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Integrated Analysis on Transport Phenomena during Thin Film Formation Using Inkjet method

Research Project

Project/Area Number 22360324
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyushu University

Principal Investigator

FUKAI Jun  九州大学, 工学研究院, 教授 (20189905)

Co-Investigator(Renkei-kenkyūsha) NAKASO Kouichi  九州大学, 工学研究院, 助教 (40363379)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2011: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2010: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywords薄膜形成 / 乾燥工程 / 移動現象 / 自然対流 / インクジェット / 乾燥 / 流動可視化 / self-pinning
Research Abstract

A way how to flatten a thin film using inkjet method is discussed experimentally and theoretically. Firstly the fluid dynamics in solution droplets evaporating on a substrate are analyzed. On the present system, the solutal-derived and thermal-derived Marangoni forces affect the fluid dynamics. They develop the flow in the opposite direction on the free surface. The thermal-derived forces increase with increasing the temperature of substrate. However, after evaporation is advanced in time, the solutal-derived forces finally dominates the fluid dynamics.The reason why binary solvent often forms a flat thin film has been thought to be that the fluid flow in the droplet can be controlled by the difference between the surface tensions of the solvents. However, the film configuration is not correlated to the fluid flow expected from the difference between the surface tension of the solvents, because the solutal-derived forces are larger than solvent-derived one.Consequently, the film shape is influenced by self-pinning position, which can be controlled by viscosity , contact angle and evaporation rate. The Marangoni forces are used to control delicate flatness. According to this result, a new method is proposed to form flat thin films.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (43 results)

All 2013 2012 2011 2010 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (29 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Effect of Solute- and Solvent-Derived Marangoni Flows on the Shape of Polymer Films Formed from Drying Droplets2013

    • Author(s)
      P. O. BABATUNDE, W. J. HONG, K. NAKASO, J. FUKAI
    • Journal Title

      AIChE Journal

      Volume: Vol. 59, No. 3 Issue: 3 Pages: 699-702

    • DOI

      10.1002/aic.14031

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Marangoni Flows in Polymer Soution Droplets Drying on Heating Surfaces2012

    • Author(s)
      S. YASUMATSU, K. NAKASO, J. FUKAI
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: Vol.45, No.2 Pages: 128-135

    • URL

      http://dx.doi.org/10.1252/jcej.11we124

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Organization of Polymer Films Using Single and Mixed Solvents on Chemically Patterned Surfaces2012

    • Author(s)
      S. YASUMATSU, H. ISHIZUKA, K. NAKASO, P. O. BABATUNDE, J. FUKAI
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: Vol.45, No.4 Pages: 265-271

    • NAID

      10030927960

    • URL

      http://dx.doi.org/10.1252/jcej.11we183

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Factors Dominating Polymer Film Morphology Formed from Droplets Using Mixed Solvents2012

    • Author(s)
      P. O. BABATUNDE, N. NANRI, K. ONTSUKA, K. NAKASO, J. FUKAI
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: Vol.45, No.8 Pages: 622-629

    • NAID

      130001858747

    • URL

      http://dx.doi.org/10.1252/jcej.12we085

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Organization of Polymer Films Using Single and Mixed Solvents on Chemically Patterned Surfaces2012

    • Author(s)
      Shohei YASUMATSU et al
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 45 Issue: 4 Pages: 265-271

    • DOI

      10.1252/jcej.11we183

    • NAID

      10030927960

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental Investigation on the Adsorption Process for Steam Generation Using a Zeolite–Water System2012

    • Author(s)
      Erfina OKTARIANI et al
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 45 Issue: 5 Pages: 355-362

    • DOI

      10.1252/jcej.11we128

    • NAID

      130001858814

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Factors Dominating Polymer Film Morphology Formed from Droplets Using Mixed Solvents2012

    • Author(s)
      Patience Oluwatosin BABATUNDE et al
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 45 Issue: 8 Pages: 622-629

    • DOI

      10.1252/jcej.12we085

    • NAID

      130001858747

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Marangoni Flows in Polymer Solution Droplets Drying on Heating Surfaces2012

    • Author(s)
      Shohei YASUMATSU, et al
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 45 Issue: 2 Pages: 128-135

    • DOI

      10.1252/jcej.11we124

    • NAID

      130000967363

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and Solutal Effects on Convection Inside a Polymer Solution Droplet on a Substrate2010

    • Author(s)
      M. KANEDA, Y. TAKAO, J. FUKAI
    • Journal Title

      International Journal of Heat and Mass Transfer

      Volume: Vol.53 Pages: 4448-4457

    • URL

      http://dx.doi.org/10.1016/j.ijheatmasstransfer.2010.06.049

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Specific Behaviors of Polymer Solution Droplets on Surfaces Due to Solutal Marangoni Effect2010

