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Development of metal-honeycomb-type structured catalyst system contributing to an advanced progression of hydrogen production

Research Project

Project/Area Number 22360330
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionShizuoka University

Principal Investigator

FUKUHARA Choji  静岡大学, 工学部, 教授 (30199260)

Co-Investigator(Kenkyū-buntansha) TATEMOTO Yuji  静岡大学, 工学部, 准教授 (00324335)
KOHNO Yoshiumi  静岡大学, 工学部, 助教 (50334959)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2010: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Keywords新エネルギー / 水素製造システム / 触媒反応システム / 水蒸気改質 / ハニカム型触媒 / 無電解めっき技術 / 触媒燃焼 / 燃料電池
Research Abstract

In order to construct a novel hydrogen production system, a honeycomb-type nickel-based catalyst systemwas constructed by a combination technique consisting of a sol-gel method and an electroless plating on a stainless steel substrate. The constructed system demonstrated high reforming property of methane steam reforming and high hydrogen production ability close to the equilibrium conversion. The multifunctional reforming system, which combined with a catalytic combustion through the reactor wall, was also constructed. This combined reforming system enabled a rapid supply of thermal energy to reactive zone by conductive heat transfer and produced an improvement of a great advance of hydrogen production ability.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (53 results)

All 2013 2012 2011 2010

All Journal Article (22 results) (of which Peer Reviewed: 22 results) Presentation (23 results) Book (7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] A Combination of Electroless Plating and Sol-Gel Methods as a Novel Technique for Preparing a Honeycomb-type-structured Catalyst2013

    • Author(s)
      Choji Fukuhara
    • Journal Title

      Chemistry Letters

      Volume: 42 Pages: 416-418

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stable and Selective Perovskite Catalyst for Dehydrogenation of Propane Working with Redox Mechanism2013

    • Author(s)
      Ryo Watanabe
    • Journal Title

      Jornal of Molecular Catalysis A:General

      Volume: in print

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption state of carbon monoxide on a structured copper-based catalyst prepared by electroless plating for low-temperature water-gas shift reaction2012

    • Author(s)
      C. Fukuhara,T. Yamada, H. Ohkura and R. Watanabe
    • Journal Title

      Chemistry Letters

      Volume: vol.41 Pages: 900-901

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structured catalysis prepared by elctroless plating technique onto a metal substrate for a wall-type hydrogen production system2012

    • Author(s)
      C.Fukuhara, 他1名
    • Journal Title

      Catalysis Surveys from Asia

      Volume: 16 Issue: 2 Pages: 1-13

    • DOI

      10.1007/s10563-012-9134-3

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Numerical Analysis of Drying Characteristics of Wet Material Immersed in Fluidized Bed of Inert Particles2012

    • Author(s)
      Y. Tatemotoand T. Sawada
    • Journal Title

      Drying Technology

      Volume: vol.30 Issue: 9 Pages: 979-988

    • DOI

      10.1080/07373937.2012.675604

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Behavior of Pieces of Plastic Sheet in Solid-Liquid Fluidized Bed with Stirring2012

    • Author(s)
      Y. Tatemoto, T. Michikoshi, T. Higashino, S. Maeda, S. Maeda and Y. Bando
    • Journal Title

      Chemical Engineering & Technology

      Volume: vol.35 Issue: 10 Pages: 1872-1878

    • DOI

      10.1002/ceat.201200201

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption State of Carbon Monoxide on a Structured Copper-based Catalyst Prepared by Electroless Plating for Low-temperature Water-Gas Shift Reaction2012

    • Author(s)
      Choji Fukuhara
    • Journal Title

      Chemistry Letters

      Volume: 41 Pages: 900-901

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Numerical Analysis of Drying Characteristics of Wet Material Immersed in Fluidized Bed of Inert Particles2012

    • Author(s)
      Yuji Tatemoto
    • Journal Title

      Drying Technology

      Volume: 30 Pages: 979-988

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of a hydrophobic natural dye byintercalation into organo- montmorillonite2011

    • Author(s)
      Y. Ko h n o, K. Kobayashi, C. Fukuharaet. al.
    • Journal Title

      Applied Clay Science

      Volume: vol.54 Issue: 3-4 Pages: 202-205

    • DOI

      10.1016/j.clay.2011.09.001

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of multi-layer anode for direct methanol fuel cell2011

