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Used of transfer technology of latex particles in oil/water interface to imitating interfacial reaction of huge biomolecular

Research Project

Project/Area Number 22550072
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionUniversity of Fukui

Principal Investigator

CHEN Jingyuan  福井大学, 大学院・工学研究科, 准教授 (50311676)

Co-Investigator(Kenkyū-buntansha) AOKI Koichi  福井大学, 大学院・工学研究科, 教授 (80142264)
NISIUMI Toyohiko  福井大学, 大学院・工学研究科, 准教授 (10377476)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords電気化学 / 油水界面 / イオン化ラテックス粒子 / 自発乳化 / 水銀分散 / 水素気泡 / 統計熱力学 / 微小電極 / 液体金属粒子 / 交流インピーダンス / 水銀 / エマルション / 水素ガス / 気水界面 / 光散乱 / ラテックス / 遠心分離 / 荷電高分子球 / ヒドロゲル粒子 / 固体電解質 / 光学 / 懸濁液
Research Abstract

Ionic latex particles were examined electrochemically and optically in the light of possibility of simulated biomolecules. Oil droplets and water droplets were found to be formed spontaneously near interfaces between oil and water phases, regardless of the latex. The formation of the droplets at the interface was applied to the gas|water interface and the mercury|water interface. Hydrogen bubbles were dispersed in water spontaneously, and kept stable. Metal mercury droplets were also dispersed in water. One of researchers was an invited speaker in ninth international conference (9ECHEMS) for electrochemistry of nano particles, droplets and bubbles.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (51 results)

All 2013 2012 2011 2010 Other

All Journal Article (24 results) (of which Peer Reviewed: 24 results) Presentation (22 results) (of which Invited: 1 results) Remarks (5 results)

  • [Journal Article] Self-Dispersion of Mercury Droplets from Saturated Calomel Electrodes into Solutions2013

    • Author(s)
      J. Chen, K. Iwama, K. J. Aoki, T. Nishiumi
    • Journal Title

      Int. J. Electrochem. Sci

      Volume: Vol.8 Pages: 7394-7400

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetry in low concentration of electrolyte supported by ionic latex suspensions2013

    • Author(s)
      K. J. Aoki, X. Zhao, J. Chen, T. Nishiumi
    • Journal Title

      J. Electroanal. Chem

      Volume: Vol.697 Pages: 5-9

    • NAID

      120005373677

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Salt-free electrolysis of water facilitated by hydrogen gas in thin layer cell2013

    • Author(s)
      C. Li, K. J. Aoki, J. Chen, T. Nishiumi
    • Journal Title

      Reports in Electrochem

      Volume: (印刷中)

    • NAID

      120005373700

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Slow scan voltammetry for diffusion-controlled currents in sodium alginate solutions2013

    • Author(s)
      B. Wang, K. J.Aoki, J. Chen, T. Nishiumi
    • Journal Title

      J. Electroanal. Chem

      Volume: Vol.700 Pages: 60-64

    • NAID

      120005386059

    • URL

      http://dx.doi.org/10.1016/j.jelechem.2013.04.018

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Dispersion of Mercury Droplets from Saturated Calomel Electrodes into Solutions2013

    • Author(s)
      Jingyuan Chen
    • Journal Title

      Int. J. Electrochem. Sci.,

      Volume: 8 Pages: 7394-7400

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetry in low concentration of electrolyte supported by ionic latex suspensions2013

    • Author(s)
      Koichi Aoki
    • Journal Title

      J. Electroanal. Chem.,

      Volume: 697 Pages: 5-9

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Resistance associated with measurements of capacitance in electric double layers2013

    • Author(s)
      Koichi Aoki
    • Journal Title

      J. Electroanal. Chem.,

      Volume: 689 Pages: 124-129

    • DOI

      10.1016/j.jelechem.2012.10.004

    • NAID

      120005296503

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrolysis of pure water in a thin layer cell2013

