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Theory of X-ray Absorption Magnetic Circular Dichroism and Resonant X-ray Emission Spectra for Mixed Valence Rare-earth Compounds in High Magnetic Fields

Research Project

Project/Area Number 22540341
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

KOTANI Akio  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 共同研究員 (90029504)

Co-Investigator(Kenkyū-buntansha) KOIDE Tsuneharu  大学共同利用機関法人高エネルギー加速器研究機構, 加速器科学支援センター, シニアフェロー (10150012)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords混合原子価 / 希土類 / 強磁場 / X線吸収 / 磁気円二色性 / 共鳴X線発光 / 希土類化合物 / X線吸収 / 共鳴X線発光
Research Abstract

We constructed the theory of X-ray absorption magnetic circular dichroism (XMCD) of mixed-valence rare-earth compounds in high magnetic field with the impurity Anderson model, and analyzed experimental data of XMCD spectra measured by pulsed high magnetic field which was developed recently in Japan. We first analyzed the field dependence of hard X-ray XMCD spectra by electric dipole transition at the Yb L_<2,3>edges of YbInCu_4,taking into account the field-induced valence transition of the first order, and then succeeded in assigning the XMCD by the electric quadrupole transition for YbAgCu_4. More recently, we analyzed successfully the soft X-ray XMCD experimental data at the Eu M_<4,5>edges of EuNi_2(Si_<0.18>Ge_<0.82>)_2. Finally, we made some calculations of resonant X-ray emission spectroscopy (RXES), aiming at future RXES experiments in high magnetic fields.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (33 results)

All 2013 2012 2011 2010 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (12 results)

  • [Journal Article] Theory of Electric Quadrupole Transition in the XMCD Spectra at the Yb L_3Edge of Mixed Valence Yb Compounds in High Magnetic Fields2013

    • Author(s)
      小谷章雄
    • Journal Title

      J. Phys.: Conf. Series

      Volume: Vol.430

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Experimental Valence and Magnetization Data around the Fieldand Temperature-Induced Valence Transitions of EuNi_2(Si_<0.18>Ge_<0.82>)_2: Unified Interpretation for the Resultsfrom Soft X-ray Absorption2013

    • Author(s)
      小谷章雄 、 中 村 哲 也
    • Journal Title

      Its Magnetic Circular Dichroism, and Magnetostatic Measurements 、J. Phys. Soc. Jpn.

      Volume: Vol.82

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure2013

    • Author(s)
      I. Jarrige
    • Journal Title

      Physical Review B

      Volume: VOL. 87 Issue: 11

    • DOI

      10.1103/physrevb.87.115107

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Experimental Valence and Magnetization Data around the Field- and Temperature-Induced Valence Transitions of EuNi2(Si0.18Ge0.82)2 : Unified Interpretation for the Results from Soft X-ray Absorption, Its Magnetic Circular Dichroism, and Magnetostatic Measurements2013

    • Author(s)
      小谷章雄
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: VOL. 82 Issue: 4 Pages: 044710-044710

    • DOI

      10.7566/jpsj.82.044710

    • NAID

      210000132523

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theory of Electric Quadrupole Transition in the XMCD Spectra at the Yb L3 Edge of Mixed Valence Yb Compounds in High Magnetic Fields2013

    • Author(s)
      小谷章雄
    • Journal Title

      Journal of Physics: Conference Series

      Volume: VOL. 430 Pages: 012002-012002

    • DOI

      10.1088/1742-6596/430/1/012002

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft-X-ray Magnetic Circular Dichroism under Pulsed High Magnetic Fields at Eu M_<4,5>Edges of Mixed Valence Compound EuNi_2(Si_<0.18>Ge_<0.82>)_22012

    • Author(s)
      中村哲也、広野等子、木下豊彦、鳴海康雄、林美咲、野尻浩之、光田暁弘、和田裕文、児玉謙司、金道浩一、小谷章雄
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: Vol.81

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Magnetic-Field X-ray Absorption and Magnetic Circular Dichroism Spectroscopy in the Mixed-Valent Compound YbAgCu_42012

