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Visible-light-operating photocatalysts of oxy-nitride semiconductor nanocrystallites synthesized by reactive pulsed excitation processing

Research Project

Project/Area Number 22510116
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionAnan National College of Technology

Principal Investigator

YOSHIDA Takehito  阿南工業高等専門学校, 機械工学科, 教授 (20370033)

Co-Investigator(Kenkyū-buntansha) UMEZU Ikurou  甲南大学, 理工学部, 教授 (30203582)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsナノ材料創製 / パルスレーザーアブレーション / 酸窒化物半導体 / 可視光応答化 / 光触媒
Research Abstract

We have tried nano-downsizing for photocatalyst particles using reactive pulsed laser ablation as a thermally non-equilibrium process, aiming at increase of photocatalytic activities. Wurtzite nanocrystalline GaN was successfully synthesized, even though inert N2 was introduced as a reactive background gas. In TiO2, It was clarified that crystal structures (rutile or anatase) as well as assembly morphologies of TiO2 nanocrystallites, can be controlled by varying process parameters (eg. gas pressure). The relation between the process parameters and the formed crystal structures was explained from the cooling process of the ablated species. Photocatalytic activities of the TiO2 nanocrystallites increased with recovering crystallinities, by rapid thermal annealing.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (37 results)

All 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 6 results) Presentation (23 results) Remarks (3 results)

  • [Journal Article] Non-equilibrium growth processes of porous TiO2 nanocrystal-films during pulsed laser ablation2013

    • Author(s)
      I. Umezu, N. Yagi, A. Sugimura and T. Yoshida
    • Journal Title

      Proceedings of Materials Research Society

      Volume: Vol. 1497

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Questionnaire research and development of self-motivating education method using intellectual property rights2012

    • Author(s)
      Y. Deguchi, E. Morimoto, T. Yoshida, A. Shimada, N. Akamatsu, H. Maei, N. Shiokawa, H. Nakanishi, and T. Kouda,
    • Journal Title

      Int. J. of Engineering Pedagogy

      Volume: Vol. 1 Pages: 82-84

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Questionnaire research and development of self-Motivating education method using intellectual property rights2012

    • Author(s)
      Y. Deguchi, E. Morimoto, T. Yoshida, A. Shimada, N. Akamatsu, H. Maei, N. Shiokawa, H. Nakanishi, and T. Kouda
    • Journal Title

      Int. J. of Engineering Pedagogy

      Volume: 2 Pages: 9-12

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Questionnaire research and development of self-motivating education method using intellectual property rights2012

    • Author(s)
      Y. Deguchi, E. Morimoto, T. Yoshida, A. Shimada, N. Akamatsu, H. Maei, N. Shiokawa, H. Nakanishi, and T. Kouda
    • Journal Title

      Proceedings of IEEE International Conference on Teaching Assessment and Learning for Engineering

      Volume: 1 Pages: 82-84

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of GaN nanocrystallites by pulsed laser ablation in pure nitrogen background gases2011

    • Author(s)
      T. Yoshida, S. Kakumoto, A. Sugimura and I. Umezu
    • Journal Title

      Applied Physics A

      Volume: Vol. 96 Pages: 907-911

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of GaN nanocrystallites by pulsed laser ablation in pure nitrogen background gases2011

    • Author(s)
      T.Yoshida, S.Kakumoto, A.Sugimura, I.Umezu
    • Journal Title

      Applied Physics A : Materials Science & Processing

      Volume: 96 Pages: 907-911

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] evelopment of self-motivating education method using intellectual property rights2011

    • Author(s)
      Y.Deguchi, T.Yoshida, A.Shimada, N.Akamatsu, H.Maei
    • Journal Title

      Proc.of 2^<nd> Asian Conference on Engineering Education

      Pages: 173-174

    • Related Report
      2011 Annual Research Report
  • [Journal Article] 反応性パルスレーザーアブレーション法によるInTaO4系ナノ構造体の作製とその光触媒特性2010

    • Author(s)
      豊山博一,吉田岳人,梅津郁朗,杉村陽
    • Journal Title

      Mem. Konan Univ., Sci. & Eng. Ser

      Volume: Vol. 57 Pages: 1-15

    • NAID

      110008429744

    • Related Report
      2012 Final Research Report
  • [Journal Article] YAGレーザーを用いたパルスレーザーメルティング法による硫黄を過飽和ドープした結晶シリコンの作成2010