    • Author(s)
      T. Nakashima, H. Saito, K. Murano, C. Fukuharaand M. Sudo
    • Journal Title

      Electrochemistry

      Volume: vol.79 Pages: 361-363

    • NAID

      10027962375

    • URL

      https://www.jstage.jst.go.jp/article/electrochemistry/79/5/79_5_361/_pdf

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Drying of Suspensions in a Fluidized Bed of Inert Particles under Reduced Pressure2011

    • Author(s)
      Y. Tatemotoand K. Miyazawa
    • Journal Title

      Drying Technology

      Volume: vol.29 Issue: 10 Pages: 1204-1209

    • DOI

      10.1080/07373937.2011.578780

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Prediction of the Behavior of a Liquid-Fluidized Bed of Inert Particles used for Separation by Density2011

    • Author(s)
      Y. Tatemoto, T. Higashino, Y. Suzuki, T. Michikoshi, S. Maeda, Y. Bando
    • Journal Title

      Chemical Engineering & Technology

      Volume: vol.34 Issue: 6 Pages: 877-885

    • DOI

      10.1002/ceat.201100012

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photo-induced coloration of 2-hydroxychalcone in the clay interlayer2011

    • Author(s)
      Y. Kohno, M. Ito, M. Kurata, S. Ikoma, M. Shibata, R. Matsushima, Y. Tomita, Y. Maeda, K. Kobayashi
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: vol.218 Issue: 1 Pages: 87-92

    • DOI

      10.1016/j.jphotochem.2010.12.007

    • NAID

      120002954716

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrochemical Characteristics of Iron Oxide/Polyaniline in Aqueous Acidic Solution2011

    • Author(s)
      Y. Kohno, Y. Tomita, K. Kobayashi, Y. Maeda
    • Journal Title

      Electrochemistry

      Volume: 79 Issue: 3 Pages: 168-171

    • DOI

      10.5796/electrochemistry.79.168

    • NAID

      130002150459

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Prediction of the Behavior of a Liquid-Fluidized Bed of Inert Particles Used for Separation by Density2011

    • Author(s)
      Y.Tatemoto, T.Higashino, Y.Suzuki, T.Michikoshi, S.Maeda, Y.Bando
    • Journal Title

      Chemical Engineering & Technology

      Volume: 34 Pages: 877-885

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo-induced coloration of 2-hydroxychalcone in the clay interlayer2011

    • Author(s)
      Yoshiumi Kohno, et al.
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Volume: 218 Pages: 87-92

    • NAID

      120002954716

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectrochemical characteristics of iron oxide/polyaniline in aqueous acidic solution2011

    • Author(s)
      Yoshiumi Kohno, et al.
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 168-171

    • NAID

      130002150459

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Possibility for hole doping into amorphous InGaZnO4 films prepared by RF sputtering2011

    • Author(s)
      Yoshiumi Kohno, et al.
    • Journal Title

      Phys.Status Solidi C

      Volume: 8 Pages: 531-533

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of flavylium dye by incorporation into Fe-containing mesoporous silicate2010

    • Author(s)
      Y. Kohno, M. Senga, M. Shibata, K. Yoda, R. Matsushima et al
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: vol.141 Issue: 1-3 Pages: 77-80

    • DOI

      10.1016/j.micromeso.2010.11.004

    • NAID

      120002954717

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of volume fraction of material on separation by density difference in liquid-fluidized bed of inert particles2010

    • Author(s)
      Tatemoto, Y., et al.
    • Journal Title

      Chemical Engineering & Technology

      Volume: 33(7) Pages: 1-9

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochromism of a 2-hydroxy-4'-methoxychalcone/silica composite2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Journal Title

      J.Jpn.Soc.Colour Mater.