    • Author(s)
      中村俊幸、松田康弘、J.-L.Her、金道浩一、道村真司、稲見俊哉、水牧仁一朗、河村直己、鈴木基寛、B.Chen、H.Ohta、吉村一良、 小谷章雄
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: Vol.81

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical analysis of X-ray magnetic circular dichroism at the Yb L_<2,3>absorption edges of YbInCu_4in high magnetic fields around the field-induced valence transition2012

    • Author(s)
      小谷章雄
    • Journal Title

      Eur.Phys. J. B

      Volume: Vol.85

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Single Impurity Anderson Model versus Density Functional Theory for Describing Ce L_3X-Ray Absorption Spectra of CeFe_2: Resolution of a Recent Controversy2012

    • Author(s)
      小谷章雄、K.O.Kvashnina、P.Glatzel、J.C.Parlebas 、 G.Schmerber
    • Journal Title

      Phys. Rev. Lett

      Volume: Vol.108

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft-X-ray Magnetic Circular Dichroism under Pulsed High Magnetic Fields at Eu M4,5 Edges of Mixed Valence Compound EuNi2(Si0.18Ge0.82)22012

    • Author(s)
      中村哲也
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: VOL. 81 Issue: 10 Pages: 103705-103705

    • DOI

      10.1143/jpsj.81.103705

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Magnetic Field X-ray Absorption and Magnetic Circular Dichroism Spectroscopy in the Mixed-Valent Compound YbAgCu_42012

    • Author(s)
      Toshiyuki Nakamura, Yasuhiro H. Matsuda, Jim-Long Her, Koichi Kindo, Shinji Michimura, Toshiya Inami, Masaichiro Mizumaki, Naomi Kawamura, Motohiro Suzuki, Bin Chen, Hiroto Ohta, Kazuyoshi Yoshimura, Akio Kotani
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: Vol. 81 Issue: 11 Pages: 114702-114702

    • DOI

      10.1143/jpsj.81.114702

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single impurity Anderson model versus density functional theory for describing Ce L_3 x-ray absorption spectra of CeFe_2 : Resolution of a recent controversy2012

    • Author(s)
      小谷章雄, 他4名
    • Journal Title

      Physical Review Letters

      Volume: VOL.108 Issue: 3

    • DOI

      10.1103/physrevlett.108.036403

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical analysis of x-ray magnetic circular dichroism at the Yb L_<2,3> absorption edges of YbInCu_4 in high magnetic fields around the field-induced valence transition2012

    • Author(s)
      小谷章雄
    • Journal Title

      European Physical Journal B

      Volume: VOL.85(掲載確定)(未定) Issue: 1

    • DOI

      10.1140/epjb/e2011-20577-y

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theory of Low Energy Excitations in Resonant Inelastic X-ray Scattering for Rare-Earth Systems: Yb Compounds as Typical Examples2011

    • Author(s)
      小谷章雄
    • Journal Title

      Phys. Rev. B

      Volume: Vol.83

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Field Effect on X-ray Magnetic Circular Dichroism Spectra at the L_<2,3>Absorption Edges of Mixed-Valence Ce and Yb Compounds in High Magnetic Fields2011

    • Author(s)
      小谷章雄
    • Journal Title

      Eur. Phys. J. B

      Volume: Vol.81 Pages: 49-63

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theory of low energy excitations in resonant inelastic x-ray scattering for rare-earth systems : Yb compounds as typical examples2011

    • Author(s)
      小谷章雄
    • Journal Title

      Physical Review B

      Volume: VOL.83 Issue: 16

    • DOI

      10.1103/physrevb.83.165126

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge-Transfer Satellite in Ce@C_<82> Probed by Resonant X-ray Emission Spectroscopy2011

    • Author(s)
      山岡人志、小谷章雄, 他6名
    • Journal Title

      Journal of Physical Society of Japan

      Volume: VOL.80

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Field Effect on X-ray Magnetic Circular Dichroism Spectra at the L_<2,3> Absorption Edges of Mixed-Valence Ce and Yb Compounds in High Magnetic Fields2011

    • Author(s)
      小谷章雄
    • Journal Title

      European Physical Journal B

      Volume: (掲載決定)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theory of high-magnetic-field XAS and XMCD spectra at the Yb L and M edges around the field -induced valence transition of YbInCu_42010

