Control of 1D chain structure constructed from half-lantern complexes with biimidazole ligand

Research Project

Project/Area Number	22550058
Research Category	Grant-in-Aid for Scientific Research (C)
Allocation Type	Single-year Grants
Section	一般
Research Field	Inorganic chemistry
Research Institution	Gifu University
Principal Investigator	EBIHARA Masahiro 岐阜大学, 工学部, 教授 (80201961)
Co-Investigator(Kenkyū-buntansha)	UEMURA Kazuhiro 岐阜大学, 工学部, 助教 (60386638)
Project Period (FY)	2010 – 2012
Project Status	Completed (Fiscal Year 2012)
Budget Amount *help	¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000) Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000) Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000) Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords	多核錯体 / ロジウム / ビイミダゾール / 水素結合 / 複核錯体 / 一次元鎖 / 白金
Research Abstract	Dirhodium complexes with biimidazole ligand were synthesized and their structures were determined. Because of their relatively high reduction potentials, one dimensional chain structures were not obtained. A novel dimer of dinuclear complexes with biimidazolate ligand showed two step oxidation.