Control of 1D chain structure constructed from half-lantern complexes with biimidazole ligand
Project/Area Number |
22550058
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | Gifu University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
UEMURA Kazuhiro 岐阜大学, 工学部, 助教 (60386638)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 多核錯体 / ロジウム / ビイミダゾール / 水素結合 / 複核錯体 / 一次元鎖 / 白金 |
Research Abstract |
Dirhodium complexes with biimidazole ligand were synthesized and their structures were determined. Because of their relatively high reduction potentials, one dimensional chain structures were not obtained. A novel dimer of dinuclear complexes with biimidazolate ligand showed two step oxidation.
|
Report
(4 results)
Research Products
(3 results)