Construction of unique photo-functional molecules based on thproperties of heteroatoms and azulene
Project/Area Number |
22550039
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Yamaguchi University |
Principal Investigator |
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | 典型元素 / アズレン / アザアズレン / 非ベンゼノイド / 光機能 / ヘテロ原子 / 光機能性 / 光機能材料 / 蛍光 |
Research Abstract |
Construction of photo-functional molecules based on the properties of heteroatoms and azulene was tried by introduction of a heteroatom (phosphorus or boron) into the position adjacent to a coordinative functional group in the 5-membered ring of azulene. Thus, we revealed how the intramolecular coordination of a pyridyl group with a phosphorus atom affected the -electron system of azulene. Furthermore, we found that the iminoazulenes prepared by the condensation of an amino acid with 2-boryl-1-formylazulene showed a variety of coloration in solid states depending on the structure of the amino acid.
|
Report
(4 results)
Research Products
(27 results)
-
-
-
-
-
-
-
[Journal Article] Synthesis of 12,12a-dihydro-7,12a-diazacyclohepta[cd]benz[g]azulen-12-one(cyclohepta[mn]pyrrolo[2,1-c][1,4]-benzodiazepin-12-one) and evaluation of cytotoxic activity against HeLa S3 cells2011
Author(s)
E. Yoshioka, H. Fujii, T. Murafuji, R. Ikeda, T. Konakahara, T. Gunji, N. Abe
-
Journal Title
Heterocycles
Volume: 83
Pages: 1409-1415
NAID
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-