    • Author(s)
      中川将, 香野淳, J. M. Warrender, J. S. Williams, S. Charnvanichborikarn, 内藤宗幸, 吉田岳人, M. J. Aziz, 杉村陽, 梅津郁朗
    • Journal Title

      Mem. Konan Univ., Sci. & Eng. Ser

      Volume: Vol. 57 Pages: 29-34

    • NAID

      110008429760

    • Related Report
      2012 Final Research Report
  • [Journal Article] 反応性パルスレーザーアブレーション法によるInTaO_4系ナノ構造体の作製とその光触媒特性2010

    • Author(s)
      豊山博一, 吉田岳人, 梅津郁朗, 杉村陽
    • Journal Title

      Mem.Konan Univ., Sci. & Eng.Ser.

      Volume: 57 Pages: 1-15

    • Related Report
      2010 Annual Research Report
  • [Journal Article] YAGレーザーを用いたパルスレーザーメルティング法によう硫黄を過飽和ドープした結晶シリコンの作成2010

    • Author(s)
      中川将, 香野淳, J.M.Warrender, J.S.Williams, S.Charnvanich borikarn, 内藤宗幸, 吉田岳人, M.J.Aziz, 杉村陽, 梅津郁朗
    • Journal Title

      Mem.Konan Univ., Sci. & Eng.Ser.

      Volume: 57 Pages: 29-34

    • Related Report
      2010 Annual Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるNiOyナノ結晶堆積膜の構造と光学特性2013

    • Author(s)
      吉田 岳人, 廣田 政人, 田中 潤, 杉村 陽, 梅津 郁朗
    • Organizer
      第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川県,厚木市
    • Related Report
      2012 Annual Research Report
  • [Presentation] ガス中レーザーアブレーション過程でのナノ結晶集合体の階層構造形成2013

    • Author(s)
      梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川県,厚木市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Non-equilibrium growth processes of porous TiO2 nanocrystal-films during pulsed laser ablation2012

    • Author(s)
      I. Umezu, N. Yagi, A. Sugimura and T. Yoshida
    • Organizer
      Materials Research Society 2012 fall meeting
    • Place of Presentation
      Boston NY,USA
    • Year and Date
      2012-11-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Controlling photoctalytic activities and crystal structures of TiO2 nanoparticles synthesized by reactive pulsed laser ablation2012

    • Author(s)
      T. Yoshida, N. Yagi, R. Nakagou, N. Kondou, A.Sugimura and I. Umezu
    • Organizer
      8th International Conference on Photo-Excited Process and Applications
    • Place of Presentation
      Rochester NY, USA
    • Year and Date
      2012-08-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるTiO2 ナノ粒子の結晶性制御と光触媒機能(招待講演)2012

    • Author(s)
      吉田 岳人, 八木信賢, 中郷力, 杉村陽, 梅津郁朗
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京都,早稲田大学
    • Year and Date
      2012-03-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるTiO_2ナノ粒子の結晶性制御と光触媒機能2012

    • Author(s)
      吉田岳人, 八木信賢, 中郷力, 杉村陽, 梅津郁朗
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京都,早稲田大学(招待講演)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Controlling photoctalytic activities and crystal structures of TiO2 nanoparticels synthesized by reactive pulsed laser ablation2012

    • Author(s)
      T. Yoshida, N. Yagi, R. Nakagou, N. Kondou, A. Sugimura and I. Umezu
    • Organizer
      8th International Conference on Photo-Excited Process and Applications
    • Place of Presentation
      Rochester NY, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Questionnaire research and development of self-motivating education method using intellectual property rights2012

    • Author(s)
      Y. Deguchi, E. Morimoto, T. Yoshida, A. Shimada, N. Akamatsu, H. Maei, N. Shiokawa, H. Nakanishi, and T. Kouda
    • Organizer
      IEEE International Conference on Teaching Assessment and Learning for Engineering
    • Place of Presentation
      Hong Kong
    • Related Report
      2012 Annual Research Report
  • [Presentation] Non-equilibrium growth grocesses of porous TiO2 nanocrystal-films during pulsed laser ablation2012

    • Author(s)
      I. Umezu1, N. Yagi1, A. Sugimura1 and T. Yoshida
    • Organizer
      Materials Research Society 2012 fall meeting
    • Place of Presentation
      Boston NY,USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるTiO2ナノ構造体の光触媒活性制御2012

