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Investigation of the effect of ion-pair formation on the stability of hydrogen-bond-assisted polyoxometalate aggregates

Research Project

Project/Area Number 22550056
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

OZEKI Tomoji  東京工業大学, 大学院・理工学研究科, 准教授 (60214136)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords多核錯体 / ポリオキソメタレート / 水素結合 / イオン対 / 自己集合 / 分子認識 / 多核NMR / X線小角散乱 / バナジウム / 結晶構造解析 / ポリ酸 / 質量分析
Research Abstract

The hydrogen-bond assisted dimerization behavior of protonated decavanadate anions has been investigated by using small angle X-ray scattering and NMR spectroscopy. In protophobic solvents such as acetone and acetonitrile, the decavanadate anions form hydrogen-bonded dimers, whereas the dimers dissociate into monomers in protophilic solvents such as 1,4-dioxane and dimethyl sulfoxide. The dimerization behavior of the decavanadate was proved to depend on the protophilic/protophobic nature of the solvents. The stability of the dimers in the presence of tetrapentyl-, tetraoctyl- and tetradecyl-ammonium cations as the counter cations was also investigated.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (72 results)

All 2013 2012 2011 2010 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (49 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Determination of α-Keggin structure of [GeW 11 O39 RuIII(H2 O)]5-. Reaction of [GeW 11 O39 RuIII(H2 O)]5- with dimethyl sulfoxide to form [GeW 11 O39 RuIII(dmso)]5-and their structural characterization2013

    • Author(s)
      S. Ogo, N. Shimizu, T. Ozeki, Y. Kobayashi, Y. Ide, T. Sano, M. Sadakane
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 7 Pages: 2540-2545

    • DOI

      10.1039/c2dt32038j

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Benzophenones from an Endophytic Fungus, Graphiopsis chlorocephala, from Paeonia lactiflora Cultivated in the Presence of an NAD+-Dependent HDAC Inhibitor2013

    • Author(s)
      T. Asai, S. Otsuki, H. Sakurai, K.Yamashita, T. Ozeki, Y. Oshima
    • Journal Title

      Org.Lett

      Volume: 15 Issue: 8 Pages: 2058-2061

    • DOI

      10.1021/ol400781b

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ir_3Co_6 and Co_3Fe_3 Dithiolene Cluster Complexes : Multiple Metal-metal Bond Formation and Correlation between Structure and Internuclear Electronic Communication2012

    • Author(s)
      Tsukada, S.; Shibata, Y.; Sakamoto, R.; Kambe, T.; Ozeki, T.; Nishihara, H.
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Issue: 3 Pages: 1228-1230

    • DOI

      10.1021/ic202548g

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels2012

    • Author(s)
      M. Saito, T. Ozeki
    • Journal Title

      Dalton Trans

      Volume: 41 Issue: 33 Pages: 9846-9848

    • DOI

      10.1039/c2dt30582h

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusual electronic structure of bis-isocyanide complexes of iron(iii) porphyrinoids2012

    • Author(s)
      Y. Ohgo, S. Neya, D. Hashizume, T. Ozeki, M. Nakamura
    • Journal Title

      Dalton Trans

      Volume: 41 Issue: 11 Pages: 3126

    • DOI

      10.1039/c2dt12249a

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dual Emission from Rhenium(I) Complexes Induced by an Interligand Aromatic Interaction2012

    • Author(s)
      T. Morimoto, M. Ito, K. Koike, T. Kojima, T.Ozeki, O. Ishitani
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Issue: 11 Pages: 3292-3304

    • DOI

      10.1002/chem.201102698

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Diversity of New C13 -Polyketides Produced by Chaetomium mollipilium Cultivated in the Presence of aNAD+-Dependent Histone DeacetylaseInhibitor2012

    • Author(s)
      T. Asai, S. Morita, N. Shirata, T. Taniguchi, K. Monde, H. Sakurai, T. Ozeki, Y. Oshima
    • Journal Title

      Org. Lett.

