Development of in-situ X-ray absorption laboratory spectrometer for aqueous metal complexes

• Project/Area Number: 22550088
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Analytical chemistry
• Research Institution: Fukuoka University
• Principal Investigator: KURISAKI Tsutomu 福岡大学, 理学部, 助教 (20268973)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: X 線吸収分光法 / 溶存構造 / 金属錯体 / 装置開発 / X線吸収スペクトル / in-situ / 触媒能 / 溶存構造解析

Research Abstract

We started to design and develop our laboratory measurement system for X-ray absorption spectrometer. This spectrometer consists of small X-ray tube, SDD detector and laptop computer. The spectrometer is covered with lead glass case, and X-rays from the tube are shielded with the case at the time of measurement. We performed the spectrum measurement of synthesized copper complexes. The measured spectra analyzed by a DV-Xα method.

Research Products

• [Journal Article] Bromo(1,4,7,10,13-pentaazacyclohexa decane)cobalt(III) Bromide (2013)
  • Author(s): T. Kurisaki, M. Hamano, H. Wakita
  • Journal Title: Dihydrate, Acta Cryst. E Volume: 69 Issue: 4 Pages: 179-180
  • DOI: 10.1107/s1600536813004947
  • Peer Reviewed
• [Journal Article] Visible-light photocatalysis with phosphorus-doped titanium(IV) oxide particlesprepared using a phosphide compound (2013)
  • Author(s): M. Iwase, K. Yamada, T. Kurisaki
  • Journal Title: Applied Catalysis B Volume: 132-133 Pages: 39-44
  • DOI: 10.1016/j.apcatb.2012.11.014
  • Peer Reviewed
• [Journal Article] Characterization and photocatalytic activity of nitrogen-doped titanium(IV) oxide prepared by doping titania with TiN powder (2013)
  • Author(s): M. Iwase, K. Yamada, T. Kurisaki, H.Wakita
  • Journal Title: Applied Catalysis A Volume: 455 Pages: 86-91
  • DOI: 10.1016/j.apcata.2013.01.016
  • Peer Reviewed
• [Journal Article] Surface Analysis of Ionic Liquids with and without Lithium salt Using x-ray Photoelectron Spectroscopy (2012)
  • Author(s): Tsutomu Kurisaki, et al.
  • Journal Title: J. Phys. Chem. B Volume: 116 Issue: 35 Pages: 7322-7327
  • DOI: 10.1021/jp301658k
  • Peer Reviewed
• [Journal Article] 軟X線吸収分光法を用いた水溶液中のナトリウムおよびマグネシウムイオンの溶存構造解析 (2012)
  • Author(s): 栗崎敏、三木祐典
  • Journal Title: 福岡大学理学集報 Volume: 42(1) Pages: 29-35
  • NAID: 110008915863
  • Peer Reviewed
• [Journal Article] 軟X線吸収分光法による固体および溶液中の軽元素の状態分析 (2011)
  • Author(s): 栗崎敏、三木祐典
  • Journal Title: X線分析の進歩 Volume: 42 Pages: 281-290
  • NAID: 40018795863
  • Peer Reviewed
• [Journal Article] 新規リンドープ酸化チタンのXRD・XPSによる解析 (2011)
  • Author(s): 岩瀬元希、藤尾侑輝、長濱俊、山田啓二、栗崎敏、脇田久伸
  • Journal Title: X線分析の進歩 Volume: 42 Pages: 213-219
  • Peer Reviewed
• [Journal Article] 軟X線吸収分光法による個体および溶液中の軽元素の状態分析 (2011)
  • Author(s): 栗崎敏
  • Journal Title: X線分析の進歩 Volume: 42 Pages: 281-290
  • Peer Reviewed
• [Journal Article] 軟X線分光スペクトル測定装置用生体試料測定システムの設計・開発・性能評価 (2010)
  • Author(s): 栗崎敏、迫川泰幸、松尾修司、脇田久伸
  • Journal Title: X線分析の進歩 Volume: 41 Pages: 165-170
  • NAID: 40017068134
  • Peer Reviewed
• [Presentation] 各種トリアザ環銅錯体の溶存構造と触媒能との相関 (2012)
  • Author(s): 栗崎敏、横山尚平、常住勇弥、脇田久伸
  • Organizer: 日本分析化学会第61年会金沢
  • Place of Presentation: 金沢
  • Year and Date: 2012-09-21
• [Presentation] DV-Xα法を用いた軽金属イオンの溶存構造解析 (2012)
  • Author(s): 栗崎敏、脇田久伸
  • Organizer: 第25回DV-Xα研究会
  • Place of Presentation: 福岡
  • Year and Date: 2012-08-06
