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Development of the new nozzle and detector system in thegas-phase electron diffraction apparatus

Research Project

Project/Area Number 22550022
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionSophia University

Principal Investigator

KUZE Nobuhiko  上智大学, 理工学部, 准教授 (80286757)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords分子構造 / 気体電子回折 / マイクロ波分光 / 星間分子 / 熱分解反応 / レーザーアブレーション
Research Abstract

The purpose of this research project is the renovation of the gas-phase electrondiffraction apparatus. In this project, we have designed and made a new nozzle systemfor the jet gas samples in the vacuum chamber of the apparatus, have modified forbetter handling and multifunctional capability. We have also developed a newdetection system of the diffraction patterns. The introduction of new XYZ-stagemanipulator has made it easier to get the precise control of the nozzle. We havedeveloped the high-temperature-pyrolysis vacuum line, made from the quartz tube andstainless-steel pipes. This system have been settled beside the diffraction chamber andit was connected to the nozzle on the XYZ-stage. Finally, we have constructed theprototype apparatus using the new nozzle and have carried out some experiments toobserve the diffraction pattern of small molecule in the gas phase..

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (40 results)

All 2012 2011 2010 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (30 results)

  • [Journal Article] Radio Search forH2CCC toward HD 183143 as aCandidate for a Diffuse Interstellar BandCarrier2012

    • Author(s)
      Mitsunori Araki, Shuro Takano,Hiromichi Yamabe, Koichi Tsukiyama,and Nobuhiko Kuze
    • Journal Title

      Astrophysical Journal Letters

      Volume: 753:L11 Issue: 1 Pages: 1-3

    • DOI

      10.1088/2041-8205/753/1/l11

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A study ofthe structure and conformation of1,1-dicyclopropylethene by gas electrondiffraction and ab initio calculations2012

    • Author(s)
      Nobuhiko Kuze, Chiaki Ohno, ShinyaMorisaki, Yo Sugawara, KoichiTamagawa, Shigehiro Konaka
    • Journal Title

      J.Mol. Struct

      Volume: 1014 Pages: 1014-1014

    • DOI

      10.1016/j.molstruc.2012.01.050

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A search for interstellar carbon-chain alcohol HC40H in star-forming region L1527 and dark cloud TMC-12012

    • Author(s)
      Mitsunori Araki, Shuro Takano, Hiromichi Yamabe, Naohiro Koshikawa, Koichi Tsukiyama, Aya Nakane, Toshiaki Okabayashi, Arisa Kunimatsu, Nobuhiko Kuze
    • Journal Title

      The Astrophysical Journal

      Volume: 744 Issue: 2 Pages: 163-166

    • DOI

      10.1088/0004-637x/744/2/163

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A search for interstellarcarbon-chain alcohol HC4OH instar-forming region L1527 and dark cloudTMC-12011

    • Author(s)
      Mitsunori Araki, Shuro Takano,Hiromichi Yamabe, Naohiro Koshikawa,Koichi Tsukiyama, Aya Nakane, ToshiakiOkabayashi, Arisa Kunimatsu, andNobuhiko Kuze
    • Journal Title

      The Astrophysical Journal

      Volume: 744 Pages: 163-163

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metastable states inNO2+probed with Auger spectroscopy2011

    • Author(s)
      R. Puttner, V. Sekushin, H. Fukuzawa, T.Uhlikova, V . Spirko, T . Asahina, N.Kuze, H. Kato, M. Hoshino, H. Tanaka, T.D. Thomas, E. Kukk, Y. Tamenori, G.Kaindl and K. Ueda
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 13 Pages: 18436-18446

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metastable states in NO2+ probed with Auger spectroscopy2011

    • Author(s)
      R.Puttner, V.Sekushin, H.Fukuzawa, T.Uhlikova, V.Spirko, T.Asahina, N.Kuze, H.Kato, M.Hoshino, H.Tanaka, T.D.Thomas, E.Kukk, Y.Tamenori, G.Kaindl, K.Ueda
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 13 Pages: 18436-18446