      Volume: 14 Issue: 21 Pages: 5456-5459

    • DOI

      10.1021/ol302539s

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tenuipyrone, a Novel Skeletal Polyketide from the Entomopathogenic Fungus, Isaria tenuipes, Cultivated in the Presence of Epigenetic Modifiers2012

    • Author(s)
      T. Asai, Y.-M. Chung, H. Sakurai, T. Ozeki, F.-R. Chang, K. Yamashita, Y. Oshima
    • Journal Title

      Org.Lett.

      Volume: 14 Issue: 2 Pages: 513-515

    • DOI

      10.1021/ol203097b

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly oxidized ergosterols and isariotin analogs from an entomopathogenic fungus, Gibellula formosana, cultivated in the presence of epigenetic modifying agents2012

    • Author(s)
      T. Asai, Y.-M. Chung, H. Sakurai, T. Ozeki,F.-R. Chang, Y.-C. Wu, K. Yamashita, Y. Oshima
    • Journal Title

      Tetrahedron

      Volume: 68 Issue: 29 Pages: 5817-5823

    • DOI

      10.1016/j.tet.2012.05.020

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallographic Studies on the Mechanisms of the Cluster Formation and the Higher Order Structure Evolution of Mixed-valence Polyoxometalates2011

    • Author(s)
      尾関智二
    • Journal Title

      Nihon Kessho Gakkaishi

      Volume: 53 Issue: 6 Pages: 371-379

    • DOI

      10.5940/jcrsj.53.371

    • NAID

      10030264594

    • ISSN
      0369-4585, 1884-5576
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure Analysis of Poly(L -lactic Acid) α Form On the basis of the 2-Dimensional Wide-Angle Synchrotron X-ray and Neutron Diffraction Measurements2011

    • Author(s)
      K. Wasanasuk, K. Tashiro, M. Hanesaka, T.Ohhara, K. Kurihara, R. Kuroki, T. Tamada, T. Ozeki, T. Kanamoto
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 16 Pages: 6441-6452

    • DOI

      10.1021/ma2006624

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and structural characterization of Ru(II)-DMSO and Ru(III)-DMSO-substituted α-Keggin-type phosphotungstates, [PW_<11>O_<39>Ru(II)DMSO]^<5-> and [PW_<11>O_<39>Ru(III)DMSO]^<4->, and catalytic activity for water oxidation2011

    • Author(s)
      M.Sadakane, N.Rinn, S.Moroi, H.Kitatomi, T.Ozeki, M.Kurasawa, M.Itakura, S.Hayakawa, K.Kato, M.Miyamoto, S.Ogo, Y.Ide, T.Sano
    • Journal Title

      Zeitschrift der Anorganischen und Allgemeinen Chemie

      Volume: 637 Issue: 11 Pages: 1467-1474

    • DOI

      10.1002/zaac.201100213

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent-Driven Association and Dissociation of the Hydrogen-Bonded Protonated Decavanadates2011

    • Author(s)
      T. Kojima, M. R. Antonio, T. Ozeki
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133 Issue: 19 Pages: 7248-7251

    • DOI

      10.1021/ja110781f

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polyoxomolybdate-Surfactant Hybrid Layered Crystal with Unusually Long Periodicity2011

    • Author(s)
      T. Ito, K. Mikurube, K. Hasegawa, M.Kurasawa, H. Naruke, T. Ozeki
    • Journal Title

      Chemistry Letters

      Volume: 40 Issue: 6 Pages: 626-628

    • DOI

      10.1246/cl.2011.626

    • NAID

      10028244119

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembled M 24 L48 Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation2010

    • Author(s)
      Q.-F. Sun, J. Iwasa, D. Ogawa, Y. Ishido, S.Sato, T. Ozeki, Y. Sei, K. Yamaguchi, M. Fujita
    • Journal Title

      Science

      Volume: 328 Issue: 5982 Pages: 1144-1147

    • DOI

      10.1126/science.1188605

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid Inorganic-Organic Crystals Composed of Octamolybdate Isomers and Pyridinium Surfactant2010

