Project/Area Number |
22550025
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Physical chemistry
|
Research Institution | High Energy Accelerator Research Organization |
Principal Investigator |
ADACHI Jun-ichi 大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 研究機関講師 (10322629)
|
Co-Investigator(Renkei-kenkyūsha) |
YAGISHITA Akira 大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (80157966)
FUJIKAWA Takashi 千葉大学, 大学院・融合科学研究科, 教授 (30114987)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
|
Keywords | 光電子回折 / 基本気相分子 / 軟 X 線放射光分光 / 内殻光電離 / 軟X線放射光分光 / 放射光 |
Research Abstract |
We investigated core-level photoionization from the viewpoint that it can serve as a low-energy-photoelectron diffraction method. For typical and simple molecules in the gas phase, we measured the molecular frame photoelectron angular distributions and recoil frame photoelectron angular distributions using a coincidence technique. The results for CO molecules showed that the back-scattered intensities depend on the kinetic energy of the photoelectron, which can, in one of the simplest cases, be attributed to a mechanism that leads an extended X-ray absorption fine structure. We compared experimental results with calculations based on X-ray photoelectron diffraction theory and found that the angular distribution comes from the interference be tween the direct photoelectron wave and the scattered waves.
|