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Valence photoelectron spectroscopy of N2and CO: Recoil-induced rotationalexcitation, relative intensities, and atomicorbital composition of molecularorbitals2010

    • Author(s)
      T. D. Thomas, E. Kukk, T. Ouchi, A.Yamada, H. Fukuzawa, K. Ueda, R.Puttner, I. Higuchi, Y. Tamenori, T.Asahina, N. Kuze, H. Kato, M. Hoshino,H. Tanaka, A. Lindblad and L. J. Sathre
    • Journal Title

      J.Chem. Phys

      Volume: 133 Pages: 174312-174312

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular structure of(E)-benzaldehyde oxime from gas-phaseelectron diffraction2010

    • Author(s)
      Nobuhiko Kuze, Takeshi Sakaizumi,Osamu Ohashi, Yutaka Yokouchi, KinyaIijima
    • Journal Title

      J. Mol. Struct

      Volume: 978 Pages: 195-200

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular structure of (E)-benzaldehyde oxime from gas-phase electron diffraction, quantum-chemical calculations and microwave spectroscopy2010

    • Author(s)
      Nobuhiko Kuze, Takeshi Sakaizumi, Osamu Ohashi, Yutaka Yokouchi, Kinya Iijima
    • Journal Title

      Journal of Molecular Structure

      Volume: 978 Pages: 195-200

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Valence photoelectron spectroscopy of N_2 and CO : Recoil-induced rotational excitation, relative intensities, and atomic orbital composition of molecular orbitals2010

    • Author(s)
      T.D.Thomas, E.Kukk, T.Ouchi, A.Yamada, H.Fukuzawa, K.Ueda, R.Puttner, I.Higuchi, Y.Tamenori, T.Asahina, N.Kuze, H.Kato, M.Hoshino, H.Tanaka, A.Lindblad, L.J.Saethre
    • Journal Title

      The Journal of Chemical Physics

      Volume: 133

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] J3, RADIO SEARCH FORH2CCC TOWARD HD 183143 AS ACANDIDATE FOR A DIFUSEINTERSTELLAR BAND CARRIER2012

    • Author(s)
      Mitsunori Araki, Shuro Takano andNobuhiko Kuze
    • Organizer
      The 22nd International Conference onHigh Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha, Czech Republic
    • Year and Date
      2012-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation] MICROWAVE SPECTRA OFTHE LINEAR CARBON-CHAINALCOHOL HC4OH Arisa Kunimatsu2012

    • Author(s)
      Saori Tanabe, Satoshi Ogawa, NobuhikoKuze
    • Organizer
      The 22nd International Conference onHigh Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha, Czech Republic
    • Year and Date
      2012-09-04
    • Related Report
      2012 Final Research Report
  • [Presentation] MOLECULAR STRUCTURE OF CAMPHOR BY GAS-PHASE ELECTR ON DIFFRACTION, ROTATIONAL SPECTROSCOPY AND QUANTUM CHEMICAL CALCULATION2012

    • Author(s)
      Nobuhiko Kuze, Ari Tokuda, Mariko Ikeuchi, Takamune Yamagami, Hiroshi Takeuchi, Shigehiro Konaka
    • Organizer
      24th Austin Symposium on Molecular Structure and Dynamics
    • Place of Presentation
      Dallas, Texas, USA
    • Year and Date
      2012-03-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] MOLECULARSTRUCTURE OF CAMPHOR BYGAS-PHASE ELECTRONDIFFRACTION, ROTATIONALSPECTROSCOPY AND QUANTUMCHEMICAL CALCULATION2012

    • Author(s)
      Nobuhiko Kuze, Ari Tokuda, MarikoIkeuchi, Takamune Yamagami, HiroshiTakeuchi, Shigehiro Konaka
    • Organizer
      24th Austin Symposium on MolecularStructure
    • Place of Presentation
      Austin, Texas, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] 気体電子回折によるbenzyl acetateの構造解析2011

