Well-ordered arranging of metal nanoparticles by low-energy ion beam irradiation and deposition

• Project/Area Number: 22510113
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Kyoto Institute of Technology
• Principal Investigator: TAKAHIRO Katsumi 京都工芸繊維大学, 工芸科学研究科, 教授 (80236348)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
• Keywords: 量子ビーム / ナノ材料 / 表面・界面 / パターン形成

Research Abstract

Well-ordered arrangements of Ag nanoparticles have been found for Ag-implanted SiO2 at depths corresponding to the projected range and end of range of Ag ions. X-ray photoelectron spectroscopy and x-ray diffraction confirm the stability of these Ag nanoparticles against oxidation and sulfidation when stored in ambient air for 19?21 months. For Ag nanoparticles deposited on SiO2, we utilized low-energy Ar ion irradiation and Ar plasma exposure to recover their plasmonic properties.

Research Products

• [Journal Article] Irradiation-induced brightening of tarnished Ag nanoparticles (2013)
  • Author(s): K. Takahiro, K. Ozaki, M. Wada, N.Terazawa, F. Nishiyama, M. Sasase
  • Journal Title: Nuclear Instruments and Methods in Physics Research B
  • Peer Reviewed
• [Journal Article] Irradiation-induced brightening of tarnished Ag nanoparticles (2013)
  • Author(s): K. Takahiro, K. Ozaki, M. Wada, N. Terazawa, F. Nishiyama, M. Sasase
  • Journal Title: Nuclear Instruments and Methods in Physics Research Volume: 未定 Pages: 218-221
  • DOI: 10.1016/j.nimb.2013.04.022
  • Peer Reviewed
• [Journal Article] Well-ordered arranging of Ag nanoparticles in SiO2/Si by ion implantation (2012)
  • Author(s): K. Takahiro, Y. Minakuchi, K. Kawaguchi, T.Isshiki, K. Nishio, M. Sasase
  • Journal Title: Applied Surface Science Volume: 258 Pages: 7322-7326
  • URL: http://dx.doi.org/10.1016/j.apsusc.2012.04.001
  • Peer Reviewed
• [Journal Article] Well-Ordered Arranging of Ag Nanoparticles in SiO_2/Si by Ion Implantation (2012)
  • Author(s): 高廣克己, 水口友貴, 川口和弘, 一色俊之, 西尾弘司、山本春也, 西山文隆
  • Journal Title: Applied Surface Science Volume: (印刷中) Issue: 19 Pages: 7322-7326
  • DOI: 10.1016/j.apsusc.2012.04.001
  • Peer Reviewed
• [Journal Article] Blue-shift and Narrowing of Plasmon Resonance Band of Silver Nanoparticles Exposed to Plasma (2011)
  • Author(s): K. Kawaguchi, M. Saito, K. Takahiro, S.Yamamoto, M. Yoshikawa
  • Journal Title: Plasmonics Volume: 6 Issue: 3 Pages: 535-539
  • DOI: 10.1007/s11468-011-9233-4
  • Peer Reviewed
• [Presentation] Irradiation-induced brightening of tarnished Ag nanoparticles (2012)
  • Author(s): K. Takahiro, K. Ozaki, M. Wada, N.Terazawa, F. Nishiyama, M. Sasase
  • Organizer: 25th International Conference on Atomic Collision in Solids
  • Place of Presentation: 京都大学
  • Year and Date: 2012-10-24
• [Presentation] Optical property of gold nanoparticles modified by plasma exposure and sputtering (2012)
  • Author(s): K. Kawaguchi,T. Sanari,K. Takahiro,S. Yamamoto,M. Yoshikawa,S. Nagata
  • Organizer: 18th International Conference on Ion Beam Modification of Materials
  • Place of Presentation: 中華人民共和国,チンタオ市
  • Year and Date: 2012-09-05
• [Presentation] 銀ナノ粒子表面に吸着した不純物のRBS/PIXE分析 (2012)
  • Author(s): 高廣克己,西山文隆,山本望鈴,佐成巧,寺澤昇久