    • Author(s)
      T. Ito, K. Mikurube, Y. Abe, T. Koroki, M.Saito, J. Iijima, H. Naruke, T. Ozeki
    • Journal Title

      Chemistry Letters

      Volume: 39 Issue: 12 Pages: 1323-1325

    • DOI

      10.1246/cl.2010.1323

    • NAID

      10027468776

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Inorganic-Organic Hybrid Crystals Composed of Octamolybdate Isomers and Pyridinium Surfactant2010

    • Author(s)
      Takeru Ito, Keisuke Mikurube, Yukihiro Abe, Takahisa Koroki, Masaki Saito, Jun Iijima, Haruo Naruke, Tomoji Ozeki
    • Journal Title

      Chemistry Letters

      Volume: 39 Pages: 1323-1325

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembled M_<24>L_<48> Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation2010

    • Author(s)
      Qing-Fu Sun, Junji Iwasa, Daichi Ogawa, Yoshitaka Ishido, Sota Sato, Tomoji Ozeki, Yoshihisa Sei, Kentaro Yamaguchi, Makoto Fujita
    • Journal Title

      Science

      Volume: 328 Pages: 1144-1147

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] ニオブ置換ポリタングステン酸とエチニル銀からなるキメラ型クラスターの合成2013

    • Author(s)
      玉利翔, 尾関智二
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学、滋賀県草津市
    • Related Report
      2012 Final Research Report
  • [Presentation] 単結晶フォトクロミック白金錯体の暗所下での単結晶中性子構造解析2013

    • Author(s)
      松下信之, 大原高志, 荒木孝誠, 尾関智二, 田中伊知朗, 日下勝弘, 細谷孝明, 山田太郎, 栗原和男, 新村信雄
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学、滋賀県草津市
    • Related Report
      2012 Final Research Report
  • [Presentation] ニオブ置換ポリタングステン酸とエチニル銀からなるキメラ型クラスターの合成2013

    • Author(s)
      玉利 翔・尾関 智二
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ポリオキソメタレートの示すイオン間相互作用2012

    • Author(s)
      尾関智二
    • Organizer
      第28回日本イオン交換研究発表会
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Related Report
      2012 Final Research Report
  • [Presentation] 多核銀クラスターによって修飾されたNb置換ポリ酸の合成と結晶構造2012

    • Author(s)
      倉澤真理子, 尾関智二
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Related Report
      2012 Final Research Report
  • [Presentation] 高濃度酢酸条件下での六核へテロポリ酸の合成とその結晶構造2012

    • Author(s)
      杉山晴紀, 鈴木紀雄, 尾関智二
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Related Report
      2012 Final Research Report
  • [Presentation] フッ素置換安息香酸Feクラスターの新展開原子価局在-非局在と57Fe-メスバウアー分光法による有機蒸気センシングの可能性2012

    • Author(s)
      尾中証, 酒井陽一, 尾関智二, 中本忠宏, 高橋正, 小林雄介, 坂村雅啓, 伊藤光宏, 小木曽了, 塩塚理仁, 高山努
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学、富山県富山市
    • Related Report
      2012 Final Research Report
  • [Presentation] ポリ酸-多核銀クラスター間に結合を有する非対称ハイブリッド化合物の合成と結晶構造2012

    • Author(s)
      倉澤真理子, 尾関智二
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学、富山県富山市
    • Related Report
      2012 Final Research Report
  • [Presentation] 巨大球状ポリ酸をビルディングブロックとする新規サンドイッチ型ポリ酸の合成と構造2012

    • Author(s)
      齋藤真毅, 尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] 多核銀クラスターを含む新規ポリ酸化合物の合成と結晶構造2012

    • Author(s)
      倉澤真理子, 尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] デカ バナジン酸をプローブとして用いた水素結合による自己集合を支配する溶媒効果の検討2012

    • Author(s)
      小島達弘, M. R. Antonio, 尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] キレート剤と希土類元素を用いたポリ酸化合物の合成とフォトクロミズム2012

    • Author(s)
      鹿釜秀康, 尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] 放射光を利用したポリオキソメタレート集合状態の研究2012

