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Development of vanadium solid battery with high energy density for hybrid vehicles

Research Project

Project/Area Number 22360408
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTohoku University

Principal Investigator

YAMAMURA Tomoo  東北大学, 金属材料研究所, 准教授 (20281983)

Co-Investigator(Kenkyū-buntansha) LI Dexin  東北大学, 金属材料研究所, 助教 (40281985)
SHIRASAKI Kenji  東北大学, 金属材料研究所, 技術職員 (70447176)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywords固体電池 / バナジウム / 有機溶媒フリー / ハイブリッド自動車用電池 / 過電圧過 程 / 固体塩電池 / エネルギー密度 / 有機物フリー / 過電圧過程
Research Abstract

Standard rate constant, which is required to evaluate the energy efficiency, is believed to be “constant". However, there are practically dependent on the concentration of active materials. In addition, our VSSB uses slurry active material with very high concentration. In this work, the dependence of the “standard rate constant" on concentration of Vanadium ions and its effect on the energy efficiency were clarified. Standard rate constants (k0) for 1 - 5 mol dm-3 in composite of “carbon fiber - slurry active material" was evaluated. On the basis of the obtained k0 values, energy efficiencies for VRFB and VSSB were calculated. In spite that k0 decreases with increasing the concentration, energy efficiency for VSSB is not decreased because of the compensation by the large concentration.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (33 results)

All 2013 2012 2011 2010 Other

All Journal Article (18 results) (of which Peer Reviewed: 4 results) Presentation (4 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (11 results)

  • [Journal Article] Linear trinuclear Zn(II)-Ce(II)-Zn(II) complex whichbehaves as a single-molecule magnet2013

    • Author(s)
      S. Hino, M. Maeda, K. Yamashita, Y.Kataoka, M. Nakano, T. Yamamura, H. Nojiri, M. Kofu, O. Yamamuro, T. Kajiwara
    • Journal Title

      Dalton Trans

      Volume: 42 Pages: 2683-2686

    • Related Report
      2012 Final Research Report
  • [Journal Article] A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe2013

    • Author(s)
      K. Yamashita, R. Miyazaki, Y. Kataoka, T. Nakanishi, Y. Hasegawa, M. Nakano, T. Yamamura, T. Kajiwara
    • Journal Title

      DaltonTrans

      Volume: 42 Pages: 1987-1990

    • Related Report
      2012 Final Research Report
  • [Journal Article] Magnetic entropy change and relative cooling power of Gd_3Ni_6A_l2 and Tb_3Ni_6Al_2 compounds2013

    • Author(s)
      D. X. Li, S. Nimori ,D. Aoki
    • Journal Title

      Solid State Communs

      Volume: 156 Pages: 54-58

    • Related Report
      2012 Final Research Report
  • [Journal Article] Giant and isotropic low temperature magnetocaloric effect in magnetic semiconductor EuSe2013

    • Author(s)
      D. X. Li, T. Yamamura, S. Nimori, Y. Homma,F. Honda ,D. Aoki
    • Journal Title

      Appl. Phys. Lett

      Volume: 102 Pages: 1524091-4

    • Related Report
      2012 Final Research Report
  • [Journal Article] Competition between Magnetic Ordering and Random Spin Freezing in Dy_2PtS_32013

    • Author(s)
      D. X. Li, T. Yamamura, Y. Homma, K. Yubuta, T. Shikama, D. Aoki
    • Journal Title

      Journal of the Korean Physical Society

      Volume: (in press)

    • Related Report
      2012 Final Research Report
  • [Journal Article] Correlation between slow magnetic relaxation and the coordination structures of a family of linear trinuclear Zn(II)-Ln(III)-Zn(II) complexes (Ln= Tb, Dy, Ho, Er, Tm and Yb)2012

    • Author(s)
      M. Maeda,S. Hino, K. Yamashita, Y.Kataoka, M. Nakano, T. Yamamura, T. Kajiwara
    • Journal Title

