Development and Scope of Homogeneous Reversible Dehydrogenation/ Hydrogenation by Means of Highly Functional Dehydrogenation Catalyst
Project/Area Number |
22550098
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Synthetic chemistry
|
Research Institution | Kyoto University |
Principal Investigator |
YAMAGUCHI Rhyohei 京都大学, 大学院・人間環境学研究科, 名誉教授 (40115960)
|
Co-Investigator(Kenkyū-buntansha) |
藤田 健一 京都大学, 人間・環境学研究科(研究院), 准教授 (80293843)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 錯体・有機金属触媒 / 脱水素化反応 / 水素化反応 / 含窒素複素環 / 水素貯蔵システム / イリジウム錯体 / 有機金属錯体触媒 / 有機ヒドリド / イリジウム |
Research Abstract |
Novel iridium complex catalysts bearing a variety of functional ligands have been designed and synthesized, and homogeneous catalytic systems for dehydrogenation/hydrogenation of nitrogen heterocycles using these catalysts have been developed. As a result, an efficient dehydrogenation/hydrogenation catalytic system for organic hydride containing 6% hydrogen content under mild conditions has been successfully achieved, providing the basis for a new and effective hydrogen storage system.
|
Report
(4 results)
Research Products
(24 results)