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A probable scenario of the liquid-liquid phase transition in tin tetraiodide

Research Project

Project/Area Number 22540392
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Mathematical physics/Fundamental condensed matter physics
Research InstitutionEhime University

Principal Investigator

FUCHIZAKI Kazuhiro  愛媛大学, 大学院・理工学研究科, 教授 (10243883)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsポリアモルフィズム / 液体 / 非晶質 / 相転移 / 臨界点 / ヨウ化錫
Research Abstract

The present study has begun to primarily elucidate a probable transition scenario between the two liquid states discovered intin tetraiodide. In the period of research, not only this purpose was achieved, but also the following two important findings were unvalued: i) our experimental study revealed that the liquid states are indeed thermodynamically stable phases characterizedby different densities, and ii) the polyamorphism observed in tin tetraiodide was theoretically identified with the one found in water and its related systems characterized bythe open tetrahedral network structure. Although the liquid-liquid critical point ofwater is considered to be located below the homogeneous nucleation temperature, and istherefore never reached, the critical point in liquid tin tetraiodide lies in an experimentally accessible region. The latter fact then opens up a new path toward a new type of critical phenomena.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (43 results)

All 2013 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (35 results)

  • [Journal Article] Characteristic Densities of Low- and High-Pressure Liquid SnI_42013

    • Author(s)
      K. Fuchizaki, N. Hamaya, Y. Katayama
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82巻 Issue: 3 Pages: 033003-033003

    • DOI

      10.7566/jpsj.82.033003

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sublimation of the Modified Lennard-Jones System2013

    • Author(s)
      K. Fuchizaki, Y. Asano
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82巻

    • NAID

      210000132431

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase diagram of the modified Lennard-Jones system2012

    • Author(s)
      Y. Asano, K. Fuchizaki
    • Journal Title

      J. Chem. Phys

      Volume: 137巻 Issue: 17

    • DOI

      10.1063/1.4764855

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Probable scenario of the liquid-liquid phase transition of SnI_42011

    • Author(s)
      K. Fuchizaki, N. Hamaya, T. Hase, Y. Katayama
    • Journal Title

      J. Chem. Phys.

      Volume: 137巻

    • URL

      http://dx.doi.org/10.1063/1.3637038

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Equation of state for the low-pressure crystalline phase of SnI42011

    • Author(s)
      K. Fuchizaki, N. Hamaya
    • Journal Title

      Phys. Rev. B

      Volume: 84巻 Issue: 14

    • DOI

      10.1103/physrevb.84.144105

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Note on Calculation of the Pressure in a Gibbs Ensemble2011

    • Author(s)
      K. Fuchizaki
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 80巻 Issue: 2 Pages: 024003-024003

    • DOI

      10.1143/jpsj.80.024003

    • NAID

      40018273856

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Communication : Probable scenario of the liquid-liquid phase transition of SnI42011

    • Author(s)
      K.Fuchizaki
    • Journal Title

      J.Chem.Phys

      Volume: 135 Issue: 9

    • DOI

      10.1063/1.3637038

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Note on Calculation of the Pressure in a Gibbs Ensemble2011

    • Author(s)
      Kazuhiro Fuchizaki
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 80

    • NAID

      40018273856

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 変形 Lennard-Jones 系の相図2013

    • Author(s)
      浅野優太, 渕崎員弘
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] ねじれ角で接合した結晶界面における幾何学とエネルギー,および 2 層グラフェンへの応用2013

    • Author(s)
      三谷尚, 渕崎員弘
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-28
    • Related Report
      2012 Final Research Report
  • [Presentation] GeI_4の融解曲線2013

    • Author(s)
      渕崎員弘, 浜谷望
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] GeI_4の融解曲線2012

    • Author(s)
      渕崎員弘, 浜谷望
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2012-11-08
    • Related Report
      2012 Final Research Report
  • [Presentation] SnI_4--A Substitute for Examining the Water-Type Polyamorphism2012

    • Author(s)
      K. Fuchizaki
    • Organizer
      IUCrHP 2012
    • Place of Presentation
      HOTEL LAKE VIEW MITO, Mito, Japan
    • Year and Date
      2012-09-25
    • Related Report
      2012 Final Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズム VII2012

    • Author(s)
      渕崎員弘, 奥出悠花, 浜谷望
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      横浜国大
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Application of the Generalized Ewald Method to Evaluation of Intermolecular Interactions in Molecular Systems2012

    • Author(s)
      K. Fuchizaki
    • Organizer
      MOLMAT 2012
    • Place of Presentation
      Auditorio Axa, Barcelona, Spain
    • Year and Date
      2012-07-04
    • Related Report
      2012 Final Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズム VI2012

