Generation rate of two-dimensional chirality by surface adsorption of dye molecules and formation of chiral domains

• Project/Area Number: 22550082
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Analytical chemistry
• Research Institution: Tokyo University of Science
• Principal Investigator: MIYAMURA Kazuo 東京理科大学, 理学部化学科, 教授 (40157673)
• Co-Investigator(Kenkyū-buntansha): TOMONO Kazuaki 東京理科大学, 理学部化学科, 助教(現在は山口高専に在籍) (40516449)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: STM / 表面 / 吸着 / 構造 / キラリティー / インジゴ / アルキル基 / 動的挙動 / 二量体 / 走査トンネル顕微鏡 / 色素 / 表面吸着 / 金属錯体 / 表面配列 / 分子観察 / 表面構造 / 吸着構造 / キラルドメイン / 二次元キラリティー / インダントロン

Research Abstract

We have successfully observed the two-dimensional chirality that dye molecules and metal complexes form on graphite surface. Both molecules exhibited homochiral domains. Furthermore, we have successfully observed the dynamic behavior of them.

Research Products

• [Journal Article] Bull. Chem (2013)
  • Author(s): Urano, K.; Ohno, T.; Tomono, K.; Miyamura K
  • Journal Title: Soc. Jpn Volume: 86 Pages: 159-164
• [Journal Article] Observation of Dynamic Behavior of Self-Assembled N-icosyl Substituted Indigo by STM (2013)
  • Author(s): (Kazuki Urano), Toshikazu Ohno, Kazuaki Tomono, Kazuo Miyamura
  • Journal Title: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN Volume: 86 Pages: 159-165
  • NAID: 10031143778
  • Peer Reviewed
• [Journal Article] Bull. Chem (2012)
  • Author(s): Urano, K.; Tomono, K.; Miyamura, K
  • Journal Title: Soc. Jpn Volume: 85 Pages: 822-829
• [Journal Article] Bull. Chem (2012)
  • Author(s): Tamaki, Y.; Tomono, K.; Hata, Y.; Saita, N.; Yamamoto, T.; Miyamura, K
  • Journal Title: Soc. Jpn Volume: 85 Pages: 592-598
• [Journal Article] Observation of Adsorbed Schiff-Base Copper(II) Complexes Substituted with N-Alkyl Chains of Various Length by STM (2012)
  • Author(s): (Kazuki Urano), Kazuaki Tomono, Kazuo Miyamura
  • Journal Title: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN Volume: 85 Issue: 7 Pages: 822-829
  • DOI: 10.1246/bcsj.20120061
  • NAID: 130004153090
  • Peer Reviewed
• [Journal Article] Observation of Different Molecular Alignments of [Ni(salphen)] Substituted by a Different Number of Octyl Groups at HOPG Surface (2012)
  • Author(s): (Yoshinori Tamaki), Kazuaki Tomono, Yuki Hata, Nanami Saita, Takashi Yamamoto, Kazuo Miyamura
  • Journal Title: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN Volume: 85 Pages: 592-598
  • NAID: 10030618855
  • Peer Reviewed
• [Journal Article] Bull. Chem (2011)
  • Author(s): Dai, K.; Tomono, K.; Miyamura, K
  • Journal Title: Soc. Jpn Volume: 84 Pages: 312-319
• [Journal Article] Crystal Structure of Dimethyldodecylhexadecylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III) (2011)
  • Author(s): K.Dai, S.Kusunoki, M.Hirota, K.Tomono, K.Miyamura
  • Journal Title: X-ray Structure Analysis Online Volume: 27 Pages: 35-36
  • NAID: 130004953603
  • Peer Reviewed
• [Journal Article] Synthesis, crystal structure and spectroscopic studies of copper(II) complex of C-meso-1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane (2011)