• [Presentation] 軟X線吸収分光法を用いた塩化ナトリウムおよび臭化ナトリウム水溶液中のナトリウムイオンの溶存構造解析 (2012)
  • Author(s): 栗崎敏、南慧多、横山尚平、岩瀬元希、脇田久伸
  • Organizer: 第72回分析化学討論会
  • Place of Presentation: 鹿児島
  • Year and Date: 2012-05-20
• [Presentation] 各種トリアザ環銅錯体の溶存構造と触媒能との相関 (2012)
  • Author(s): 栗崎 敏
  • Organizer: 日本分析化学会第61年会
  • Place of Presentation: 金沢
• [Presentation] ポリキャピラリー集光レンズを導入した生体試料測定システムを用いる水溶液中の軽金属イオンの溶存構造解析 (2011)
  • Author(s): 栗崎敏,横山尚平、南慧多、岩瀬元希、脇田久伸
  • Organizer: 第47回X線分析討論会
  • Place of Presentation: 福岡
  • Year and Date: 2011-10-29
• [Presentation] The Characterization of Light Element Ions in Aqueous Solution by Soft X-ray Absorption Spectral Measurement Apparatus using Polycapillary X-ray Optics (2011)
  • Author(s): T. Kurisaki、Y. Sakogawa, Y. Miki, S.Kokubu, K. Minami, S. Yokoyama, and H. Wakita
  • Organizer: International Congress on Analytical Sciences 2011
  • Place of Presentation: 京都
  • Year and Date: 2011-05-24
• [Presentation] The Characterization of Light Element Ions in Aqueous Solution by Soft X-ray Absorption Spectral Measurement Apparatus using Polycapillary X-ray Optics (2011)
  • Author(s): T.Kurisaki
  • Organizer: ICAS2011
  • Place of Presentation: 国立京都国際会館(京都)
  • Year and Date: 2011-05-24
• [Presentation] X-ray absorption spectroscopic characterization of Phosphorus-doped TiO2 with visible-light photocatalytic activity (2010)
  • Author(s): M. Iwase, K. Yamada, T. Kurisaki, H.Wakita
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu、USA
  • Year and Date: 2010-12-19
• [Presentation] Characterization of minerals and archeological samples by soft X-ray spectroscopy (2010)
  • Author(s): T. Kurisaki, D. Tanaka, S. Kokubu, H.Wakita
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu、USA
  • Year and Date: 2010-12-18
• [Presentation] X線吸収スペクトル測定装置の開発と各種金属イオンおよび金属錯体の溶存構造解析 (2010)
  • Author(s): 栗崎敏
  • Organizer: 第46回X線分析討論会
  • Place of Presentation: 広島
  • Year and Date: 2010-10-22
• [Presentation] Characterization of Light Element Ions in Aqueous Solution by Soft X-ray Absorption Spectroscopy using Liquid Cell System (2010)
  • Author(s): T. Kurisaki、Y. Sakogawa、H. Wakita
  • Organizer: 6th International Conference on DV-Xα and the 23rd DV-Xα Annual Meeting
  • Place of Presentation: Daejeon、Korea
  • Year and Date: 2010-08-04
• [Presentation] Electronic Structure of Phosphorus-doped TiO2with visible-light photocatalytic activity (2010)
  • Author(s): M. Iwase, S. Kokubu, K. Yamada, T.Kurisaki, H. Wakita
  • Organizer: 6th International Conference on DV-Xα and the 23rd DV-Xα Annual Meeting
  • Place of Presentation: Daejeon、Korea
  • Year and Date: 2010-08-04
• [Presentation] Characterization of Iron Slags and Lump Found from Reverberatory Furnace Vacant Lot by X-ray Absorption Spectroscopy (2) (2010)
  • Author(s): S. Kokubu, T. Kurisaki, H. Wakita
  • Organizer: 6th International Conference on DV-Xα and the 23rdDV-Xα Annual Meeting
  • Place of Presentation: Daejeon、Korea
  • Year and Date: 2010-08-04
• [Presentation] The Characterization of Light Element Ions in Aqueous Solution by Soft X-ray Absorption Spectroscopy using Liquid Cell System (2010)
  • Author(s): T.Kurisaki
  • Organizer: The 6^<th> International Conference on DV-Xα and the 23^<rd> DV-XαAnnual Meeting
  • Place of Presentation: Korea Basic Science Institute(South Korea)
  • Year and Date: 2010-08-04