Development of Highly Efficient Synthetic Method Using Novel Concept "Pseudo-Intramolecular Reaction"
| Project/Area Number |
22550043
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kochi University of Technology |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2010: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 擬似分子内反応 / 高効率反応 / イミノ化反応 / ビシクロ化反応 / タンデム型反応 / ジヒドロピリジン / ケトニトリル / ピリジン / ヒドラゾン化 / ジアゼピン / ピリダジン / ニトロソ |
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| Research Abstract |
A new synthetic method was developed, in which novel concept “pseudo-intramolecular process” is used. When -nitro- -keto nitrile was allowed to react with amines, hydrazines, and diamines, polyfunctionalized 1,4-dihydropyridines, diazepines, pyridazines and bicyclic compounds were efficiently synthesized, respectively.
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Report
(4 results)
Research Products
(20 results)
