Development of Recyclable Organic Reductants in Aqueous Environment
| Project/Area Number |
22550102
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
KUROBOSHI Manabu 岡山大学, 大学院・自然科学研究科, 准教授 (30242316)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 有機還元剤 / ビオロゲン / 有機電解還元 / パラジウム触媒 / ホモカップリング / ビアリール / 2,2'-ビピリジニウム誘導体 / 2,2’-ビピリジニウム誘導体 |
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| Research Abstract |
Organic reductants, prepared from electroreduction of bipyridinium and pyridinium derivatives, proceed C-C bond formation such as homo-coupling of aryl bromides and cross-coupling between aryl aldehydes and allyl bromides in the presence of transition metal catalysts. The organic reductants having amphiphilic substituents can promote the homo-coupling of aryl bromides in an aqueous environment. The C-C bond formation can be performed by using a catalytic amount of bipyridinium and pyridinium derivatives via in situ regeneration of the organic reductants by electroreduction.
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Report
(4 results)
Research Products
(13 results)
