Development of Transition Metal-Initiated Controlled Polymerization of Diazocarbonyl Compounds
| Project/Area Number |
22550113
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
IHARA Eiji 愛媛大学, 大学院・理工学研究科, 教授 (90243592)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 高分子合成 / ジアゾ酢酸エステル / パラジウム錯体触媒 / パラジウム錯体 / 重合開始・停止機構 / MALDI-TOF-MS / 光機能性高分子 / ピレン / 蛍光スペクトル / 重合開始剤 |
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| Research Abstract |
The researcher in this project has succeeded in establishing a new synthetic method for carbon-carbon main chain polymers. The objective of this project was development of a method for controlling the polymerization with respect to the molecular weight and stereo structure of the resulting polymers. By using certain initiators based on palladium complexes, the objective was achieved in a certain extent.
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Report
(4 results)
Research Products
(31 results)
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[Journal Article] Pd-mediated Polymerization of Diazoacetates with Aromatic Ester Group: Synthesis and Photophysical Property of Poly(1-pyrenylmethoxycarbonylmethylene).2013
Author(s)
Eiji Ihara, Ryoji Okada, Takanobu Sogai, Tetsuya Asano, Masami Kida, Kenzo Inoue, Tomomichi Itoh, Hiroaki Shimomoto, Yukihide Ishibashi, and Tsuyoshi Asahi.
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Journal Title
J. Poly. Sci., Part A: Polym. Chem.
Volume: Vo l. 51
Issue: 5
Pages: 1020-1023
DOI
Related Report
Peer Reviewed
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