    • Author(s)
      Koichi Aoki
    • Journal Title

      J. Electroanal. Chem.,

      Volume: 695 Pages: 24-29

    • DOI

      10.1016/j.jelechem.2013.02.020

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Is hydrogen gas in water present as bubbles or hydrated form2012

    • Author(s)
      K. Aoki, H. Toda, J. Yamamoto, J. Chen, T. Nishiumi
    • Journal Title

      J.Electroanal. Chem

      Volume: Vol.668 Pages: 83-89

    • NAID

      120004009101

    • URL

      http://dx.doi.org/10.1016/j.jelechem.2012.01.013

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of diameters of disk microelectrodes obtained from microscopes with those evaluated from steady-state currents2012

    • Author(s)
      K. Aoki, C. Ouyang, C. Zhang, J. Chen, T. Nishiumi
    • Journal Title

      Int. J. Electrochem. Sci

      Volume: Vol.7 Pages: 5880-5892

    • URL

      http://www.electrochemsci.org/papers/vol7/7075880.pdf

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diffusion coefficients in viscous sodium alginate solutions2012

    • Author(s)
      Koichi Aoki
    • Journal Title

      Electrochim. Acta.,

      Volume: 83 Pages: 348-353

    • DOI

      10.1016/j.electacta.2012.08.004

    • NAID

      120005296502

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-dispersion of mercury metal into aqueous solutions2012

    • Author(s)
      Koichi Aoki
    • Journal Title

      J. Electroanal. Chem.,

      Volume: 682 Pages: 66-71

    • DOI

      10.1016/j.jelechem.2012.07.003

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of diameters of disk microelectrodes obtained from microscopes with those evaluated from steady-state currents2012

    • Author(s)
      Koichi Aoki
    • Journal Title

      Int. J. Electrochem. Sci.,

      Volume: 7 Pages: 5880-5892

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Is hydrogen gas in water present as bubbles or hydrated form?2012

    • Author(s)
      K.Aoki, H.Toda, J.Yamamoto, J.Chen, T.Nishiumi
    • Journal Title

      J.Electroanal.Chem.

      Volume: 668 Pages: 83-89

    • DOI

      10.1016/j.jelechem.2012.01.013

    • NAID

      120004009101

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric determination of concentrations of ferrocene-included nitrobenzene droplets in water2011

    • Author(s)
      M. Li, K. Aoki, J. Chen, T. Nishiumi
    • Journal Title

      J. Electroanal. Chem.

      Volume: Vol.655 Pages: 159-163

    • NAID

      120003002588

    • URL

      http://dx.doi.org/10.1016/j.jelechem.2011.02.015

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric electrodes modified with swollen polyacrylic latex particles2011

    • Author(s)
      T. Li, K. Aoki, J. Chen, T. Nishiumi
    • Journal Title

      J. Electroanal. Chem

      Volume: Vol. 656 Pages: 279-284

    • NAID

      120003002587

    • URL

      http://dx.doi.org/10.1016/j.jelechem.2010.10.009

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diffusion-controlled current at elliptically deformed microelectrodes2011

    • Author(s)
      K. Aoki, C. Ouyang, J. Chen, T. Nishiumi
    • Journal Title

      J. Solid State Electrochem

      Volume: Vol.15 Pages: 2305-2309

    • NAID

      120004009100

    • URL

      http://dx.doi.org/10.1007/s10008-011-1448-y

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric electrodes modified with swollen polyacrylic latex particles2011

    • Author(s)
      T.Li, K.Aoki, J.Chen, T.Nishium
    • Journal Title

      J.Electroanal.Chem.

