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Fundamental processes of low-kinetic-energy-photoelectron diffraction for gaseous molecules.

Research Project

Project/Area Number 22550025
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

ADACHI Jun-ichi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 研究機関講師 (10322629)

Co-Investigator(Renkei-kenkyūsha) YAGISHITA Akira  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (80157966)
FUJIKAWA Takashi  千葉大学, 大学院・融合科学研究科, 教授 (30114987)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywords光電子回折 / 基本気相分子 / 軟 X 線放射光分光 / 内殻光電離 / 軟X線放射光分光 / 放射光
Research Abstract

We investigated core-level photoionization from the viewpoint that it can serve as a low-energy-photoelectron diffraction method. For typical and simple molecules in the gas phase, we measured the molecular frame photoelectron angular distributions and recoil frame photoelectron angular distributions using a coincidence technique. The results for CO molecules showed that the back-scattered intensities depend on the kinetic energy of the photoelectron, which can, in one of the simplest cases, be attributed to a mechanism that leads an extended X-ray absorption fine structure. We compared experimental results with calculations based on X-ray photoelectron diffraction theory and found that the angular distribution comes from the interference be tween the direct photoelectron wave and the scattered waves.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (27 results)

All 2012 2011 2010 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (8 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Multiple-scattering calculations for 1s photoelectron angular distributions from single oriented molecules in the energy region above 50 eV2012

    • Author(s)
      Misato KAZAMA, Jun-ichi ADACHI, 他 , Takashi FUJIKAWA, Akira YAGISHITA
    • Journal Title

      J. Electron Spectrosc. Relat. Phenom

      Volume: 185 Pages: 535-545

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] C 1s photoelectron angular distributions from fixed-in-space CO molecules in the high energy continuum >= 50eV2012

    • Author(s)
      Jun-ichi ADACHI, 他
    • Journal Title

      J. Phys

      Volume: B 45

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions in core O 1s ionization of H_2CO2012

    • Author(s)
      Mauro STENER, 他 , Jun-ichi ADACHI, Akira YAGISHITA
    • Journal Title

      J. Phys

      Volume: B 45

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiple-scattering calculations for Is photoelectron angular distributions from single oriented molecules in the energy region above 50 eV2012

    • Author(s)
      M. Kazama, H. Shinotsuka, T. Fujikawa, M. Stener, P. Decleva, J. Adachi, T. Mizuno, A. Yagishita
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 185 Issue: 11 Pages: 535-545

    • DOI

      10.1016/j.elspec.2012.10.009

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C Is photoelectron angular distributions from fixed-in-space CO molecules in the high-energy continuum >50 eV2012

    • Author(s)
      J. Adachi, M. Kazama. T. Teramoto, N. Miyauchi, T. Mizuno, M. Yamazaki, T. Fujikawa, A. Yagishita
    • Journal Title

      Journal of Physics B

      Volume: 45 Issue: 19 Pages: 194007-194007

    • DOI

      10.1088/0953-4075/45/19/194007

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions in core O 1s ionozation of H2CO2012

    • Author(s)
      M. Stener
    • Journal Title

      J. Phys. B: At. Mol. Opt. Phys.

      Volume: 45 Issue: 19 Pages: 194004-194004

    • DOI

      10.1088/0953-4075/45/19/194004

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions of BF_3 : A sensitive probe of the shape resonance in the F 1s continuum2012

    • Author(s)
      T.Mizuno
    • Journal Title

      The Journal of Chemical Physics

      Volume: 136 Issue: 7

    • DOI

      10.1063/1.3687006

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] O 1s photoionization dynamics in oriented NO_22011

    • Author(s)
      Mauro STENER, 他 , Jun-ichi ADACHI, Akira YAGISHITA
    • Journal Title

      J. Chem. Phys

      Volume: 133

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] O 1s photoionization dynamics in oriented NO_22011

    • Author(s)
      M.Stener, P.Decleva, M.Yamazaki, J.Adachi, A.Yagishita
    • Journal Title

      The Journal of Chemical Physics

      Volume: 134 Issue: 18

    • DOI

      10.1063/1.3584202

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of x-ray photoelectron diffraction for fixed-in-space CO molecules2010

    • Author(s)
      Misato KAZAMA, Jun-ichi ADACHI, 他 3名
    • Journal Title

      Chem. Phys

      Volume: 373 Pages: 261-266

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoemission dynamics in the molecular frame2010

    • Author(s)
      YAGISHITA Akira, ADACHI Jun-ichi,YAMAZAKI Masakazu
    • Journal Title

      J. Phys. Conf. Ser

      Volume: 212

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 解説「分子座標系で観測する孤立自由分子の光電離ダイナミクス」2010

    • Author(s)
      足立純一, 柳下明
    • Journal Title

      日本物理学会誌

      Volume: 65巻 Pages: 416-424

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of x-ray photoelectron diffraction for fixed-in-space CO molecules2010

    • Author(s)
      KAZAMA Misato, ADACHI Jun-ichi, (他5名)
    • Journal Title

      Chem.Phys.

