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Development and Scope of Homogeneous Reversible Dehydrogenation/ Hydrogenation by Means of Highly Functional Dehydrogenation Catalyst

Research Project

Project/Area Number 22550098
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionKyoto University

Principal Investigator

YAMAGUCHI Rhyohei  京都大学, 大学院・人間環境学研究科, 名誉教授 (40115960)

Co-Investigator(Kenkyū-buntansha) 藤田 健一  京都大学, 人間・環境学研究科(研究院), 准教授 (80293843)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords錯体・有機金属触媒 / 脱水素化反応 / 水素化反応 / 含窒素複素環 / 水素貯蔵システム / イリジウム錯体 / 有機金属錯体触媒 / 有機ヒドリド / イリジウム
Research Abstract

Novel iridium complex catalysts bearing a variety of functional ligands have been designed and synthesized, and homogeneous catalytic systems for dehydrogenation/hydrogenation of nitrogen heterocycles using these catalysts have been developed. As a result, an efficient dehydrogenation/hydrogenation catalytic system for organic hydride containing 6% hydrogen content under mild conditions has been successfully achieved, providing the basis for a new and effective hydrogen storage system.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2013 2012 2011 2010 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (16 results) (of which Invited: 1 results) Book (2 results)

  • [Journal Article] 機能性配位子を有するイリジウム錯体の創製と脱水素化反応触媒系の開発2013

    • Author(s)
      山口 良平
    • Journal Title

      Organometallic News

      Volume: 2013 Pages: 8-13

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone2012

    • Author(s)
      Ryoko Kawahara, Ken-ichi Fujita, Ryohei Yamaguchi
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 51 Pages: 12790-12794

    • DOI

      10.1002/anie.201206987

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydrogenative Oxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex Having a Functional C2011

    • Author(s)
      Ken-ichi Fujita, Tetsuya Yoshida, Yoichiro Imori, Ryohei Yamaguchi
    • Journal Title

      N-Chelate Ligand、ORGANIC LETTERS

      Volume: 13 Issue: 9 Pages: 2278-2281

    • DOI

      10.1021/ol2005424

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Information Sharing, Local Knowledge, and Development Practices: The Experience of Community-based HIV/AIDS Initiatives among the Gurage, Southern Ethiopia2011

    • Author(s)
      Nishi Makoto
    • Journal Title

      Nilo-Ethiopian Studies

      Volume: 15 Pages: 1-10

    • URL

      http://www.janestudies.org/drupal-jp/sites/default/files/NES_no15(2011)_NIshi.pdf

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 疫学的な他者と生きる身体-エチオピアのグラゲ社会におけるHIV/AIDSの経験2011

    • Author(s)
      西真如
    • Journal Title

      文化人類学

      Volume: 76 Pages: 267-287

    • URL

      http://ci.nii.ac.jp/naid/110008897503

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] ケアの政治学-アジア・アフリカ地域社会の視座2011

    • Author(s)
      西真如
    • Journal Title

      Kyoto Working Paper on Area Studies 119

      Pages: 30-30

    • URL

      http://hdl.handle.net/2433/155725

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] 機能性ビピリドナート系配位子を有するイリジウム錯体触媒を用いた含窒素複素環の可逆的脱水素化/水素化とその反応機構2013

    • Author(s)
      小林昌登・田中結依・藤田健一・山口良平
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学 びわこ・くさつキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Risk and Responsibility in the Era of Global Health: Public Health Interventions and Local Responses among the Gurage2012

    • Author(s)
      Nishi Makoto
    • Organizer
      18th International Conference of Ethiopian Studies
    • Place of Presentation
      Dire Dawa University,Ethiopia.
    • Year and Date
      2012-11-03
    • Related Report
      2012 Final Research Report
  • [Presentation] 服薬アドヒアランスに関する医療人類学的考察-アフリカから学ぶ、感染症治療に服薬者の社会関係が果たす役割2012

    • Author(s)
      西真如・姜明江
    • Organizer
      第53回日本社会医学会総会
    • Place of Presentation
      関西大学
    • Year and Date
      2012-07-16
    • Related Report
      2012 Final Research Report
  • [Presentation] 能性N,N-キレート配位子を有するイリジウム錯体触媒を用いた含窒素複素環の脱水素化および水素化反応2012