      Volume: 83 Pages: 289-294

    • NAID

      10026797599

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of cathode active material for Li-ion secondary battery by mechanical milling and their properties2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Journal Title

      Trans.MRSJ

      Volume: 35 Pages: 709-712

    • NAID

      130004676362

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Development of a novel methane reforming system combined with catalytic combustion through the reactor wall2012

    • Author(s)
      C. Fukuhara
    • Organizer
      22th International Symposium of Chemical Reaction Engineering
    • Place of Presentation
      Maastricht Netherlands
    • Year and Date
      2012-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] A structured methane-reforming system combined with catalytic combustion as a novel type2012

    • Author(s)
      C. Fukuhara
    • Organizer
      7th International Conference on Environmental Catalysis
    • Place of Presentation
      Lyon Furance
    • Year and Date
      2012-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] A novel hydrogen production system in which compactly combined reforming and CO removing system2012

    • Author(s)
      C. Fukuhara
    • Organizer
      15th International Congress on Catalysis
    • Place of Presentation
      Munchen Germany
    • Year and Date
      2012-07-01
    • Related Report
      2012 Final Research Report
  • [Presentation] Development of novel perovskite-type oxide catalysts for dehydrogenation of propane with steam2012

    • Author(s)
      C. Fukuhara
    • Organizer
      15th International Congress on Catalysis
    • Place of Presentation
      Munchen Germany
    • Year and Date
      2012-07-01
    • Related Report
      2012 Final Research Report
  • [Presentation] A novel hydrogen production system in which compactly combined reforming and CO removing system2012

    • Author(s)
      Choji Fukuhara
    • Organizer
      15th International Congress on Catalysis
    • Place of Presentation
      International Congress Center Munich (Munchen, Germany)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Development of novel perovskite-type oxide catalysts for dehydrogenation of propane with steam2012

    • Author(s)
      Choji Fukuhara
    • Organizer
      15th International Congress on Catalysis
    • Place of Presentation
      International Congress Center Munich (Munchen, Germany)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Development of a novel methane reforming system combined with catalytic combustion through the reactor wall2012

    • Author(s)
      Choji Fukuhara
    • Organizer
      22th International Symposium of Chemical Reaction Engineering
    • Place of Presentation
      MECC Maastricht (Maastricht, Netherlands)
    • Related Report
      2012 Annual Research Report
  • [Presentation] A structured methane-reforming system combined with catalytic combustion as a novel type reformer2012

    • Author(s)
      Choji Fukuhara
    • Organizer
      7th International Conference on Environmental Catalysis
    • Place of Presentation
      Lyon Convention Center (Lyon, France)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Drying Characteristics of Agricultural Products Immersed in Fluidized Bed of Inert Particles under Reduced Pressure2012

    • Author(s)
      Yuji Tatemoto
    • Organizer
      18th International Drying Symposium
    • Place of Presentation
      Swiss International Hotel (Xiamen, China)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Photooxidation Treatment of Organic Materials on Titanium Dioxide Photoelectrode in Aqueous Solution Containing Sodium Chloride2012

    • Author(s)
      Yoshiumi Kohno
    • Organizer
      2012 Pacific RIM Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Hawaii Convention Center and the Hilton Hawaiian Village (Honolulu, Hawaii)
    • Related Report
      2012 Annual Research Report
  • [Presentation] A novel preparation method for construction of methane-steam reforming site over a honeycomb-type substrate2011

    • Author(s)
      C. Fukuhara
    • Organizer
      10thEuropean Congress on Catalysis
    • Place of Presentation
      Glasgow Scotland, U.K
    • Year and Date
      2011-09-01
    • Related Report
      2012 Final Research Report
  • [Presentation] A Novel Preparation Method for Construction of Methane-Steam Reforming Site over a Honeycomb-Type Substrate2011

    • Author(s)
      C.Fukuhara, K.Yasuda, Y.Makiyama, H.Ohkura
    • Organizer
      EuropaCat X (The 10th European Catalyst Symposium)
    • Place of Presentation
      University of Glasgow, Glasgow, Scotland, U.K.
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Multi-Functional Reaction System with Compactly Combining Reformer and CO Remover2011

    • Author(s)
      T.Suzuki, S.Nakatsuka, K.Sugimoto, C.Fukuhara
    • Organizer
      The 6th Joint Japan/China Chemical Engineering Symposium
    • Place of Presentation
      武漢湖浜花園Wuhan, China
    • Year and Date
      2011-06-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Performance of Methane-Steam Reforming System Combined with Catalytic Combustion through the Reactor Wall2011