    • Author(s)
      吉田 岳人, 八木 信賢, 中郷 力, 近藤 雅斗, 杉村 陽, 梅津 郁朗
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛県,松山市
    • Related Report
      2012 Annual Research Report
  • [Presentation] 地域連携を踏まえた知財活用創造力創出教育手法の推進2012

    • Author(s)
      出口祥啓, 森本恵美,吉田岳人, 島田章伸, 前井宏之, 赤松尚子, 塩川信明, 中西博行, 香田常克
    • Organizer
      日本知財学会 第10回年次学術研究発表会
    • Place of Presentation
      大阪府,守口市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Controlling crystal structures and morphologies of TiO2 nanoparticels deposited by reactive pulsed laser ablation for photocatalyst applications2011

    • Author(s)
      T. Yoshida, N. Yagi, A. Sugimura, and I. Umezu
    • Organizer
      11th International Conference on Laser Ablation
    • Place of Presentation
      Playa del Carmen, Mexico
    • Year and Date
      2011-11-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Controlling for crystal structures and morphologies of TiO_2 nanoparticels deposited by reactive pulsed laser ablation for photocatalyst applications2011

    • Author(s)
      T.Yoshida, N.Yagi, A.Sugimura, I.Umezu
    • Organizer
      1th International Conference on Laser Ablation
    • Place of Presentation
      Playa del Carmen, Mexico
    • Year and Date
      2011-11-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of self-motivating education method using intellectual property rights2011

    • Author(s)
      Y.Deguchi, T.Yoshida, A.Shimada, N.Akamatsu, H.Maei
    • Organizer
      2^<nd> Asian Conference on Engineering Education (ACEE2011)-Challenges and Innovations in Engineering Education-
    • Place of Presentation
      徳島県,徳島大学
    • Year and Date
      2011-10-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 酸素ガス中のパルスレーザーアブレーション法(PLA)によるTiO_2ナノ結晶構造の制御2011

    • Author(s)
      八木信賢, 梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形県,山形大学
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるIn_<0.9>Ni_<0.1>TaO_4とNiOxの複合ナノ構造体の作製2011

    • Author(s)
      松本啓志, 豊山博一, 田中潤, 梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形県,山形大学
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光触媒ナノ結晶の反応性ガス中パルスレーザーアブレーションによる創製(招待講演)2011

    • Author(s)
      吉田岳人, 梅津郁朗, 杉村陽
    • Organizer
      第58回応用物理学関係連合講演会,シンポジウム:グリーンイノベーションを実現するレーザープロセッシング技術
    • Place of Presentation
      神奈川県,神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 光触媒ナノ結晶の反応性ガス中パルスレーザーアブレーションによる創製2011

    • Author(s)
      吉田岳人, 梅津郁朗, 杉村陽
    • Organizer
      第58回応用物理学関係連合講演会,シンポジウム:グリーンイノベーションを実現するレーザープロセッシング技術
    • Place of Presentation
      神奈川県,神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 酸素ガス中のパルスレーザーアブレーション法(PLA)によるTiO_2ナノ結晶構造の制御2011

    • Author(s)
      八木信賢, 梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川県,神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 反応性パルスレーザーアブレーション法によるGaNナノ結晶の作製II2010

    • Author(s)
      角本宗一郎, 梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎県,長崎大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 酸素ガス中のパルスレーザーアブレーション法(PLA)によるTiO_2ナノ結晶集合体構造の制御2010

    • Author(s)
      八木信賢, 梅津郁朗, 杉村陽, 吉田岳人
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎県,長崎大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] ガス中レーザーアブレーション-薄膜・ナノ粒子から酸窒化物光触媒への道-2010

    • Author(s)
      吉田岳人
    • Organizer
      甲南大学理工学部物理学科ガス中で爆発的に膨張する原子種の流体的挙動とナノ結晶生成に関する小研究会
    • Place of Presentation
      神戸市,甲南大学
    • Year and Date
      2010-08-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of gallium nitride nanocrystallites by pulsed laser ablation in pure nitrogen background gases2010

    • Author(s)
      T. Yoshida, S. Kakumoto, A. Sugimura and I. Umezu
    • Organizer
      7th International Conference on Photo-Excited Process and Applications
    • Place of Presentation
      Copenhagen, Denmark
    • Year and Date
      2010-08-20
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Remarks] 阿南高専 研究者総覧 機械工学科 吉田岳人

    • URL

      http://www1.anan-nct.ac.jp/souran/takehito

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www01.anan-nct.ac.jp/souran/takehito

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www01.anan-nct.ac.jp/souran/takehito

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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