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Low energy indium ion beam injection for the development of novel catalysts

Research Project

Project/Area Number 22540506
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Plasma science
Research InstitutionOsaka University

Principal Investigator

YOSHIMURA Satoru  大阪大学, 大学院・工学研究科, 准教授 (40294029)

Co-Investigator(Renkei-kenkyūsha) YASUDA Makoto  大阪大学, 大学院・工学研究科, 准教授 (40273601)
KIUCHI Masato  独立行政法人産業技術総合研究所, ユビキタスエネルギー研究部門, 主任研究員 (50356862)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsインジウム / イオン / 触媒化学 / 触媒 / イオンビーム
Research Abstract

Chemical substances that contain indium (In) and silicon (Si) in close proximity are known to catalyze certain organic chemical reactions. We have demonstrated that In implanted SiO_2thin films, formed under some specific conditions, contain In atoms on or near the substrate surface in close proximity with Si atoms and catalyze a reaction of benzhydrol with acetylacetone. In this study, dependence of the catalytic ability of an In implanted SiO_2thin film on the ion incident energy and dose for the In ion implantation process has been examined. It has been shown that a right combination of ion energy and ion dose must be selected in the film preparation process for the manifestation of the catalytic effect.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2013 2012 2011 2010 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (10 results)

  • [Journal Article] ポリメタクリル酸メチル樹脂の水素プラズマ曝露と低エネルギーアルゴンイオンビームによるエッチング2013

    • Author(s)
      吉村智, 幾世和将, 杉本敏司, 村井健介, 木内正人, 浜口智志
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 56 Pages: 129-132

    • NAID

      10031163964

    • URL

      http://www.vacuum-jp.org

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of catalytic properties of indium-implanted SiO_2 thin films on the energy and dose of incident indium ions2012

    • Author(s)
      S. Yoshimura, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Journal Title

      Thin Solid Films

      Volume: 520 Issue: 15 Pages: 4894-4897

    • DOI

      10.1016/j.tsf.2012.03.028

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low energy metal ion beam production with a modified Freeman-type ion source for development of novel catalysts2012

    • Author(s)
      S. Yoshimura, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 10 Pages: 139-144

    • URL

      http://www.ssj.org/ejssnt

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sputtering yields of CaO, SrO, and BaO by monochromatic noble gas ion bombardment2012

    • Author(s)
      S. Yoshimura, K. Hine, M. Kiuchi, J. Hashimoto, M. Terauchi, Y. Honda, M. Nishitani, S. Hamaguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51

    • NAID

      210000072700

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sputtering yields and surface modification of poly(methyl methacrylate) (PMMA) by low-energy, Ar+/CF3+ ion bombardment with vacuum ultraviolet (VUV) photon irradiation2012

    • Author(s)
      S. Yoshimura, Y. Tsukazaki, M. Kiuchi, S.Sugimoto, and S. Hamaguchi
    • Journal Title

      J. Phys. D; Appl. Phys

      Volume: 45 Issue: 50 Pages: 1-10

    • DOI

      10.1088/0022-3727/45/50/505201

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sputtering yields of CaO, SrO, and BaO by monochromatic noble gas ion bombardment2012

    • Author(s)
      S. Yoshimura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51 Issue: 8S1 Pages: 08HB02-08HB02

    • DOI

      10.1143/jjap.51.08hb02

    • NAID

      210000072700

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sputtering yields of magnesium hydroxide [Mg(OH)2] by noble-gas ion bombardment2012

    • Author(s)
      K. Ikuse
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 45 Issue: 43 Pages: 432001-432001

    • DOI

      10.1088/0022-3727/45/43/432001

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ポリメタクリル酸メチル樹脂の水素プラズマ曝露と低エネルギーアルゴンイオンビームによるエッチング2012

    • Author(s)
      吉村智
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 56 Pages: 129-132

    • NAID

      10031163964

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental evaluation of CaO, SrO and BaO sputtering yields by Ne^+ or Xe^+ions2011

    • Author(s)
      S. Yoshimura, K. Hine, M. Kiuchi, J. Hashimoto, M. Terauchi, Y. Honda, M. Nishitani, S. Hamaguchi
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 44 Issue: 25 Pages: 255203-255203