      Dalton Trans

      Volume: 41巻 Issue: 44 Pages: 13640-13648

    • DOI

      10.1039/c2dt31399e

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Random spin freezing in single crystalline Ce2CuSi32012

    • Author(s)
      D. X. Li
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 400 Issue: 3 Pages: 32044-32044

    • DOI

      10.1088/1742-6596/400/3/032044

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic ordering and magnetocaloric effect in PrPdIn and NdPdIn2012

    • Author(s)
      D. X. Li, S. Nimori,Y. Shikama
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 400 Pages: 0320451-4

    • Related Report
      2012 Final Research Report
  • [Journal Article] ウラン電池からバナジウム固体塩電池(VSSB)へ2012

    • Author(s)
      山村朝雄
    • Journal Title

      放射化学ニュース

      Volume: 24 Pages: 61-66

    • Related Report
      2012 Annual Research Report
  • [Journal Article] ウラン電池からバナジウム固体塩電池(VSSB)へ2011

    • Author(s)
      山村朝雄、大田卓
    • Journal Title

      放射化学ニュース

      Volume: 24巻 Pages: 61-66

    • URL

      http://www.radiochem.org/rad-nw/rad_nw24.pdf

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Journal Article] Vanadium solid-salt battery: Solid state with two redox couples2011

    • Author(s)
      Tomoo Yamamura, Xiongwei Wu, Suguru Ohta, Kenji Shirasaki, Hiroki Sakuraba,Isamu Satoh, Tatsuo Shikama
    • Journal Title

      J. Power Sources

      Volume: 196巻 Pages: 4003-4011

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multi-path magnetic relaxation of Mono-Dysprosium(III)single-molecule magnet with extremely high barrier2011

    • Author(s)
      A. Watanabe, A. Yamashita, M. Nakano, T. Yamamura, T. Kajiwara
    • Journal Title

      Chem. Eur. J

      Volume: 17 Pages: 7428-7432

    • Related Report
      2012 Final Research Report
  • [Journal Article] Wheel-Shaped ErIIIZnII3 Single-Molecule Magnet: A Macrocyclic Approach to Designing Magnetic Anisotropy2011

    • Author(s)
      A. Yamashita, A. Watanabe, A. Akine, T. Nabeshima, M. Nakano, T. Yamamura,T. Kajiwara
    • Journal Title

      Angew. Chem

      Volume: 50 Pages: 4016-4019

    • Related Report
      2012 Final Research Report
  • [Journal Article] Magnetic anisotropy and spin-glass behavior in single crystalline U_2PdSi_32011

    • Author(s)
      D. X. Li, A. Kimura, Y. Haga, S. Nimori,T. Shikama
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: 23 Pages: 0760031-7

    • Related Report
      2012 Final Research Report
  • [Journal Article] Evidence for spin-glass state in nonmagnetic atom disorder compound Pr_2AgIn_32011

    • Author(s)
      D. X. Li, T. Yamamura, K. Yubuta, S. Nimori, Y. Haga, T. Shikama
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 320 Pages: 0120411-6

    • Related Report
      2012 Final Research Report
  • [Journal Article] Vanadium solid-salt battery : Solid state with two redox couples2011

    • Author(s)
      Tomoo Yamamura, Xiongwei Wu, Suguru Ohta, Kenji Shirasaki, Hiroki Sakuraba, Isamu Satoh, Tatsuo Shikama
    • Journal Title

      J.Power Sources

      Volume: 196 Pages: 4003-4011

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-Situ High-Energy X-Ray Diffuse-Scattering Study of the Phase Transition of Ni2MnGa Single Crystal under High Magnetic Field2010

    • Author(s)
      G. Wang, Y. D. Wang, Y. Ren, D X. Li, Y. D. Liu, P. K. Liaw
    • Journal Title

      Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science

      Volume: 41A Pages: 1269-1275

    • Related Report
      2012 Final Research Report
  • [Journal Article] Giant and anisotropic magnetocaloric effect in antiferromagnetic single crystalline DySb2010

    • Author(s)
      D. X. Li, S. Nimori, T. Shikama
    • Journal Title

      Solid State Communs

      Volume: 150 Pages: 1865-1868

    • Related Report
      2012 Final Research Report
  • [Presentation] Concentration dependence of " standard rate constant " of Vanadium redox couples: Concentration overpotential in VSSB2012

    • Author(s)
      T. Yamamura
    • Organizer
      IUPAC 8th Int. Conf. on Novel Mater. and Syn. (NMS- VIII) & 22nd Int. Symp. on Fine Chem. and Functional Polymer(招待講演)
    • Place of Presentation
      Xi'an, China
    • Year and Date
      2012-10-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 希土類パイロクロア型複合酸化物の水熱合成2012

    • Author(s)
      山村朝雄
    • Organizer
      原子力学会「2012年秋の大会」
    • Place of Presentation
      広島大学
    • Year and Date
      2012-09-20
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Proposal of vanadium solid-electrolyte battery2010

    • Author(s)
      T. Yamamura, X. Wu, I. Satoh, T. Shikama
    • Organizer
      218th ECS Meeting
    • Place of Presentation
      Las Vegas, NV, USA
    • Year and Date
      2010-10-12
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Concentration dependence of “standard rate constant” of Vanadium redox couples: Concentration overpotential in VSSB

    • Author(s)
      T. Yamamura
    • Organizer
      IUPAC 8th Int. Conf. on Novel Mater. and Syn. (NMS-VIII) & 22nd Int. Symp. on Fine Chem. and Functional Polymer
    • Place of Presentation
      Xi'an, China
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Patent(Industrial Property Rights)] バナジウムレドックス電池及びその運転方法2013

    • Inventor(s)
      山村朝雄,坂本清志,吉田茂樹
    • Industrial Property Rights Holder
      山村朝雄,坂本清志,吉田茂樹
    • Industrial Property Number
      2013-073613
    • Filing Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] バナジウムレドックス電池及びその運転方法2013

    • Inventor(s)
      山村朝雄,坂本清志,弦巻武久,吉田茂樹
    • Industrial Property Rights Holder
      山村朝雄,坂本清志,弦巻武久,吉田茂樹
    • Industrial Property Number
      2013-073614
    • Filing Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] バナジウムレドックス電池及びその運転方法2013

    • Inventor(s)
      山村朝雄, 坂本清志, 吉田茂樹
    • Industrial Property Rights Holder
      山村朝雄, 坂本清志, 吉田茂樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-073613
    • Filing Date
      2013-03-29
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] バナジウムレドックス電池及びその運転方法2013

    • Inventor(s)
      山村朝雄, 坂本清志, 弦巻武久, 吉田茂樹
    • Industrial Property Rights Holder
      山村朝雄, 坂本清志, 弦巻武久, 吉田茂樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-073614
    • Filing Date
      2013-03-29
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 固体活物質を含むバナジウム電池2012

    • Inventor(s)
      山村朝雄
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-074806
    • Filing Date
      2012-03-28
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 二次電池2012

    • Inventor(s)
      山村朝雄,佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-038057
    • Filing Date
      2012-02-23
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 二次電池2012

    • Inventor(s)
      山村朝雄,佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-007709
    • Filing Date
      2012-01-18
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 電池及びその方法2012

    • Inventor(s)
      山村朝雄,佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-007125
    • Filing Date
      2012-01-17
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 電池及びその方法2012

    • Inventor(s)
      山村朝雄, 佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-007125
    • Filing Date
      2012-01-17
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 二次電池2012

    • Inventor(s)
      山村朝雄, 佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-007709
    • Filing Date
      2012-01-18
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 二次電池2012

    • Inventor(s)
      山村朝雄, 佐藤伊佐務
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-038057
    • Filing Date
      2012-02-23
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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