    • Author(s)
      尾関智二
    • Organizer
      第29回PFシンポジウム
    • Place of Presentation
      つくば国際会議場、茨城県つくば市
    • Related Report
      2012 Final Research Report
  • [Presentation] 単結晶中性子回折によるモリブデンオキソ錯体中の水素結合の解析2012

    • Author(s)
      尾関智二, 大原高志, 下野貴弘, 田中伊 知朗, 日下勝弘, 細谷孝明, 山田太郎, 栗 原和男, 新村信雄, 定金正洋, 上田渉, W. Feng
    • Organizer
      第3回 MLFシンポジウム, いばらき量子ビーム研究センター
    • Place of Presentation
      茨城県東海村
    • Related Report
      2012 Final Research Report
  • [Presentation] ポリ酸-多核銀クラスター間に結合を有する非対称ハイブリッド化合物の合成と結晶構造2012

    • Author(s)
      倉澤真理子・尾関智二
    • Organizer
      錯体化学会 第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多核銀クラスターによって修飾されたNb置換ポリ酸の合成と結晶構造2012

    • Author(s)
      倉澤真理子・尾関智二
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高濃度酢酸条件下での六核へテロポリ酸の合成とその結晶構造2012

    • Author(s)
      杉山晴紀・鈴木紀雄・尾関智二
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ポリオキソメタレートの示すイオン間相互作用2012

    • Author(s)
      尾関智二
    • Organizer
      第28回日本イオン交換研究発表会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単結晶中性子回折によるモリブデンオキソ錯体中の水素結合の解析2012

    • Author(s)
      尾関智二, 大原高志, 下野貴弘、田中伊知朗, 日下勝弘, 細谷孝明, 山田太郎, 栗原和男, 新村信雄, 定金正洋, 上田渉, Wang Feng
    • Organizer
      第3回MLFシンポジウム
    • Place of Presentation
      いばらき量子ビーム研究センター(茨城県東海村)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 放射光を利用したポリオキソメタレート集合状態の研究2012

    • Author(s)
      尾関智二
    • Organizer
      第29回PFシンポジウム
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 多核銀クラスターを含む新規ポリ酸化合物の合成と結晶構造2012

    • Author(s)
      倉澤真理子・尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(横浜)
    • Related Report
      2011 Annual Research Report
  • [Presentation] デカバナジン酸をプローブとして用いた水素結合による自己集合を支配する溶媒効果の検討2012

    • Author(s)
      小島達弘・Mark R.Antonio・尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(横浜)
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート剤と希土類元素を用いたポリ酸化合物の合成とフォトクロミズム2012

    • Author(s)
      鹿釜秀康・尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(横浜)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 巨大球状ポリ酸をビルディングブロックとする新規サンドイッチ型ポリ酸の合成と構造2012

    • Author(s)
      斎藤真毅・尾関智二
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(横浜)
    • Related Report
      2011 Annual Research Report
  • [Presentation] The effect of solvents on the dissociation and association of decavanadates2011

    • Author(s)
      T. Kojima, M. R. Antonio, T. Ozeki
    • Organizer
      XXII Congress and General Assembly of the International Union of Crystallography (IUCr2011)
    • Place of Presentation
      Municipal Conference Centre, Madrid, Spain
    • Related Report
      2012 Final Research Report
  • [Presentation] The pH dependent nuclearity variation of {Mo 154-x } type polyoxomolybdates and on their aggregation patterns in their crystals2011

    • Author(s)
      T. Ozeki
    • Organizer
      The 9thTaiwan-Japan Joint Seminar on Crystallography
    • Place of Presentation
      National Taiwan University, Taipei, Taiwan
    • Related Report
      2012 Final Research Report
  • [Presentation] The pH driven nuclearity growths of mixed-valence polyoxomolybdates and their structure directed aggregations2011