  • Author(s): K.Tomono, E.Otani, R.Ikeda, Y.Soneta, N.Saita, K.Miyamura
  • Journal Title: Journal of Inclusion Phenomena and Macrocyclic Chem Volume: 70 Issue: 1-2 Pages: 241-247
  • DOI: 10.1007/s10847-010-9900-7
  • Peer Reviewed
• [Journal Article] Odd-even Effect and Unusual Behavior of Dodecyl Substituted Analogue Observed in the Crystal Struture of Alkyltrimethylammonium-[Ni(dmit)2]- (2011)
  • Author(s): K.Dai, K.Tomono, K.Miyamura
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 84 Pages: 312-317
  • Peer Reviewed
• [Journal Article] Synthesis, crystal structure and spectroscopic studies of copper(II) complex of C-meso-1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane (2011)
  • Author(s): K.Tomono, E.Otani, R.Ikeda, Y.Soneta, N.Saita, K.Miyamura
  • Journal Title: J.Incl.Phenom.Macrocycl.Chem. Volume: (電子媒体)
  • Peer Reviewed
• [Journal Article] Odd-even Effect and Unusual Behavior of Dodecyl Substituted Analogue Observed in the Crystal Structure of Alkryltrimethylammonium-[Ni(dmit)2]- Salts (2011)
  • Author(s): K.Dai, K.Tomono, K.Miyamura
  • Journal Title: Bull.Chem.Soc.Jpn. Volume: 84 Pages: 312-319
  • Peer Reviewed
• [Presentation] Advanced Nanomaterials (2012)
  • Author(s): Miyamura, K.; Urano, K.; Ohno, T
  • Organizer: 1st International Conference on Emerging
  • Year and Date: 2012-10-23
• [Presentation] 吸着色素分子が示す表面キラリティーとその動的挙動 (2012)
  • Author(s): 宮村一夫
  • Organizer: 第13回機能構造と分析化学シンポジウム
  • Place of Presentation: 東北大学
  • Year and Date: 2012-02-18
• [Presentation] (2012)
  • Author(s): Miyamura, K.; Urano, K
  • Organizer: 10th Symposium on Chemical Approaches to Chirality
  • Year and Date: 2012-02-14
• [Presentation] Slow dynamics of the 2-dimensional chiral domain constituted of indigo dye derivatives (2010)
  • Author(s): K.Miyamura, T.Ohno, K.Tomono
  • Organizer: 2^<nd> International Symposium on the Soai Reaction and Related Topic
  • Place of Presentation: Felsomocsolad, Hungary
  • Year and Date: 2010-09-12
• [Presentation] Observation of Chiral Nanostructure Constituted of Achiral Indigo Dye Derivatives and its Sow Dynamics
  • Author(s): (Kazuo Miyamura), Kazuki Urano, Yoshikazu Ohno
  • Organizer: 1st International Conference on Emerging Advanced Nanomaterials - 2012
  • Place of Presentation: 豪州ブリスベン
  • Invited
• [Presentation] HOPG表面におけるPigment Red 234及びその誘導体の配列構造解析
  • Author(s): （本田暁紀）、宮村一夫
  • Organizer: 日本分析化学会第６１年会
  • Place of Presentation: 金沢大学
• [Presentation] アルキル基置換シッフ塩基Cu(II)錯体におけるアルキル鎖長に伴う表面配列構造変化
  • Author(s): （浦野翔輝）、佐伯雅弘、宮村一夫
  • Organizer: 錯体化学第６２討論会
  • Place of Presentation: 富山大学
• [Presentation] ジフェニルグリオキシムNi錯体の系統的アルコキシ鎖長変化に伴う自己集合構造解析
  • Author(s): （篠崎紗季）、阿部桂市、友野和哲、宮村一夫
  • Organizer: 錯体化学第６２討論会
  • Place of Presentation: 富山大学
• [Presentation] TCDBとのホスト－ゲスト硬貨を用いた金属錯体の表面配列構造
  • Author(s): （堀江碧香子）、古川信太郎、阿部桂市、宮村一夫
  • Organizer: 錯体化学第６２討論会
  • Place of Presentation: 富山大学
• [Remarks]
  • URL: http://www.rs.kagu.tus.ac.jp/miyamura/miyaken.html
• [Remarks]
  • URL: http://www.rs.kagu.tus.ac.jp/miyamura/miyaken.html