    • Author(s)
      田中結依
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
  • [Presentation] Life and Suffering in the Era of Global Health: Women with HIV in Rural Ethiopia2012

    • Author(s)
      Nishi Makoto
    • Organizer
      Translational Movements: Ethnographic Engagements with Technocultural Practices
    • Place of Presentation
      Osaka University.
    • Year and Date
      2012-03-04
    • Related Report
      2012 Final Research Report
  • [Presentation] 触媒的水素移動反応を基軸とする有機合成・分子変換2012

    • Author(s)
      山口良平
    • Organizer
      有機合成化学協会近畿支部・新春講演会
    • Place of Presentation
      大阪科学技術センター(招待講演)
    • Year and Date
      2012-01-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Dehydrogenative Oxidation of Primary and Secondary Alcohols under Mild Reaction Conditions Catalyzed by a Novel Cp*Ir Complex Bearing a Functional Bipyridonate Ligand2012

    • Author(s)
      Ryoko Kawahara, Ken-ichi Fujita, Ryohei Yamaguchi
    • Organizer
      第59回有機金属討論会
    • Place of Presentation
      大阪大学吹田キャンパスコンベンションセンター
    • Related Report
      2012 Annual Research Report
  • [Presentation] ピリジン系機能性N,O-キレート配位子を有する新規イリジウム錯体の合成と脱水素化反応における触媒活性2012

    • Author(s)
      山口 良平・小林 大記・藤田 健一
    • Organizer
      錯体化学会 第62回討論会
    • Place of Presentation
      富山大学五福キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 機能性配位子を有する Ir 錯体触媒を用いた含窒素複素環の可逆的脱水素化/水素化反応2012

    • Author(s)
      藤田 健一・田中 結依・波多野 諒・白石 巧充・山口 良平
    • Organizer
      第42回複素環化学討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2012 Annual Research Report
  • [Presentation] 新規イリジウム錯体触媒を用いた含窒素複素環の効果的脱水素化および水素化反応2011

    • Author(s)
      山口良平
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      崇城大学市民ホール
    • Year and Date
      2011-10-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] アフリカ社会における生存・ケア・レジリエンス2011

    • Author(s)
      西真如・戸田美佳子
    • Organizer
      日本人間の安全保障学会創立大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 機能性ビピリジン系配位子を有する新規Cp*イリジウム錯体触媒を用いた含窒素複素環の脱水素化および水素化反応2011

    • Author(s)
      田中結依
    • Organizer
      第58回有機金属討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Dehydrogenation-Hydrogenation Reactions of Nitrogen Heterocycles Catalyzed by Functional Cp*Ir Complexes2011

    • Author(s)
      山口良平
    • Organizer
      23rd International Congress on Heterocyclic Chemistry
    • Place of Presentation
      グラスゴー(イギリス)
    • Year and Date
      2011-08-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fight AIDS, Not People with AIDS: Public Health Interventions and HIV-Discordant Couples in Rural Ethiopia, JSPS Conference on Contextualizing Post- reconciliationViolence: Globalization2011

    • Author(s)
      Nishi Makoto
    • Organizer
      Politics and Identities in Africa
    • Place of Presentation
      Embassy of Japan, Nairobi.
    • Year and Date
      2011-01-20
    • Related Report
      2012 Final Research Report
  • [Presentation] ウイルスと検査キット-エチオピアの農村でHIVとともに生きる人びとの経験2010

    • Author(s)
      西真如
    • Organizer
      日本文化人類学会第44回研究大会
    • Place of Presentation
      立教大学
    • Year and Date
      2010-06-13
    • Related Report
      2012 Final Research Report
  • [Presentation] 機能性配位子を有するイリジウム錯体の創製と脱水素化反応触媒系の開発

    • Author(s)
      山口 良平
    • Organizer
      近畿化学協会有機金属部会
    • Place of Presentation
      大阪科学技術センター
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] 講座生存基盤論3人間圏の再構築-熱帯社会の潜在力2012

    • Author(s)
      速水洋子・西真如・木村周平
    • Total Pages
      396
    • Publisher
      都大学学術出版会
    • Related Report
      2012 Final Research Report
  • [Book] 講座生存基盤論5生存基盤指数2012

    • Author(s)
      西真如
    • Publisher
      京都大学学術出版会
    • Related Report
      2012 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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