A Breakthrough in Preparation of Noble Metal Nanoparticle Catalysts Supported on Activated Carbon Support - A New Approach from the View Point of Coordination Chemistry
Project/Area Number |
22550054
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | Yamagata University |
Principal Investigator |
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
Keywords | 金属錯体化学 / パラジウム・カーボン / ロジウム・カーボン / パラジウムナノ微粒子 / ロジウムナノ微粒子 / 触媒 / フェノールの水素化 / パラジウム / シュウ酸錯体 |
Research Abstract |
Activated carbon-supported Pd and Rh nanoparticles (Pd/C andRh/C) have been prepared by a new method which is based on the self-redox of their oxaltecomplexes without any additional reducing agents. Octylamine-and oleylamine-stabilizedPd nanoparticles supported on activated carbon (octyla-Pd/C and oleyla-Pd/C) have beenalso prepared. Catalytic properties of these Pd/C, Rh/C, octyla-Pd/C and oleyla-Pd/C wereevaluated for the hydrogenation of phenol, and compared with those of commerciallyavailable catalysts.
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Report
(4 results)
Research Products
(6 results)