    • DOI

      10.1088/0022-3727/44/25/255203

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft x-ray computer tomography of tokamak plasma in control experiment of locked mode disruption by electron cyclotron heating2011

    • Author(s)
      S. Yoshimura, T. Maekawa
    • Journal Title

      IEEE Transactions on Plasma Science

      Volume: 39 Issue: 11 Pages: 3000-3001

    • DOI

      10.1109/tps.2011.2131685

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel catalysts: indium implanted SiO_2 thin films2010

    • Author(s)
      S. Yoshimura, K. Hine, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Journal Title

      Applied Surface Science

      Volume: 257 Issue: 1 Pages: 192-196

    • DOI

      10.1016/j.apsusc.2010.06.063

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of light irradiation from inductively coupled Ar plasma on etching yields of SiO_2 film by CF_3 ion beam injections2010

    • Author(s)
      S.Yoshimura, et al.
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 232 Pages: 12020-12020

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel catalysts : indium implanted SiO_2 thin films2010

    • Author(s)
      S.Yoshimura, et al.
    • Journal Title

      Applied Surface Science

      Volume: 257 Pages: 192-196

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of catalytic properties of indium implanted SiO2thin films on the film-substrate temperature during indium ion implantation

    • Author(s)
      S. Yoshimura, K. Ikuse, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Journal Title

      Nuclear Instruments and Method in Physics Research B

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] 低エネルギーインジウム照射 SiO2 の触媒効果の基板温度依存性2013

    • Author(s)
      吉村智、幾世和将、木内正人、西本能弘、安田誠、馬場章夫、浜口智志
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工大
    • Year and Date
      2013-03-28
    • Related Report
      2012 Final Research Report
  • [Presentation] 低エネルギーインジウム照射SiO2の触媒効果の基板温度依存性2013

    • Author(s)
      吉村智
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low energy metal ion beam injection to SiO_2 thin films for development of novel catalysts2012

    • Author(s)
      S. Yoshimura, K. Ikuse, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Organizer
      25th International Conference on Atomic Collisions in Solid
    • Place of Presentation
      Kyoto University, Japan
    • Year and Date
      2012-10-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 低エネルギーイオンビーム照射によるPMMAエッチングイールドの測定と水素プラズマ暴露のエッチングイールドへの影響2012

    • Author(s)
      吉村智、塚崎泰裕、杉本敏司、木内正人、浜口智志
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Low energy metal iom beam injection to SiO2 thin films for development of novel catalysts2012

    • Author(s)
      S. Yoshimura
    • Organizer
      25th International Conference on Atomic Collisions in Solids (ICACS-25), 21-25 October, 2012, & 8th International Symposium on Swift Heavy Ions in Matter (SHIM2012)
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低エネルギーイオンビーム照射によるPMMAエッチングイールドへの紫外線照射および水素プラズマ暴露の影響2012

    • Author(s)
      吉村智
    • Organizer
      第53回真空に関する連合講演会
    • Place of Presentation
      甲南大学ポートアイランドキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 希ガスイオン照射による水酸化マグネシウムのスパッタ率測定2012

    • Author(s)
      幾世和将
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Low energy mass-selected metal ion beam production with a modified Freeman-type ion source for the development of novel catalysts2011

    • Author(s)
      S. Yoshimura, M. Kiuchi, Y. Nishimoto, M. Yasuda, A. Baba, S. Hamaguchi
    • Organizer
      International Symposium on Surface Science and Nanotechnology
    • Place of Presentation
      Tower Hall Funabori, Tokyo, Japan
    • Year and Date
      2011-11-11
    • Related Report
      2012 Final Research Report
  • [Presentation] インジウム照射 SiO_2基板の触媒効果の入射エネルギー依存性2011

    • Author(s)
      吉村智、木内正人、西本能弘、安田誠、馬場章夫、浜口智志
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-01
    • Related Report
      2012 Final Research Report
  • [Presentation] インジウム照射SiO2基板の触媒効果の入射エネルギー依存性2011

    • Author(s)
      吉村智、木内正人、西本能弘、安田誠、馬場章夫、浜口智志
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report

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Published: 2010-11-30   Modified: 2019-07-29  

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