| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Research Abstract |
The novel polymerization method for heterotactic polymers via free radical polymerization by using divinyl or pseudo-divinyl monomer was developed. In this method, vinyl groups were finely arranged in the solution by template molecules. The covalent bonding and hydroben bonding of methacrylic acid and catechol provided highly heterotactic and syndiotactic poly(methacrylic acid)s, respectively. Highly heterotactic poly(4-vinyl pyridine) was obtained by forming the inclusion complex with4-vinyl pyridine and cyclodextrin derivatives. The hetrotactic polymers were novel materils.
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