    • Author(s)
      小谷章雄
    • Journal Title

      J. Electron Spectrosc. Relat. Phenom.

      Volume: Vol.181 Pages: 168-173

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface structure of half-metallic Heusler alloy Co_2MnSi thin films facing an MnO tunnel barrier determined by x-ray magnetic circular dichroism2010

    • Author(s)
      齊藤敏明、片山利一、石川貴之、山本眞史、朝倉大輔、小出常晴、三浦良雄、白井正文
    • Journal Title

      Phys. Rev. B

      Volume: Vol.81

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theory of high-magnetic-field XAS and XMCD spectra at the Yb L and Medges around the field-induced valence transition of YbInCu_42010

    • Author(s)
      小谷章雄
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: VOL.181 Pages: 168-172

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] YbInCu_4 と YbAgCu_4 の Yb L_3 吸収端の強磁場 XMCD における電気四重極子遷移2013

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] ベクトル型超伝導マグネットを用いた強磁性薄膜 La_<0.6>Sr_<0.4>MnO_3 の角度依存 XMCD2012

    • Author(s)
      芝田悟朗、石神啓介、原野貴幸、高橋文雄、吉松公平、門野利治、藤森淳、小出常晴、組頭広志、古瀬光穂、淵野修一郎、岡野眞、藤平潤一、内田公、渡辺和訓、藤平誠一、藤平秀幸
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-09-18
    • Related Report
      2012 Final Research Report
  • [Presentation] CeFe_2 の Ce L_3 端X線吸収および共鳴X線発光スペクトルにおける Ce5d バンド状態密度と内殻正孔の効果2012

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-09-18
    • Related Report
      2012 Final Research Report
  • [Presentation] 強磁場下の YbAgCu_4の Yb L_3 吸収端 XMCD における電気四重極子遷移2012

    • Author(s)
      小谷章雄、松田康弘
    • Organizer
      日本物理学会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] パルス強磁場による EuNi_2(Si_<0.18>Ge_<0.82>)_2 の軟X線吸収 MCD 実験の理論解析2011

    • Author(s)
      小谷章雄、中村哲也、鳴海康雄、林美咲、光田暁弘、広野等子、児玉謙司、森岡貴之、木下豊彦、和田裕文、金道浩一、野尻浩之
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] パルス強磁場によるEuNi_2(Si_<0.18>Ge_<0.82>)_2の軟X線吸収MCD実験の理論解析2011

    • Author(s)
      小谷章雄, 他11名
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Theory of Low Energy Excitations in Resonant Inelastic X-ray Scattering for Rare Earth Systems2010

    • Author(s)
      小谷章雄
    • Organizer
      7th International Conference on Inelastic X-ray Scattering
    • Place of Presentation
      Grenoble
    • Year and Date
      2010-10-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 混合原子価Ce化合物のL端励起共鳴X線発光における新しい分光データとその理論2010

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] A New Method of Directly Determining the Core-hole Effect in the Ce L3XAS of Mixed Valence Ce Compounds --- An Application of Resonant X-ray Emission Spectroscopy2010

    • Author(s)
      小谷章雄、K.O.Kvashnina、S.M.Butorin、P.Glatzel
    • Organizer
      37th Inter-national Conference on Vacuum Ultra-violet and X-ray Physics
    • Place of Presentation
      Vancouver
    • Year and Date
      2010-07-12
    • Related Report
      2012 Final Research Report
  • [Presentation] YbInCu_4 の磁場誘起価数転移におけるX線吸収磁気円二色性と共鳴X線非弾性散乱の理論2010

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-21
    • Related Report
      2012 Final Research Report
  • [Presentation] CeFe2のCe L3端X線吸収および共鳴X線発光スペクトルにおけるCe5dバンド状態密度と内殻正孔の効果

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] YbInCu4とYbAgCu4のYb L3吸収端の強磁場XMCDにおける電気四重極子遷移

    • Author(s)
      小谷章雄
    • Organizer
      日本物理学会
    • Place of Presentation
      広島大学(広島県)
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2020-05-15  

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