Synthesis and Reaction of Butterfly-type Stable Organic Hydroperoxides
| Project/Area Number |
22550041
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kumamoto University |
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Principal Investigator |
NISHINO Hiroshi 熊本大学, 大学院・自然科学研究科, 教授 (50145281)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | ビス(ヒドロペルオキシド) / 有機過酸化物 / 有酸素酸化反応 / 有機化学 / 複素環化合物 / エンドペルオキシド / ラジカル反応 / 自動酸化反応 / ビス（ヒドロペルオキシド） / 酸化反応 / 有機合成化学 / 有機反応化学 / 化学 / ヒドロペルオキシド |
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| Research Abstract |
Butterfly-type organic hydroperoxides containing heterocyclessuch as bis(alkylhydroperoxide) were synthesized. Selectivity of the hydroperoxidationand endoperoxidation under the same reaction conditions was investigated. Oxidation oforganic compounds with the obtained crystalline bis(alkylhydroperoxide)s as an organicoxidant was examined. Biological activity such as antibacterial and herbicidal of thenewly obtained hydroperoxides was examined.
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Report
(4 results)
Research Products
(69 results)