      Volume: 656 Issue: 1-2 Pages: 279-284

    • DOI

      10.1016/j.jelechem.2010.10.009

    • NAID

      120003002587

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Radii of microelectrodes undervalued from steady-state currents2011

    • Author(s)
      K.Aoki, H.Takeuchi, J.Chen, T.Nishiumi
    • Journal Title

      Review of Polarography

      Volume: 57 Issue: 2 Pages: 101-119

    • DOI

      10.5189/revpolarography.57.101

    • NAID

      10029678128

    • ISSN
      0034-6691, 1884-7692
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Difiusion-controlled current at elliptically deformed microelectrodes2011

    • Author(s)
      K.Aoki, C.Ouyang, J.Chen, T.Nishiumi
    • Journal Title

      J.Solid State Electrochem.

      Volume: 15 Issue: 11-12 Pages: 2305-2309

    • DOI

      10.1007/s10008-011-1448-y

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric determination of concentrations of ferrocene-included nitrobenzene droplets in water2011

    • Author(s)
      M.Li
    • Journal Title

      J. Electroanal. Chem.

      Volume: 655 Pages: 159-163

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric electrodes modified with swollen polyacrylic latex particles2011

    • Author(s)
      T.Li
    • Journal Title

      J. Electroanal. Chem.

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetry in viscous poly (ethylene glycol) solutions at microelectrodes2011

    • Author(s)
      Y.Guo
    • Journal Title

      Electrochim. Acta.

      Volume: 56 Pages: 3727-3730

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Voltammetric Determination of Both Concentration and Diffusion Coefficient by Combinational Use of Large and Small Electrodes2011

    • Author(s)
      H.Zhang
    • Journal Title

      Electroanalysis

      Volume: 23 Pages: 947-952

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Voltammetry of hydrogen bubbles, latex particles and oil droplets2013

    • Author(s)
      J. Chen
    • Organizer
      9^<th> ECHEMS Meeting
    • Place of Presentation
      Lochow, Poland
    • Related Report
      2012 Final Research Report
  • [Presentation] Voltammetry of hydrogen bubbles, latex particles and oil droplets2013

    • Author(s)
      Jingyuan Chen
    • Organizer
      9th ECHEMS Meeting
    • Place of Presentation
      Lochow, Poland
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 油|水|電極の三相界面における反応層の厚さの自発的エマルションによる変化2012

    • Author(s)
      陳競鳶
    • Organizer
      第77回日本電気化学会春年会
    • Place of Presentation
      浜松
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Voltammetric determination of self-emulsified mercury metal in aqueous solution2012

    • Author(s)
      J. Chen, K. Aoki, C. Li
    • Organizer
      The 14th International Conference on Electroanalysis
    • Place of Presentation
      Slovenia, Portoroz
    • Related Report
      2012 Final Research Report
  • [Presentation] Contribution of Emulsification to Thickness of Three-Phase Boundaries2012

    • Author(s)
      J. Chen, K. Aoki, Q. Wang, J. Yu
    • Organizer
      63rd Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Prague, Czech Republic
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 薄層油膜電極におけるエマルションが引き起こす反応2012

    • Author(s)
      陳競鳶、Jie Yu、青木幸一、西海豊彦
    • Organizer
      第58回ポーラログラフィーおよび電気分析化学討論
    • Place of Presentation
      八王子市
    • Related Report
      2012 Final Research Report
  • [Presentation] 油|水|電極の三相界面における反応層の厚さの自発的エマルションによる変化2012

    • Author(s)
      陳競鳶、Qian Wang、青木幸一、西海豊彦
    • Organizer
      日本電気化学会 77回学会
    • Place of Presentation
      浜松
    • Related Report
      2012 Final Research Report
  • [Presentation] Voltammetric determination of self-emulsified mercury metal in aqueous solution2012

    • Author(s)
      Jingyuan Chen
    • Organizer
      The 14th International Conference on Electroanalysis
    • Place of Presentation
      Slovenia, Portoro&#382;
    • Related Report
      2012 Annual Research Report
  • [Presentation] 薄層油膜電極におけるエマルションが引き起こす反応2012

