Development of on-off controllable photochromic dinuclear ruthenium complexes by redox switch
| Project/Area Number |
22550062
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
YAMAGUCHI Motoo 首都大学東京, 都市環境科学研究科, 教授 (60174637)
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| Co-Investigator(Kenkyū-buntansha) |
SATO Kiyoshi 首都大学東京, 都市環境科学研究科, 准教授 (40285101)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 多核錯体 / フォトクロミズム / ルテニウム錯体 / 二核錯体 / 光配位子置換反応 / オンオフ制御 / 酸化還元スイッチ / 光配位子反応 |
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| Research Abstract |
Pyrazine-bridged dinuclear ruthenium complexes show color change in solution by selective dissociation of the bridging ligand under visible-light irradiation. The dinuclear complexes display photochromic behavior, since they are recovered by heating. In this study, we synthesized the dinuclear complexes having redox responsive switchingmoieties, such as benzoquinone and hydroquinone, and the photodissociation rates of these complexes have been measured. It was found that the photodissociation rate of thedinuclear complexes having benzoquinone moieties was depressed. The observation suggests that the application of the complexes developed in this study to the new photochromic material which is controllable by external factor would be possible.
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Report
(4 results)
Research Products
(51 results)