      Volume: 373 Pages: 261-266

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoemission dynamics in the molecular frame2010

    • Author(s)
      YAGISHITA Akira, ADACHI Jun-ichi, YAMAZAKI Masakazu
    • Journal Title

      J.Phys.Conf.Ser.

      Volume: 212

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 解説「分子座標系で観測する孤立自由分子の光電離ダイナミクス」2010

    • Author(s)
      足立純一、柳下明
    • Journal Title

      日本物理学会誌

      Volume: 65 Pages: 416-424

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Core-level photoelectron angular distributions for fixed-in-space CO and CO2 molecules with a kinetic energy of up to 150 eV2012

    • Author(s)
      ADACHI Jun-ichi
    • Organizer
      TMU Research Program "Ion Storage Research Network for Molecular Science" and ISAS Workshop on Atomic and Molecular Processes in Space
    • Place of Presentation
      首都大学東京国際交流会館 (東京都)
    • Year and Date
      2012-02-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Core-level photoelectron angular distributions for fixed-in-space CO and CO_2 molecules with a kinetic energy of up to 150 eV2012

    • Author(s)
      ADACHI Jun-ichi
    • Organizer
      TMU Research Program "Ion Storage Research Network for Molecular Science" and ISAS Workshop on Atomic and Molecular Processes in Space
    • Place of Presentation
      首都大学東京国際交流会館(東京都)
    • Year and Date
      2012-02-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] 気相分子の内殻光電離の基礎過程: X 線光電子回折像の測定2011

    • Author(s)
      足立純一
    • Organizer
      第240回 X 線分析研究懇談会 (招待講演)
    • Place of Presentation
      名古屋大学グリーンサロン東山 (愛知県)
    • Year and Date
      2011-12-02
    • Related Report
      2012 Final Research Report
  • [Presentation] 気相分子の内殻光電離の基礎過程:X線光電子回折像の測定2011

    • Author(s)
      足立純一
    • Organizer
      第240回X線分析研究懇談会
    • Place of Presentation
      名古屋大学グリーンサロン東山(愛知県)(招待講演)
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Invited: Photoelectron diffractions of 1s electrons for fixed-in-space molecules, ADACHI Jun-ichi2010

    • Author(s)
      ADACHI Jun-ichi
    • Organizer
      5th Asia Oceania Forum on Synchrotron Radiation ResearchJuly
    • Place of Presentation
      POSCO International Center, Pohang (韓国).
    • Related Report
      2012 Final Research Report
  • [Presentation] C 1s photoelectron angular distributions from fixed-in-space CO2 and OCS molecules with kinetic energy of above 50 eV2010

    • Author(s)
      ADACHI Jun-ichi, KAZAMA Misato (他 4 名)
    • Organizer
      37th International conference on Vacuum Ultraviolet and X-ray Physics
    • Place of Presentation
      Univ. of British Columbia, Vancouver (Canada).
    • Related Report
      2012 Final Research Report
  • [Presentation] Photoelectron diffractions of 1s electrons for fixed-in-space molecules2010

    • Author(s)
      ADACHI Jun-ichi
    • Organizer
      5th Asia Oceania Forum on Synchrotron Radiation Research
    • Place of Presentation
      POSCO International Center, Pohang(韓国)(Invited)
    • Related Report
      2010 Annual Research Report
  • [Presentation] C 1s photoelectron angular distributions from fixed-in-space CO_2 and OCS molecules with kinetic energy of above 50 eV2010

    • Author(s)
      ADACHI Jun-ichi, KAZAMA Misato, (他4名)
    • Organizer
      37th International conference on Vacuum Ultraviolet and X-ray Physics [VUXX2010]
    • Place of Presentation
      Univ.of British Columbia, Vancouver (Canada)
    • Related Report
      2010 Annual Research Report
  • [Book] 放射光ユーザーのための検出器ガイド - 原理と使い方2011

    • Author(s)
      足立純一, 彦坂泰正 (共同執筆)
    • Publisher
      講談社サイエンティフィック
    • Related Report
      2012 Final Research Report
  • [Book] 放射光ユーザーのための検出器ガイド-原理と使い方(第11章;p.122-138)2011

    • Author(s)
      足立純一, 彦坂泰正(共同執筆)
    • Publisher
      講談社サイエンティフィック
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://molecule.kek.jp/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://molecule.kek.jp/

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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