    • Author(s)
      関塚紘子, 佐野香奈, 久世信彦, 伊藤千夏, 竹内浩, 小中重弘
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 量子化学計算による2-butyn-1-olの熱分解反応機構2011

    • Author(s)
      小川智史, 久世信彦, 國松亜利沙, 荒木光典
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 星形成領域L1527におけるSO, HCS+、H2CCOの検出2011

    • Author(s)
      茅根彩花, 荒木光典, 高野秀路, 工藤沙紀, 梅木博也, 山辺裕倫, 越川直洋, 築山光一, 久世信彦
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Oral presentationTHE MOLECULAR STRUCTURE OFCAMPHOR BY GAS ELECTRONDIFFRACTION ANDQUANTUM-CHEMICALCALCULATIONS2011

    • Author(s)
      Nobuhiko Kuze,Mariko Ikeuchi, Takamune Yamagami,Shigehiro Konaka
    • Organizer
      14th European Symposium on GasElectron Diffraction
    • Place of Presentation
      Moscow, Russia
    • Year and Date
      2011-07-27
    • Related Report
      2012 Final Research Report
  • [Presentation] THE MOLECULAR STRUCTURE OF CAMPHOR BY GAS ELECTRON DIFFRACTION AND QUANTUM-CHEMICAL CALCULATIONS2011

    • Author(s)
      N.Kuze, M.Ikeuchi, T.Yamagami, S.Konaka
    • Organizer
      14th European Symposium on Gas Electron Diffraction
    • Place of Presentation
      Moscow, Russia
    • Year and Date
      2011-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] A SEARCH FOR INTERSTELLAR CARBON-CHAIN ALCOHOL HC4OH IN THE STAR FORMING REGION L15272011

    • Author(s)
      M.Araki, H.Yamabe, N.Koshikawa, K.Tsukiyama, A.Nakane, T.Okabatyashi, A.Kunimatsu, N.Kuze
    • Organizer
      International Symposium on Molecular Spectroscopy 66th Meeting
    • Place of Presentation
      Columbus, Ohio, USA
    • Year and Date
      2011-06-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] マイクロ波で見る分子の世界2011

    • Author(s)
      久世信彦
    • Organizer
      第2回日本電磁波エネルギー応用学会講演会
    • Place of Presentation
      上智大学,東京(招待講演)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 直線炭素鎖アルコールHC4OHのマイクロ波分光2011

    • Author(s)
      國松亜利沙, 田辺沙織, 小川智史, 久世信彦, 中根綾, 岡林利明, 荒木光典
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学
    • Year and Date
      2011-05-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 直線炭素鎖アルコールHC4OH:星形成領域L1527と暗黒星雲TMC-1での探査2011

    • Author(s)
      荒木光典, 高野秀路, 工藤沙紀, 茅根彩花, 梅木博也, 山辺裕倫, 越川直洋, 築山光一, 中根綾, 岡林利明, 國松亜利沙, 久世信彦
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学
    • Year and Date
      2011-05-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] SEARCH FORINTERSTELLAR CARBON-CHAINALCOHOL HC4OH IN THE STARFORMING REGION L15272011

    • Author(s)
      Mitsunori Araki, Shuro TakanoHiromichi Yamabe Naohiro Koshikawa,Koichi Tsukiyama, Aya Nakane, ToshiakiOkabayashi, Arisa Kunimatsu andNobuhiko Kuze
    • Organizer
      International Symposium on MolecularSpectroscopy 66th Meeting
    • Place of Presentation
      Columbus,Ohio, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] 量子化学計算による2-butyn-1-olの熱分解反応機構2010

    • Author(s)
      小川智史, 久世信彦
    • Organizer
      第4回分子科学討論会2010
    • Place of Presentation
      阪大豊中キャンパス(大阪府)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Thermolysis reaction mechanism of 2-butyn-1-ol by the quantum chemical calculation2010