    • Author(s)
      陳 競鳶
    • Organizer
      第58回ポーラログラフィーおよび電気分析化学討論
    • Place of Presentation
      八王子市 日本
    • Related Report
      2012 Annual Research Report
  • [Presentation] 電気化学法による油水界面に生成したエマルション量の測定2011

    • Author(s)
      陳競鳶、Jie Yu、青木幸一、西海豊彦
    • Organizer
      第57回ポーラログラフィーおよび電気分析化学討論
    • Place of Presentation
      沖縄
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Voltammetry of the carboxylate functionalized particles-modified electrodes2011

    • Author(s)
      T. Li, K. Aoki, J. Chen
    • Organizer
      61th The Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy
    • Place of Presentation
      Atlanta, GA. USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Multistep Spontaneously Formed Emulsions at Water|Nitrobenzene Interface2011

    • Author(s)
      M. Li, K. Aoki, J. Chen
    • Organizer
      13th International Symposium on Electroanalytical Chemistry
    • Place of Presentation
      Changchun, China
    • Related Report
      2012 Final Research Report
  • [Presentation] Voltammetry of Ferrocenyl Derivatives at Glass-coated Platinum Nano-electrodes2011

    • Author(s)
      Jingyuan Chen
    • Organizer
      62th Annual Meeting of International Society of Electro chemistry
    • Place of Presentation
      Niigata, Japan
    • Related Report
      2011 Annual Research Report
  • [Presentation] Voltammetric Determination of Nano-electrodes2011

    • Author(s)
      Jingyuan Chen
    • Organizer
      13^<th> International Symposium on Electroanalytical Chemistry
    • Place of Presentation
      Changchun, China
    • Related Report
      2011 Annual Research Report
  • [Presentation] Multistep Spontaneously Formed Emulsions at Water Nitrobenzene Interface2011

    • Author(s)
      M.Li
    • Organizer
      13^<th> International Symposium on Electroanalytical Chemistry
    • Place of Presentation
      Changchun, China
    • Related Report
      2011 Annual Research Report
  • [Presentation] Voltammetry of Carboxyl Functionalized Particle Films2011

    • Author(s)
      T.Li
    • Organizer
      13^<th> International Symposium on Electroanalytical Chemistry
    • Place of Presentation
      Changchun, China
    • Related Report
      2011 Annual Research Report
  • [Presentation] Voltammetric variations with structure of latex particles2011

    • Author(s)
      Jingyuan Chen
    • Organizer
      International Symposium on Electroanalytical Chemistry Shikata Discussion 2011
    • Place of Presentation
      Awaji, Japan
    • Related Report
      2011 Annual Research Report
  • [Presentation] Voltammetry of the carboxylate functionalized particles-modified electrodes2011

    • Author(s)
      Jingyuan Chen
    • Organizer
      PITTCON 2011
    • Place of Presentation
      Atlanta, GA. USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリエチレングルコール高粘度溶液における微小電極のボルタンメトリー2010

    • Author(s)
      陳競鳶
    • Organizer
      第56回ポーラログラフィーおよび電気分析化学討論
    • Place of Presentation
      秋田大学(秋田市)
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 微小電極のボルタンメトリーによる酸化還元種の濃度・拡散係数の測定2010

    • Author(s)
      陳競鳶
    • Organizer
      日本電気化学会秋大会
    • Place of Presentation
      神奈川工科大学(厚木市)
    • Year and Date
      2010-09-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Determination of concentration and diffusion coefficient by the combination of regular and micro electrodes2010

    • Author(s)
      Jingyuan Chen
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Relation between oxidation current of hydrogen gas and amount of the bubbles in aqueous solution2010

    • Author(s)
      H.Toda
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://asura.apphy.u-fukui.ac.jp/~chen/

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.echems9.pl/scientific-profile

    • Related Report
      2012 Final Research Report
  • [Remarks] 研究室

    • URL

      http://asura.apphy.u-fukui.ac.jp/~chen/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://asura.apphy.u-fukui.ac.jp/~chen/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://asura.apphy.u-fukui.ac.jp/~chen/

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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