    • Author(s)
      T. Ozeki
    • Organizer
      2011Tsinghua-Tokyo Tech Nano-materials Symposium
    • Place of Presentation
      Jingdezhen Ceramic Institute, Jingdezhen, China
    • Related Report
      2012 Final Research Report
  • [Presentation] 球状モリブデン酸アニオンのアルカリ土類金属塩の結晶構造2011

    • Author(s)
      齋藤真毅, 尾関智二
    • Organizer
      平成23年度日本結晶学会年会
    • Place of Presentation
      北 海道大学、北海道札幌市
    • Related Report
      2012 Final Research Report
  • [Presentation] Keggin型ポリ酸と希土類元素を用いたジエチレントリアミン五酢酸(DTPA)塩の構造比較2011

    • Author(s)
      鹿釜秀康, 尾関智二
    • Organizer
      平成23年度日本結晶学会年会
    • Place of Presentation
      北海道大学、北海道札幌市
    • Related Report
      2012 Final Research Report
  • [Presentation] プロ トン付加デカバナジン酸の水素結合による溶液内の自己集合へ及ぼす溶媒の効果2011

    • Author(s)
      小島達弘, M. R. Antonio, 尾関智二
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学、岡山県岡山市
    • Related Report
      2012 Final Research Report
  • [Presentation] プロトン付加デカバナジン酸の塩基性溶媒による脱プロトン化に伴う構造変化2011

    • Author(s)
      尾関智二, 小島達弘
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] 第一系列遷移金属と1価のカチオンを含むデカバナジン酸塩の構造比較2011

    • Author(s)
      樽井亮介, 山脇拓人, 飯田昭文, 尾関智二
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] ポリ酸-金属クラスター混和系における新規化合物の合成研究2011

    • Author(s)
      大橋賢二, 尾関智二
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学、神奈川県横浜市
    • Related Report
      2012 Final Research Report
  • [Presentation] The effect of solvents on the dissociation and association of decavanadates2011

    • Author(s)
      T.Kojima, M.R.Antonio, T.Ozeki
    • Organizer
      XXII Congress and General Assembly of the International Union of Crystallography
    • Place of Presentation
      Madrid,スペイン
    • Related Report
      2011 Annual Research Report
  • [Presentation] プロトン付加デカバナジン酸の水素結合による溶液内の自己集合へ及ぼす溶媒の効果2011

    • Author(s)
      小島達弘・Mark R.Antonio・尾関智二
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Related Report
      2011 Annual Research Report
  • [Presentation] The pH dependent nuclearity variation of {Mo_<154-x>} type polyoxomolybdates and on their aggregation patterns in their crystals2011

    • Author(s)
      Tomoji Ozeki
    • Organizer
      The 9th Taiwan-Japan Joint Seminar on Crystallography
    • Place of Presentation
      Taipei,台湾(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] The pH driven nuclearity growths of mixed-valence polyoxomolybdates and their structure directed aggregations2011

    • Author(s)
      Tomoji Ozeki
    • Organizer
      2011 Tsinghua-Tokyo Tech Nano-materials Symposium
    • Place of Presentation
      Jingdezhen,中国(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Keggin型ポリ酸と希土類元素を用いたジェチレントリアミン五酢酸(DTPA)塩の構造比較2011

    • Author(s)
      鹿釜秀康・尾関智二
    • Organizer
      平成23年度日本結晶学会年会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 球状モリブデン酸アニオンのアルカリ土類金属塩の結晶構造2011

    • Author(s)
      斎藤真毅・尾関智二
    • Organizer
      平成23年度日本結晶学会年会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 大環状ポリ酸の核数変化と高次構造2010

    • Author(s)
      尾関智二
    • Organizer
      日本化学会 第4回関東支部大会
    • Place of Presentation
      つくば大学
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Neutral polyoxovanadate with pendantaquo-hydroxo-copper groups2010

    • Author(s)
      T. Ozeki, T. Koroki, A. Iida
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] 「Effect of basicsolvents on dissociation of the protonated decavanadate dimers into the monomers by using 51V-NMR」2010

    • Author(s)
      T. Kojima, T. Ozeki
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] ボール型巨大ポリ酸内部の酢酸配位子交換反応の粉末X線回折法による追跡2010

