程での相分離挙動と創製される多孔構造 (2012)
  • Author(s): 岡地理佳、瀧健太郎、長嶺信輔、大嶋正裕
  • Organizer: 化学工学会第77年会
  • Place of Presentation: 工学院大学
  • Year and Date: 2012-03-15
• [Presentation] 溶媒2成分高分子溶液の一方向凍結過程での相分離挙動と創製される多孔構造, (2012)
  • Author(s): 岡地理佳, 瀧健太郎, 長嶺信輔, 大嶋正裕
  • Organizer: 化学工学会第77年会
  • Place of Presentation: 工学院大学
• [Presentation] 液-液相分離現象と一方向凍結法を利用した多孔構造体の構造制御 (2011)
  • Author(s): 岡地理佳、瀧健太郎、長嶺信輔、大嶋正裕
  • Organizer: 化学工学会第43回秋季大会
  • Place of Presentation: 名古屋大学
• [Presentation] Preparation of Fibers, Lamella and Honeycomb Structures by Unidirectional Freezing (2010)
  • Author(s): Tazumi, K., S. Nagamine, J-W. Kim, R. Okaji, M. Ohshima
  • Organizer: The 9th Korea-Japan Symposium on Materials & Interfaces
  • Place of Presentation: Korea
  • Year and Date: 2010-11-01
• [Presentation] Preparation of Fibers, Lamella and Honeycomb Structures by Unidirectional Freezing (2010)
  • Author(s): Tazumi, T., S.Nagamine, J-W.Kim, R.Okaji, M.Ohshima
  • Organizer: The 9^<th> Korea-Japan Symposium on Materials & Interfaces, (Poster Awarded)
  • Place of Presentation: Yeous, Korea
  • Year and Date: 2010-11-01
• [Presentation] 一方向凍結を用いたセラミック構造体(ファイバー・ラメラ・ハニカム)の作製とその構造制御 (2010)
  • Author(s): 田積皓平、長嶺信輔、大嶋正裕
  • Organizer: 粉体工学会 2010 年度春期研究発表会
  • Place of Presentation: 京都
  • Year and Date: 2010-05-25
• [Presentation] 一方向凍結を用いたセラミック構造体(ファイバー・ラメラ・ハニカム)の作製とその構造制御 (2010)
  • Author(s): 田積皓平, 長嶺信輔, 大嶋正裕
  • Organizer: 粉体工学会2010年度春期研究発表会(Best presentation賞)
  • Place of Presentation: 京都
  • Year and Date: 2010-05-25
• [Presentation] Preparation of porous (lamella, short lamella, honeycomb) materials (2010)
  • Author(s): Tazumi, K., J-W. Kim, S. Nagamine, M. Ohshima
  • Organizer: World Congress on Particle Technology (WCPT6)
  • Place of Presentation: Germany
  • Year and Date: 2010-04-26
• [Presentation] Preparation of porous(lamella, short lamella, honeycomb)materials (2010)
  • Author(s): Tazumi, K., J-W.Kim, S.Nagamine, M.Ohshima
  • Organizer: World Congress on Particle Technology(WCPT 6)
  • Place of Presentation: Nurnberg, Germany
  • Year and Date: 2010-04-26
• [Remarks]
  • URL: http://www.cheme.kyoto-u.ac.jp/6koza/modules/pico/
• [Remarks] 京都大学工学研究科 材料プロセス工学研究室 研究概要
  • URL: http://www.cheme.kyoto-u.ac.jp/6koza/modules/pico/
• [Remarks] コロイド溶液の一方向凍結法によるセラミック繊維・多孔構造体の作製とその構造制御
  • URL: http://www.cheme.kyoto-u.ac.jp/6koza/modules/pico/index.php?content_id=12