| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
Construction of photo-functional molecules based on the properties of heteroatoms and azulene was tried by introduction of a heteroatom (phosphorus or boron) into the position adjacent to a coordinative functional group in the 5-membered ring of azulene. Thus, we revealed how the intramolecular coordination of a pyridyl group with a phosphorus atom affected the -electron system of azulene. Furthermore, we found that the iminoazulenes prepared by the condensation of an amino acid with 2-boryl-1-formylazulene showed a variety of coloration in solid states depending on the structure of the amino acid.
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