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Nano-capacitor fabrication process development by using supercritical fluid

Research Project

Project/Area Number 22360329
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionThe University of Tokyo

Principal Investigator

SHIMOGAKI Yukihiro  東京大学, 大学院・工学系研究科, 教授 (60192613)

Co-Investigator(Kenkyū-buntansha) MOMOSE Takeshi  東京大学, 大学院・工学系研究科, 助教 (10611163)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2012: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords超臨界流体 / 薄膜合成 / プロセス開発 / DRAM / FeRAM / 電極 / 高誘電体 / 強 誘電体 / 超臨界流体薄膜合成 / 強誘電体 / ナノキャパシタ / 電極形成 / SrRuO3 / SrTiO3 / BiTiO3 / 超臨界 / 電極金属 / ステップカバレッジ / メモリーデバイス / 薄膜形成 / 金属・酸化膜積層構造形成
Research Abstract

Process for nano-capacitors to be used in DRAMs and FeRAMs using supercritical CO2 (scCO2) was developed. Organic metal compounds were dissolved into scCO2 and reacted to form thin films on a heated substrate. This process, Supercritical Fluid Deposition, SCFD, was used to deposit Ru, Pt, and SrRuO3 as an electrode. TiO2, SrTiO3, and BiTiO3 were also deposited as a high-dielectric constant material and ferroelectric material. The developed processes showed excellent step coverage like as the conventional processes of CVD/ALD with lower deposition temperature.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (18 results)

All 2013 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (12 results) Remarks (1 results)

  • [Journal Article] Strontium ruthenium oxide deposition in supercritical carbon dioxide using a closed reactor system2013

    • Author(s)
      Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Journal Title

      J.Supercritical Fluid

      Volume: 79 Pages: 244-250

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ethanol-Assisted Flow-Type Supercritical Fluid Deposition of SrRuO3 for Stoichiometric Film Formation2013

    • Author(s)
      Kyubong Jung, Yu Zhao, Takeshi Momose ,and Yukihiro Shimogaki
    • Journal Title

      ECS Solid State Letters

      Volume: 2

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Strontium ruthenium oxide deposition in supercritical carbon dioxide using a closed reactor system2013

    • Author(s)
      Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Journal Title

      The Journal of Supercritical Fluid

      Volume: In Press Pages: 244-250

    • DOI

      10.1016/j.supflu.2013.03.008

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Step Coverage Quality of Cu Films by Supercritical Fluid Deposition Compared with Chemical Vapor Deposition2010

    • Author(s)
      T.Momose, M.Sugiyama, E.Kondoh, Y.Shimogaki
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 49

    • NAID

      210000068539

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Initial Cu Growth in Cu-Seeded and Ru-Lined Narrow Trenches for Supercritical Fluid Cu Chemical Deposition2010

    • Author(s)
      E.Kondoh, M.Matsubara, K.Tamai, Y.Shimogaki
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 49

    • NAID

      210000068522

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Conformal step coverage TiO2 deposition using supercritical CO22013

    • Author(s)
      Kyubong Jung, Yu Zhao, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      Materials for Advanced Metallization 2013
    • Place of Presentation
      Leuven, Bergium.
    • Related Report
      2012 Final Research Report
  • [Presentation] Supercritical fluid deposition (SCFD) of crystallized TiO2 with alcohol assistance2013

    • Author(s)
      Yu Zhao, Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      E-MRS Spring Conference 2013
    • Place of Presentation
      Strasbourg, France.
    • Related Report
      2012 Final Research Report
  • [Presentation] Supercritical fluid deposition of crystallized TiO2 with assistance of alcohol2013

    • Author(s)
      Yu Zhao, Kyubong Jun, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Kinetics study of TiO2 deposition in supercritical CO2 using Micro-/Macro-cavity method2013

    • Author(s)
      Kyubong Jun, Yu Zhao, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 超臨界流体を利用した次世代DRAM用高誘電体薄膜作製プロセスの開発2012

    • Author(s)
      渡邊圭, 百瀬健, 霜垣幸浩
    • Organizer
      化学工学会
    • Place of Presentation
      工学院大学(新宿)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Low temperature process for Strontium Ruthenium Oxide in Supercritical Carbon Dioxide2012

    • Author(s)
      Kyubong Jung, Takeshi Momose, and YukihiroShimogaki
    • Organizer
      10th International Symposium on Supercritical Fluids
    • Place of Presentation
      San Francisco, USA.
    • Related Report
      2012 Final Research Report
  • [Presentation] Precursors Selection for TiO2 Thin Film Deposition in Supercritical CO22012

    • Author(s)
      Yu Zhao, Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      International Union of Materials Research Societies- International Conference on Electronic Materials
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Final Research Report
  • [Presentation] Supercritical Fluid Deposition of Bismuth Titanate for Embedded FeRAM Applications2012

    • Author(s)
      Yu Zhao, Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science
    • Place of Presentation
      Hawaii, USA.
    • Related Report
      2012 Final Research Report
  • [Presentation] Deposition Mechanism of Metal Oxide for FeRAM Electrode using Flow Type Supercritical Fluid Deposition Reactor2012

    • Author(s)
      Kyubong Jung, Yu Zhao, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science
    • Place of Presentation
      Hawaii, USA.
    • Related Report
      2012 Final Research Report
  • [Presentation] 超臨界流体を利用したDRAM, FeRAM電極用Ru薄膜及びPt薄膜の作製2011

    • Author(s)
      渡邊圭, 霜垣幸浩
    • Organizer
      化学工学会第76回年会
    • Place of Presentation
      東京農工大学小金井キャンパス
    • Year and Date
      2011-03-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ru and Pt Films Fabrication for 3D Capacitor Electrodes Using Supercritical Fluid Deposition Technique2011

    • Author(s)
      Kei Watanabe, Takeshi Momose, and YukihiroShimogaki
    • Organizer
      Advanced Metallization Conference 2011, Asian Session
    • Place of Presentation
      Tokyo
    • Related Report
      2012 Final Research Report
  • [Presentation] RuO2 Deposition Using Supercritical Fluid Deposition (SCFD)2011

    • Author(s)
      Kyubong Jung, Takeshi Momose, and Yukihiro Shimogaki
    • Organizer
      Advanced Metallization Conference 2011, Asian Session
    • Place of Presentation
      Tokyo
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.dpe.mm.t.u-tokyo.ac.jp

    • Related Report
      2012 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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