First transition metal catalyst toward artificial photosynthesis
Project/Area Number |
22550064
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Osaka City University |
Principal Investigator |
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Co-Investigator(Renkei-kenkyūsha) |
HAMAZAWA Rika 大阪市立大学, 技術員 (80433316)
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Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 光合成 / 錯体化学 / 銅錯体 / 人工光合成 / トリポッド配位子 / 金属炭素結合 / 混合原子価 / ケト-エノール平衡 / トリポッド錯体 / 鉄錯体 / 亜鉛錯体 / 二酸化炭素 / 金属錯体化学 / 環境科学 / 資源化学 |
Research Abstract |
This research aimed to realize artificial photosynthesis (APS) for practical usage. As the first step for this movement, we intended to use the first transition metal complexes as the catalyst for APS. Usually, relatively rare metals such as Ru and Pt act
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Report
(4 results)
Research Products
(40 results)
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[Journal Article] Redox-Controlled, Reversible Rearrange-ment of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an "N,S-Confused" 2-Pyridylthiolate Arm.2011
Author(s)
Kuwamura, N., Kitano, K., Hirotsu, M., Nishioka, T., Teki, Y., Santo, R., Ichimura, A., Hashimoto, H., Wright, L. James; Kinoshita, I.
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Journal Title
Chemistry-A European Journal.
Volume: 17
Issue: 38
Pages: 10708-10715
DOI
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[Journal Article] Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes.2010
Author(s)
Kuwamura, N., Ryo Kato, Kitano,K., Hirotsu, M., Nishioka, T., Hashimoto, H., Kinoshita, I.
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Journal Title
Dalton Trans.
Volume: 39
Issue: 41
Pages: 9988-9993
DOI
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