    • Author(s)
      Y.Makiyama, C.Fukuhara, et al
    • Organizer
      The 6th Joint Japan/China Chemical Engineering Symposium
    • Place of Presentation
      武漢湖浜花園Wuhan, China
    • Year and Date
      2011-06-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Positive effect of steaming and oxidation pretreatments on construction of Methanol reforming site over a structured Pd/Zn-based catalyst prepared by electroless plating2010

    • Author(s)
      Choji Fukuhara, et al.
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii Convention Center (USA)
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Positive effect of steaming and oxidation pretreatments on construction of methanol reforming site over a structured Pd/Zn-based catalyst prepared by electroless plating2010

    • Author(s)
      C. Fukuhara
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu USA
    • Year and Date
      2010-12-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Photoanodic deposition of metal oxides and conducting polymers oniron oxide electrode in aqueous solution2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Organizer
      61st Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Acropolis Palais des Congres (France)
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Amperometric detection of dye concentration in the solution by using diamond electrode2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Organizer
      61st Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Acropolis Palais des Congres (France)
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Performance and characterization of a plate-type catalyst for structured Reformer and CO shift converter2010

    • Author(s)
      Choji Fukuhara, et al.
    • Organizer
      21th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Loews Philadelphia Hotel (USA)
    • Year and Date
      2010-06-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Performance and Characterization of a plate-type catalyst for structured reformer and CO shift converter2010

    • Author(s)
      C. Fukuhara
    • Organizer
      21th International Symposium of Chemical Reaction Engineering
    • Place of Presentation
      Philadelphia USA
    • Year and Date
      2010-06-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Amorphous p-type InGaZnO4 films prepared by rf sputtering of targets of InGaZnO4 and A1N mixed powders2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Organizer
      The 37th International Symposium on Compound Semiconductors
    • Place of Presentation
      Takamatsu Symbol Tower (Kagawa)
    • Year and Date
      2010-05-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electrochemical detection of the concentration of methylene blue in the solution by diamond electrode2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Organizer
      The 7th Asian Conference on Electrochemistry in Kumamoto
    • Place of Presentation
      KKR Hotel Kumamoto (Kumamoto)
    • Year and Date
      2010-05-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photoelectrochemical characteristics of iron oxide/polyaniline in aqueous solution2010

    • Author(s)
      Yoshiumi Kohno, et al.
    • Organizer
      The 7th Asian Conference on Electrochemistry in Kumamoto
    • Place of Presentation
      KKR Hotel Kumamoto (Kumamoto)
    • Year and Date
      2010-05-19
    • Related Report
      2010 Annual Research Report
  • [Book] 分離技術シリーズ27,実用乾燥技術集覧2013

    • Author(s)
      立元雄治
    • Total Pages
      283
    • Publisher
      分離技術会
    • Related Report
      2012 Annual Research Report
  • [Book] 第2版 初歩から学ぶ乾燥技術-基礎と実践2013

    • Author(s)
      中村正秋
    • Total Pages
      201
    • Publisher
      丸善出版
    • Related Report
      2012 Annual Research Report
  • [Book] 基礎化学工学2012

    • Author(s)
      福原長寿分筆, (全6名)
    • Total Pages
      239
    • Publisher
      共立出版
    • Related Report
      2012 Final Research Report
  • [Book] 基礎化学工学2012

    • Author(s)
      須藤雅夫
    • Total Pages
      239
    • Publisher
      三共出版
    • Related Report
      2012 Annual Research Report
  • [Book] 触媒調製ハンドブック(監修岩本正和)2011

    • Author(s)
      福原長寿(分筆)
    • Total Pages
      702
    • Publisher
      NTS
    • Related Report
      2011 Annual Research Report
  • [Book] 触媒調製ハンドブック2011

    • Author(s)
      福原長寿(分筆)
    • Total Pages
      700
    • Publisher
      NTS
    • Related Report
      2010 Annual Research Report
  • [Book] 触媒調製ハンドブック2010

    • Author(s)
      福原長寿分筆, (全190名)
    • Total Pages
      1200
    • Publisher
      NTS
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] エチルベンゼン脱水素用触媒およびエチルベンゼンの脱水素方法2013

    • Inventor(s)
      福原長寿,渡部 綾,岩井 清
    • Industrial Property Rights Holder
      福原長寿,渡部 綾,岩井 清
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-03-08
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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