    • Author(s)
      Satoshi Ogawa, Nobuhiko Kuze
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii Convention Center (Honolulu, USA)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Molecular structure and conformations of 2-phenylethanol by gas-phase electron diffraction, quantum-chemical calculations and rotational spectroscopy2010

    • Author(s)
      Hiroko Sekizuka, Nobuhiko Kuze, Mika Sunagawa, Hiroshi Takeuchi, Shigehiro Konaka
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii Convention Center(Honolulu, USA)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Study of Molecular Spectral Lines for Carbon Chain Molecules in a Star Forming Region L1527 between 29 and 90GHz2010

    • Author(s)
      Hironori Yamabe, Naohiro Koshikawa, Hiroya Umeki, Mitsunori Araki, Koichi Tsukiyama, Shuro Takano, Nobuhiko Kuze
    • Organizer
      Pacifichem2010
    • Place of Presentation
      Hawaii Convention Center(Honolulu, USA)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気体電子回折とマイクロ波分光による2-フェニルエタノールの分子構造解析2010

    • Author(s)
      関塚紘子, 久世信彦, 砂川美佳, 竹内浩, 小中重弘
    • Organizer
      第4回分子科学討論会2010
    • Place of Presentation
      阪大豊中キャンパス(大阪府)
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] L1527における29~90GHz帯ラインサーベー及びHC_4OH探査2010

    • Author(s)
      荒木光典, 越川直洋, 山辺裕倫, 梅木博也, 築山光一, 高野秀路, 久世信彦
    • Organizer
      Workshop on Interstellar Matter
    • Place of Presentation
      北大低温研(北海道)
    • Year and Date
      2010-09-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] ROTATIONAL SPECTRUM, POTENTIAL FUNCTION OF RING PUCKERING, MOLECULAR STRUCTURE, AND QUANTUM CHEMICAL CALCULATION OF CYCLO BUTANONE OXIME AND ITS PYROLYSIS MECHANISM2010

    • Author(s)
      Nobuhiko Kuze, Emi Sato, Takeshi Sakaizumi
    • Organizer
      The 21st International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      The Adam Mickiewicz University(Poznan, Poland)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rotations spectrum of the pyrolysate of 2-butyn-1-ol in the gas phase2010

    • Author(s)
      Nobuhiko Kuze, Saori Tanabe, Satoshi Ogawa, Masato Ebisugi, Mitsunori Araki
    • Organizer
      第26回化学反応討論会
    • Place of Presentation
      広島大学サタケメモリアルホール(広島県)
    • Year and Date
      2010-06-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 29-90GHz帯における星形成領域L1527の炭素鎖分子ライン探査2010

    • Author(s)
      越川直洋, 山辺裕倫, 梅木博也, 荒木光典, 築山光一, 高野秀路, 久世信彦
    • Organizer
      第10回分子分光研究会
    • Place of Presentation
      東京工業大学デジタル多目的ホール(東京都)
    • Year and Date
      2010-05-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] MICROWAVE SPECTRA OF THE LINEAR CARBON-CHAIN ALCOHOL HC4OH

    • Author(s)
      Arisa Kunimatsu
    • Organizer
      The 22nd International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] RADIO SEARCH FOR H2CCC TOWARD HD 183143 AS A CANDIDATE FOR A DIUSE INTERSTELLAR BAND CARRIER

    • Author(s)
      Mitsunori Araki
    • Organizer
      The 22nd International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] 熱励起直線三原子分子の軟X 線内殻光電子分光

    • Author(s)
      星野正光
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 貨幣金属モノアセチリド(AgCCH, AuCCH)のFTMW 分光

    • Author(s)
      久保田裕文
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] HD183143 におけるDiffuse Interstellar Bands 候補H2CCC の電波観測による検証

    • Author(s)
      荒木光典
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 直線炭素鎖アルコールHC4OHのマイクロ波分光

    • Author(s)
      國松亜利沙
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学,東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 貨幣金属モノアセチリド(AgCCH, AuCCH)のマイクロ波分光

    • Author(s)
      久保田裕文
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学,東京
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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