| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Research Abstract |
Organic reductants, prepared from electroreduction of bipyridinium and pyridinium derivatives, proceed C-C bond formation such as homo-coupling of aryl bromides and cross-coupling between aryl aldehydes and allyl bromides in the presence of transition metal catalysts. The organic reductants having amphiphilic substituents can promote the homo-coupling of aryl bromides in an aqueous environment. The C-C bond formation can be performed by using a catalytic amount of bipyridinium and pyridinium derivatives via in situ regeneration of the organic reductants by electroreduction.
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