    • Author(s)
      K. MIYAMOTO, M. KANEDA and J. FUKAI
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: Vol.43, No.7 Pages: 618-622

    • NAID

      10027373186

    • URL

      http://dx.doi.org/10.1252/jcej.43.618

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Specific Behaviors of Polymer Solution Droplets on Surfaces Due to Solutal Marangoni Effect2010

    • Author(s)
      Kuniyasu MIYAMOTO, et al.
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: 43-7 Pages: 618-622

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and Solutal Effects on Convection Inside a Polymer Solution Droplet on a Substrate2010

    • Author(s)
      Masayuki KANEDA, et al.
    • Journal Title

      International Journal of Heat and Mass Transfer

      Volume: 53 Pages: 4448-4457

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 基板上における高分子/2成分溶媒系液滴内の移動現象解析2013

    • Author(s)
      鬼塚 健二, 南里功美, 中曽浩一, 深井潤
    • Organizer
      化学工学会第78年会
    • Year and Date
      2013-03-17
    • Related Report
      2012 Final Research Report
  • [Presentation] バンク基板上に形成した低分子有機 EL薄膜形状と操作条件の関係2012

    • Author(s)
      原田 紘伸, 坂上恵, 深井潤, 安達千波
    • Organizer
      化学工学会第44回秋季大会
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 高分子薄膜形状予測のための数値シミュレーション2012

    • Author(s)
      久保 一樹, 鬼塚 健二, 中曽 浩一, 深井潤
    • Organizer
      化学工学会第44回秋季大会
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Polymer Film Configuration Formed from Polymer Solution Droplet2012

    • Author(s)
      K. KUBO, J.-H. WANG, K. NAKASO, J. FUKAI
    • Organizer
      4th Kyushu University-Yeungnam University Joiny Symposium on Chemical Engineering
    • Place of Presentation
      fukuoka, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Numerical Simulation of Drying Process of Polymer Solution Inkjet-Droplets for Predicting Film Configuration2012

    • Author(s)
      J. FUKAI, K. KUBO, J.-H. WANG, K.NAKASO
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      Pittsburgh, U.S.A.
    • Related Report
      2012 Final Research Report
  • [Presentation] インクジェット成膜法における液滴内部の移動現象2011

    • Author(s)
      深井潤
    • Organizer
      化学工学会第43回秋季大会
    • Year and Date
      2011-09-16
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] 2成分溶液滴の蒸発速度の検討2011

    • Author(s)
      南里功美, 鬼塚健二, 中曽浩一, 深井潤
    • Organizer
      化学工学会 第43回秋季大会
    • Year and Date
      2011-09-16
    • Related Report
      2012 Final Research Report
  • [Presentation] 2成分溶液滴の蒸発速度の検討2011

    • Author(s)
      南里功美, ら
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 樹脂溶液滴の内部流動と薄膜形成に関する研究2011

    • Author(s)
      西畑陽一, 中曽浩一, 深井潤, 齋藤亨, 藤代光一
    • Organizer
      化学工学会第43回秋季大会
    • Year and Date
      2011-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 樹脂溶液滴の内部流動と薄膜形成に関する研究2011

    • Author(s)
      西畑陽一, ら
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 溶液滴内部の自然対流に及ぼす基板温度の影響2011

    • Author(s)
      鬼塚健二, 安松祥平, 南里功美, 中曽浩一, 深井潤
    • Organizer
      化学工学会 第43回秋季大会
    • Year and Date
      2011-09-14
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶液滴内部の自然対流に及ぼす基板温度の影響2011

    • Author(s)
      鬼塚健二, ら
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Structure of Circulation Flows in Polymer Solution Droplets Receding on Flat Surfaces2011

    • Author(s)
      吉竹祐, ら
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京農工大学(東京都)
    • Year and Date
      2011-03-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Free Convection in Microscopic Polymer Solution Droplets2010

    • Author(s)
      Shohei YASUMATSU, et al.
    • Organizer
      International Workshop on Process Intensification 2010
    • Place of Presentation
      九州大学(福岡市)
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子液滴内の内部流動の可視化と数値解析2010

    • Author(s)
      深井潤
    • Organizer
      第7回色材IT講座
    • Place of Presentation
      日本大学理工学部(東京都)
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation of Thin Polymer Film from Droplet on Circular Patterned Surfaces : Effect of Surface Tension and Viscosity on Film Configuration2010

