Synthesis of Novel Macrocyclic Carbazole Derivatives and Their Application for Functional Materials
| Project/Area Number |
22550033
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka Kyoiku University |
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Principal Investigator |
TANI Keita 大阪教育大学, 教育学部, 教授 (60207165)
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| Co-Investigator(Kenkyū-buntansha) |
OHKITA Hideo 京都大学大学院, 工学研究科, 准教授 (50301239)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | カルバゾール / カルバゾロファン / 蛍光 / 面不斉 / エキシマー / ドナー-アクセプター / 円二色性スペクトル / シクロファン / ドナー / アミド結合 / 光学分割 / CDスペクトル / キロプティカル特性 / キラルカルバゾール誘導体 / 不斉 |
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| Research Abstract |
Various carbazolophane derivatives and their reference monomers have been synthesized. Their photophysical, chiroptical, electrochemical properties and structures are examined by NMR, electronic absorption, fluorescence, and circular dichroism spectra, redox potentials, and X-ray crystal structure analysis. It is revealed that donor ability of carbazolphane derivatives is higher than that of the corresponding monomers. In particular, optical resolution of partially overlapped carbazolophanes can be achieved and their absolute configuration is determined.
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Report
(4 results)
Research Products
(37 results)
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[Journal Article] Di-・2-acetato-1:2・2O:O';2:3・2O:O'-bis{・2-4,4'-dichloro-2,2'-[2,2-dimethyl-1,3-propanediyl-bis(nitrilomethylidyne)]diphenolato}-1:2・6O,N,N',O':O,O';2:3・6O,O':O,N,N',O-tricopper(II)2012
Author(s)
Koji Kubono, Keita Tani, Kunihiko Yokoi
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Journal Title
Acta Crystallographica
Volume: E68
Issue: 11
Pages: 1545-1547
DOI
Related Report
Peer Reviewed / Open Access
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[Journal Article] Synthesis, Photochromic, and Electrical Properties of Diarylethene Derivatives Having 9-Carbazolyl or 2-(1,3,4-Oxadiazolyl) Group as Carrier Mobilization Sites2011
Author(s)
K. Tani, K. Kubono, K. Hori, K. Shoji, G. Shiga, M. Yamamoto, T. Tsujioka
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Journal Title
Chem. Lett.
Volume: 40
Issue: 11
Pages: 1267-1268
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene2011
Author(s)
K. Kubono, T. Synmyouzu, K. Goto, T. Tsujioka, K. Tani
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Journal Title
Acta Cryst.
Volume: E6
Issue: 8
Pages: o2194-o2194
DOI
Related Report
Peer Reviewed
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