| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
A series of one-electron oxidized metal(II) salen-type complexes were prepared allowing for a comparison of the electronic structure between 5- and 6-membered chelate backbone. The chelate ring-size difference of the diamine backbone gave different electronic structure of the oxidized Cu(II) complex, the 5-membered chelate complex was assigned to a Cu(III) ground state, while the 6-membered chelate complex was a Cu(II)-phenoxyl radical. Investigation of the reactivity of these oxidized complex revealed that reaction rate of the Cu(II)-phenoxyl radical was fastest in the series of oxidized species.
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