    • Author(s)
      Babatunde Patience OLUWATOSIN, et al.
    • Organizer
      6th International Symposium on Novel Carbon Resource Sciences
    • Place of Presentation
      九州大学(福岡市)
    • Year and Date
      2010-11-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Marangoni and Rayleigh Effects on Fluid Dynamics in Polymer Solution Droplets Evaporating on Flat Surfaces2010

    • Author(s)
      Narumi NANRI, et al.
    • Organizer
      13th Asia Pacific Confederation of Chemical Engineering Congress
    • Place of Presentation
      Howard International House台北(台湾)
    • Year and Date
      2010-10-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] 基板上で蒸発する溶液滴内の溶質濃度差対流の構造2010

    • Author(s)
      南里功美, ら
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 基板上で蒸発する溶液滴内部流動に及ぼす気相内熱物質拡散の影響2010

    • Author(s)
      安松祥平, ら
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Internal Flows in Microscopic Polymer Solution Droplets Evaporating on Flat Surfaces2010

    • Author(s)
      Shohei YASUMATSU, et al.
    • Organizer
      International Heat Transfer Conference (IHTC)
    • Place of Presentation
      Omni Shoreham Hotelワシントン・DC(アメリカ合衆国)
    • Year and Date
      2010-08-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Internal Flows in Microscopic Polymer Solution Droplets Evaporating on Flat Surfaces2010

    • Author(s)
      S. YASUMATSU, N. NANRI, Y. YOSHITAKE, K. NAKASO, J. FUKAI
    • Organizer
      International Heat Transfer Conference (IHTC)
    • Place of Presentation
      Washington. DC, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Marangoni and Rayleigh Effects on Fluid Dynamics in Polymer Solution Droplets Evaporating on Flat Surfaces2010

    • Author(s)
      N. NANRI, S. YASUMATSU, K. NAKASO, J. FUKAI
    • Organizer
      13th Asia Pacific Confederation of Chemical Engineering Congress
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2012 Final Research Report
  • [Presentation] Formation of Thin Polymer Film from Droplet on Circular Patterned Surfaces: Effect of Surface Tension and Viscosity on Film Configuration2010

    • Author(s)
      B. P. OLUWATOSIN, K. NAKASO, J. FUKAI
    • Organizer
      6th International Symposium on Novel Carbon Resource Sciences
    • Place of Presentation
      Fukuoka, JAPAN
    • Related Report
      2012 Final Research Report
  • [Presentation] Free Convection in Microscopic Polymer Solution Droplets2010

    • Author(s)
      S. YASUMATSU, N. NANRI, K. NAKASO, J.FUKAI
    • Organizer
      International Workshop on Process Intensification 2010
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] 高分子薄膜形状予測のための数値シミュレーション

    • Author(s)
      久保 一樹ら
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] バンク基板上に形成した低分子有機EL薄膜形状と操作条件の関係

    • Author(s)
      原田 紘伸ら
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Prediction of Polymer Film Configuration Formed from Polymer Solution Droplet

    • Author(s)
      Kazuki KUBO et al
    • Organizer
      The 4th Kyushu University-Yeungnam University Joiny Symposium on Chemical Engineering
    • Place of Presentation
      九州大学(福岡市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Numerical Simulation of Drying Process of Polymer Solution Inkjet-Droplets for Predicting Film Configuration

    • Author(s)
      Jun Fukai  et al
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      David L. Lawrence Convention Center(Pittsburgh,PA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 基板上における高分子/2成分溶媒系液滴内の移動現象解析

    • Author(s)
      鬼塚 健二ら
    • Organizer
      化学工学会 第78年会
    • Place of Presentation
      大阪大学(豊中市)
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機半導体含有層形成用レベリング剤、有機半導体含有層形成用組成物、並びに、有機デバイス及びその製造方法2013

    • Inventor(s)
      坂上恵, 原田紘伸 , 安藤健人,深井潤, 安達千波矢
    • Industrial Property Rights Holder
      坂上恵, 原田紘伸 , 安藤健人,深井潤, 安達千波矢
    • Industrial Property Number
      2013-058581
    • Filing Date
      2013-03-21
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 有機半導体含有層形成用レベリング剤、有機半導体含有層形成用組成物、並びに、有機デバイス及びその製造方法2013

    • Inventor(s)
      坂上恵, 原田紘伸 , 安藤健人, 深井潤, 安達千波矢
    • Industrial Property Rights Holder
      坂上恵, 原田紘伸 , 安藤健人, 深井潤, 安達千波矢
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-058581
    • Filing Date
      2013-03-21
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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