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Development of high-performance termite control agent using supercritical carbon dioxide using supercritical carbon dioxide

Research Project

Project/Area Number 22510101
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionNiihama National College of Technology

Principal Investigator

TSUTSUMI Chikara  新居浜工業高等専門学校, 生物応用化学科, 准教授 (00300640)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords循環再生材料設計 / 環境適応型ポリマー / 徐放剤 / 忌避剤 / 超臨界二酸化炭素 / ポリ乳酸
Research Abstract

Preparation of the controlled-release materials was carried out using essential oil from Thujopsis dolabrata var. hondae and synthetic L-LA (L-lactide) random copolymers as a base material using scCO2. The contents of oil into poly(L-LA) random copolymers at 75% of L-LA were the highest. The pressure of essential oil impregnated into poly(L-LA) random copolymers was the highest at 14 MPa. In the influence of temperature on impregnation, the amount of essential oil increased with increasing temperature. The mechanical properties (tensile strength, elongation and elastic modulus) of the copolymers impregnated with essential oil were evaluated. The tensile strength and the elastic modulus of poly(L-LA) fell by impregnation of the oil. It turned out that mechanical properties differ in a tendency by polymer. In the degradation test, the residual oil by degradation of copolymer was proportional to degradation rate, and the earliest copolymer of degradation had an early reduction of residual oil.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (13 results)

All 2012 2011 2010

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (6 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Incorporation of L-lactide random copolymers with Japanese cypress oil (α-pinene) using supercritical carbon dioxide2012

    • Author(s)
      C. Tsutsumi, T. Hara, N. Fukukawa, K. Oro, K. Hata, Y. Nakayama, T. Shiono
    • Journal Title

      Green Chemistry

      Volume: Vol. 14, No. 4 Pages: 1211-1219

    • Related Report
      2012 Final Research Report
  • [Journal Article] 生分解性プラスチックを用いた環境適応型徐放剤2012

    • Author(s)
      堤主計
    • Journal Title

      コンバーテック

      Volume: No. 472 Pages: 113-116

    • NAID

      40019387499

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Incorporation of L-lactide random copolymers with Japanese cypress oil (α-pinene) using supercritical carbon dioxide2012

    • Author(s)
      Chikara Tsutsumi, Teruyuki Hara, Naohisa Fukukawa, Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      Green Chemistry

      Volume: 14 Issue: 4 Pages: 1211-1219

    • DOI

      10.1039/c2gc16546e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impregnation of poly(L-lactide- ran-cyclic carbonate) copolymers with useful compounds using supercritical carbon dioxide2011

    • Author(s)
      C. Tsutsumi, N. Fukukawa, J. Sakafuji, K. Oro, K. Hata, Y. Nakayama, T. Shiono
    • Journal Title

      Journal of Applied Polymer Science

      Volume: Vol. 121, Issue 3 Pages: 1431-1441

    • Related Report
      2012 Final Research Report
  • [Journal Article] Impregnation of poly (L-lactide-ran-cyclic carbonate) copolymers with useful compounds using supercritical carbon dioxide2011

    • Author(s)
      Chikara Tsutsumi, Naohisa Fukukawa, Jun Sakafuji, Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 121 Issue: 3 Pages: 1431-1441

    • DOI

      10.1002/app.33646

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 精油含浸によるポリ乳酸共重合体の機械的特性への影響2012

    • Author(s)
      堤主計、桑岡奈央、津々木亜美、原光志、中山祐正、塩野毅
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 生分解性プラスチックを用いた環境適応型徐放剤2012

    • Author(s)
      堤主計
    • Organizer
      グリーン・イノベーションEXPO2012
    • Place of Presentation
      東京国際展示場西展示棟
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 超臨界二酸化炭素流体下でのポリ乳酸共重合体への有用化合物の含浸に影響する諸因子の検討2011

    • Author(s)
      堤主計、原光志、上野結華、中山祐正、塩野毅
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2012 Final Research Report
  • [Presentation] 超臨界二酸化炭素流体下でのポリ乳酸共重合体への有用化合物の含浸に影響する諸因子の検討2011

    • Author(s)
      堤主計, 原光志, 上野結華, 中山祐正, 塩野毅
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学津島キャンパス
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 環境にやさしい高性能徐放剤2011

    • Author(s)
      堤主計
    • Organizer
      平成22年度高専-技科大新技術説明会
    • Place of Presentation
      科学技術振興機構 JSTホール
    • Year and Date
      2011-01-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 超臨界二酸化炭素によるL-ラクチド/環状カーボネートランダム共重合体への有用化合物の含浸に関する研究2010

    • Author(s)
      堤主計、福川直久、酒藤潤、尾路一幸、畑和明、中山祐正、塩野毅
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 徐放剤2011

    • Inventor(s)
      堤主計
    • Industrial Property Rights Holder
      (独)国立高等専門学校機構
    • Patent Publication Number
      2013-035779
    • Filing Date
      2011-08-08
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 徐放剤2011

    • Inventor(s)
      堤主計
    • Industrial Property Rights Holder
      (独)国立高等専門学校機構
    • Industrial Property Number
      2011-173093
    • Filing Date
      2011-08-08
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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