  • Organizer: 第59回応用物理学関係連合講演会
  • Place of Presentation: 早稲田大学
  • Year and Date: 2012-03-16
• [Presentation] 銀ナノ粒子表面に吸着した不純物のRBS/PIXE分析 (2012)
  • Author(s): 高廣克己, 西山文隆, 山本望鈴, 佐成巧, 寺澤昇久
  • Organizer: 第59回応用物理学関係連合講演会
  • Place of Presentation: 東京都新宿区早稲田大学
  • Year and Date: 2012-03-16
• [Presentation] Optical property of gold nanoparticles modified by plasma exposure and sputtering (2012)
  • Author(s): K. Kawaguchi, T. Sanari, K. Takahiro, S. Yamamoto, M. Yoshikawa, S. Nagata
  • Organizer: 18th International Conference on Ion Beam Modifications of Materials
  • Place of Presentation: 中国・チンタオ市
• [Presentation] Formation of noble metal nanoparticles on damaged and undamaged graphite studied by photoelectron and Auger electron spectroscopies (2012)
  • Author(s): Y. Iwakiri, K. Moromoto, N. Terazawa, K. Takahiro, S. Nagata
  • Organizer: 25th International Conference on Atomic Collision in Solids
  • Place of Presentation: 京都市
• [Presentation] Irradiation-induced brightening of tarnished Ag nanoparticles (2012)
  • Author(s): K. Takahiro, K. Ozaki, M. Wada, N. Terazawa, F. Nishiyama, M. Sasase
  • Organizer: 25th International Conference on Atomic Collision in Solids
  • Place of Presentation: 京都市
• [Presentation] Formation of Noble Metal Nanoparticles on Damaged and Undamaged Graphite Studied by Photoelectron and Auger Electron Spectroscopies (2011)
  • Author(s): Y. Minakuchi,K. Morimoto,K. Takahiro,N. Terazawa,T. Isshiki,S. Nagata
  • Organizer: 6th International Symposium on Surface Science
  • Place of Presentation: 東京都 船堀ホール
  • Year and Date: 2011-12-12
• [Presentation] Formation of Noble Metal Nanoparticles on Damaged and Undamaged Graphite Studied by Photoelectron and Auger Electron Spectroscopies (2011)
  • Author(s): 水口友貴, 森本圭一, 高廣克己, 寺澤昇久, 一色俊之, 永田晋二
  • Organizer: 6th International Symposium on Surface Science
  • Place of Presentation: 東京都江戸川区船堀ホール
  • Year and Date: 2011-12-12
• [Presentation] Formation of noble metal nanoparticles on damaged and undamaged graphite studied by photoelectron and Auger electron spectroscopies (2011)
  • Author(s): Y. Iwakiri,K. Morimoto,N. Terazawa,K.Takahiro,S. Nagata
  • Organizer: 25th International Conference on Atomic Collision in Solids
  • Place of Presentation: 京都大学
  • Year and Date: 2011-10-23
• [Presentation] Well-Ordered Arranging of Ag Nano- particles in SiO2/Si by Ion Implantation (2011)
  • Author(s): K. Takahiro,Y. Minakuchi,K. Kawaguchi,T. Isshiki,K. Nishio,S. Yamamoto,F. Nishiyama
  • Organizer: 17th international Conference on Surface Modification of Materials by Ion Beams
  • Place of Presentation: 中華人民共和国 ハルピン市,ハルピン工業大学
  • Year and Date: 2011-09-15
• [Presentation] Optical Property of Gold Nanoparticles Modified by Plasma Exposure and Sputtering (2011)
  • Author(s): K. Kawaguchi,T. Sanari,K. Takahiro,S. Yamamoto,M. Yoshikawa,S. Nagata
  • Organizer: 17th international Conference on Surface Modification of Materials by Ion Beams
  • Place of Presentation: 中華人民共和国 ハルピン市,ハルピン工業大学
  • Year and Date: 2011-09-15
• [Presentation] Optical Property of Gold Nanoparticles Modified by Plasma Exposure and Sputtering (2011)