    • Author(s)
      渕崎員弘, 浜谷望, 片山芳則
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学(兵庫県)
    • Year and Date
      2012-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズムVI2012

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学(兵庫県)
    • Year and Date
      2012-03-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] ヨウ化錫液相間転移の存在可能性2012

    • Author(s)
      渕崎員弘
    • Organizer
      第29回PFシンポジウム
    • Place of Presentation
      エポカルつくば(茨城県)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高温・高圧下でのヨウ化錫液体の放射光X 線その場観察法とヨウ化錫低圧結晶相の状態方程式2011

    • Author(s)
      渕崎員弘, 浜谷望
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2011-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] 高温・高圧下でのヨウ化錫液体の放射光X線その場観察法とヨウ化錫低圧結晶相の状態方程式2011

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Is There a Phase Transition between the Two Liquid States in Tin Tetraiodide?2011

    • Author(s)
      K. Fuchizaki, N. Hamaya, Y. Katayama, T. Kikegawa
    • Organizer
      IUCr2011
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2011-08-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Is There a Phase Transition between the Two Liquid States in Tin Tetraiodide?2011

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      IUCr2011
    • Place of Presentation
      Madrid (Spain)
    • Year and Date
      2011-08-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズム V2011

    • Author(s)
      渕崎員弘, 長谷貴樹, 浜谷望, 片山芳則, 亀卦川卓美
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学(新潟県)
    • Year and Date
      2011-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズムV2011

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学(新潟県)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Possible existence of a higher-pressure liquid state in SnI_42010

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      IMSS Symposium 2010
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2010-12-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズム IV2010

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-25
    • Related Report
      2012 Final Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズムIV2010

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Possible polyamorphic relationship between liquid and crystalline phase in SnI_42010

    • Author(s)
      K. Fuchizaki
    • Organizer
      26th European Crystallographic Meeting
    • Place of Presentation
      Darmstadt, Germany
    • Year and Date
      2010-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] Possible polyamorphic relationship between liquid and crystalline phase in SnI_42010

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      26^<th> European Crystallographic Meeting
    • Place of Presentation
      Darmstadt(Germany)
    • Year and Date
      2010-09-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] A possible transition scenario between the two liquid phases in SnI42010

    • Author(s)
      K. Fuchizaki
    • Organizer
      STATPHYS 24
    • Place of Presentation
      Cairns Australia
    • Year and Date
      2010-07-19
    • Related Report
      2012 Final Research Report
  • [Presentation] A possible transition scenario between the two liquid phases in SnI_42010

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      STATPHYS 24
    • Place of Presentation
      Cairns(Australia)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of the Generalized Ewald Method to Evaluation of Intermolecular Interactions in Molecular Systems

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      MOLMAT 2012
    • Place of Presentation
      Auditorio Axa, Barcelona, Spain
    • Related Report
      2012 Annual Research Report
  • [Presentation] ヨウ化錫のポリアモルフィズムVII

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      横浜国大
    • Related Report
      2012 Annual Research Report
  • [Presentation] SnI4 – A Substitute for Examining the Water-Type Polyamorphism

    • Author(s)
      Kazuhiro Fuchizaki
    • Organizer
      IUCrHP 2012
    • Place of Presentation
      HOTEL LAKE VIEW MITO, Mito, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Phase transition of the modified Lennard-Jones system

    • Author(s)
      Yuta Asano
    • Organizer
      IUCrHP 2012
    • Place of Presentation
      HOTEL LAKE VIEW MITO, Mito, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Intrinsic features of the Lennard-Jones system under pressures

    • Author(s)
      Yuta Asano
    • Organizer
      IUCrHP 2012
    • Place of Presentation
      HOTEL LAKE VIEW MITO, Mito, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] GeI4の融解曲線

    • Author(s)
      渕崎員弘
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二ヨウ化スズの融解曲線と液体構造

    • Author(s)
      奥出悠花
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二ヨウ化スズの温度圧力相図

    • Author(s)
      河原玲奈
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] KEK-AR NE7AでのX線吸収による液体密度測定の試み

    • Author(s)
      渕崎員弘
    • Organizer
      物構研サイエンスフェスタ
    • Place of Presentation
      エポカルつくば
    • Related Report
      2012 Annual Research Report
  • [Presentation] GeI4の融解曲線

    • Author(s)
      渕崎員弘
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] ねじれ角で接合した結晶界面における幾何学とエネルギー,および2層グラフェンへの応用

    • Author(s)
      三谷尚
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 変形Lennard-Jones系の相図

    • Author(s)
      浅野優太
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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