    • Author(s)
      齋藤真毅, 尾関智二
    • Organizer
      平成22年度日本結晶学会年会
    • Place of Presentation
      大阪大学、大阪府吹田市
    • Related Report
      2012 Final Research Report
  • [Presentation] 環状混合原子価ポリ酸の生成機構および高次構造形成に関する結晶学的研究2010

    • Author(s)
      尾関智二
    • Organizer
      平成22年度日本結晶学会年会
    • Place of Presentation
      大阪大学、大阪府吹田市
    • Related Report
      2012 Final Research Report
  • [Presentation] 塩基性溶媒によるプロトン付加デカバナジン酸の自己集合の制御2010

    • Author(s)
      小島達弘, 尾関智二
    • Organizer
      平成22年度日本結晶学会年会
    • Place of Presentation
      大阪大学、大阪府吹田市
    • Related Report
      2012 Final Research Report
  • [Presentation] Controlling the coordination numbers of lanthanoidatoms by the use of multidentate polyoxometalate ligands2010

    • Author(s)
      T. Ozeki, Y. Kato, T. Shimono
    • Organizer
      The 10th Conference of the Asian Crystallographic Association (AsCA2010)
    • Place of Presentation
      Busan Exhibition& Convention Center (BEXCO), Busan, Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] The mechanism of thephase transition of tetraalkylammonium salt of decavnadate containing 1,4-dioxane molecules2010

    • Author(s)
      T. Kojima, T. Ozeki
    • Organizer
      The 10th Conference of the Asian Crystallographic Association (AsCA2010)
    • Place of Presentation
      Busan Exhibition & ConventionCenter (BEXCO), Busan, Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] 大環状ポリ酸の核数変化と高次構造2010

    • Author(s)
      尾関智二
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      筑波大学、茨城県つくば市
    • Related Report
      2012 Final Research Report
  • [Presentation] Coordination Numbers ofLanthanoid Cations Chelated byMultidentate Polyoxometalate Ligands2010

    • Author(s)
      T. Ozeki
    • Organizer
      Frontiers in Metal Oxide Cluster Science, IAS (The Institute for Advanced Studies) - ISF (Israel Science Foundation) Conferences
    • Place of Presentation
      Hebrew University of Jerusalem, Jerusalem, Israel
    • Related Report
      2012 Final Research Report
  • [Book] ハウスクロフト無機化学2012

    • Author(s)
      巽和行, 西原寛, 穐田宗隆, 酒井健 監訳, 穐田宗隆, 石井洋一, 石田斉, 上野圭司, 尾関智二, 加藤昌子, 酒井健, 棚瀬知明,坪村太郎, 西原寛, 長谷川美貴, 水田勉訳
    • Publisher
      東京化学同人
    • Related Report
      2012 Final Research Report
  • [Book] ハウスクロフト無機化学2012

    • Author(s)
      巽和行,西原寛,穐田宗隆,酒井健 監訳,穐田宗隆,石井洋一,石田斉,上野圭司,尾関智二,加藤昌子,酒井健,棚瀬知明,坪村太郎,西原寛,長谷川美貴,水田勉 訳
    • Total Pages
      1060
    • Publisher
      東京化学同人
    • Related Report
      2012 Annual Research Report
  • [Book] 金属錯体の機器分析(上)2010

    • Author(s)
      石黒慎一, 尾関智二, 海崎純男, 神崎亮,齋藤一弥, 坂本良太, 寺岡淳二, 西原寛
    • Publisher
      三共出版
    • Related Report
      2012 Final Research Report
  • [Book] 金属錯体の機器分析 上(分担、頁183~246)2010

    • Author(s)
      尾関智二
    • Total Pages
      286
    • Publisher
      三共出版株式会社
    • Related Report
      2010 Annual Research Report
  • [Remarks] 1.工大祭研究室公開(2011年10月22日)2.駒込高等学校大学見学会(2012年6月15日)

    • URL

      http://www.polyoxo.cms.titech.ac.jp/

    • Related Report
      2012 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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