  • Author(s): 川口和弘, 佐成巧, 高廣克己, 山本春也, 吉川正人, 永田晋二
  • Organizer: 17th international Conference on Surface Modification of Materials by Ion Beams
  • Place of Presentation: 中華人民共和国ハルピン市ハルピン工業大学
  • Year and Date: 2011-09-15
• [Presentation] Well-Ordered Arranging of Ag Nanoparticles in SiO_2/Si by Ion Implantation (2011)
  • Author(s): 高廣克己, 水口友貴, 川口和弘, 一色俊之, 西尾弘司、山本春也, 西山文隆
  • Organizer: 17th international Conference on Surface Modification of Materials by Ion Beams
  • Place of Presentation: 中華人民共和国ハルピン市ハルピン工業大学
  • Year and Date: 2011-09-15
• [Presentation] イオン照射によるAuナノ粒子の光吸収スペクトルの変化 (2011)
  • Author(s): 川口和弘,高廣克己,山本春也,箱田照幸,吉川正人
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形大学
  • Year and Date: 2011-09-02
• [Presentation] イオン照射によるAuナノ粒子の光吸収スペクトルの変化 (2011)
  • Author(s): 川口和弘, 高廣克己, 山本春也, 箱田照幸, 吉川正人
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形市山形大学
  • Year and Date: 2011-09-02
• [Presentation] Sputtering and Plasma Exposure to Fabricate Gold Nanoparticles with Clean Surfaces (2011)
  • Author(s): K. Kawaguchi,T. Sanari,K. Takahiro,S. Yamamoto,M. Yoshikawa,S. Nagata
  • Organizer: International Symposium on Sputtering and Plasma Processes 2011
  • Place of Presentation: 京都リサーチパーク
  • Year and Date: 2011-07-06
• [Presentation] Sputtering and Plasma Exposure to Fabricate Gold Nanoparticles with Clean Surfaces (2011)
  • Author(s): 川口和弘, 佐成巧, 高廣克己, 山本春也, 吉川正人, 永田晋二
  • Organizer: International Symposium on Sputtering and Plasma Processes 2011
  • Place of Presentation: 京都市下京区京都リサーチパーク
  • Year and Date: 2011-07-06
• [Presentation] Effects of Ion Irradiation on Localized Surface Plasmon Resonance of Ag and Au nanoparticles (2010)
  • Author(s): K. Kawaguchi,K. Takahiro,S. Yamamoto,T. Hakoda,K. Yoshimura,M. Yoshikawa
  • Organizer: 日本MRS学術シンポジウム
  • Place of Presentation: 横浜市開港記念会館
  • Year and Date: 2010-12-22
• [Presentation] Effects of Ion Irradiation on Localized Surface Plasmon Resonance of Ag and Au nanoparticles (2010)
  • Author(s): 川口和弘, 高廣克己, 山本春也, 箱田照幸, 吉村公男, 吉川正人
  • Organizer: 日本MRS学術シンポジウム
  • Place of Presentation: 横浜市 横浜市開港記念会館
  • Year and Date: 2010-12-22
• [Presentation] Takahiro,"Au and Pt Nanoclusters Formed by Sputter-Deposition on Graphite with and without Ion Irradiation" (2010)
  • Author(s): K. Morimoto,M. Saito,K. Yasuda,S. Nagata,K. Takahiro
  • Organizer: The 6th International Workshop on Nanoscale Spectroscopy and Nano- technology
  • Place of Presentation: 神戸大学
  • Year and Date: 2010-10-27
• [Presentation] Au and Pt Nanoclusters Formed by Sputter-Deposition on Graphite with and without Ion Irradiation (2010)
  • Author(s): 森本圭一, 齋藤正裕, 安田賢司, 永田晋二, 高廣克己
  • Organizer: The 6^<th> International Workshop on Nano-scale Spectroscopy and Nanotechnology
  • Place of Presentation: 神戸市 神戸大学
  • Year and Date: 2010-10-27
• [Presentation] イオンビーム照射によるAgナノ粒子の光学特性変 (2010)
  • Author(s): 川口和弘,高廣克己,山本春也,箱田照幸,吉川正人
  • Organizer: 第71回応用物理学学術講演会
  • Place of Presentation: 長崎大学
  • Year and Date: 2010-09-16
• [Presentation] イオンビーム照射によるAgナノ粒子の光学特性変 (2010)
  • Author(s): 川口和弘, 高廣克己, 山本春也, 箱田照幸, 吉川正人
  • Organizer: 第71回応用物理学学術講演会
  • Place of Presentation: 長崎市 長崎大学
  • Year and Date: 2010-09-16