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Fabrication and electrochemical properties of novel fullerene cluster microparticles

Research Project

Project/Area Number 22550123
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionThe University of Shiga Prefecture

Principal Investigator

AKIYAMA Tsuyoshi  滋賀県立大学, 工学部, 准教授 (20304751)

Co-Investigator(Renkei-kenkyūsha) YAMADA Sunao  九州大学, 大学院工学研究院応用化学部 門, 教授 (30136551)
TAKAHASHI Kazuyuki  神戸大学, 大学院理学研究科化学専攻, 准 教授 (60342953)
Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords膜・集合体 / フラーレン / 分子構造 / 電気化学 / 有機薄膜太陽電池 / 有機半導体
Research Abstract

A series of fullerene-aliphatic diamine adduct particle was synthesized by simply mixing of solutions of corresponding fullerenes and amines. From results of the reaction between fullerenes and amines, formation mechanism of adduct particles was investigated.
Fullerene-diamine adduct particles were solubilized in hydrophobic organic solvents by the addition of alkyl acid chloride. An organic thin-film solar cell using polythiophene and the solubilized fullerene-diamine adduct was fabricated and evaluated. The photovoltaic performance of the solar cell suggested that the solubilized fullerene-diamine adduct works as n-type semiconductor. Thin-film of fullerene-diamine adduct as n-type semiconductor was also possible to fabricate on the surface of amino-substituted substrate. C60 and amino-substituted porphyrin composite was also prepared by simply mixing C60 and the porphyrin in organic solvent. The composite contributed to photoelectric conversion.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (36 results)

All 2014 2013 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (31 results) (of which Invited: 2 results)

  • [Journal Article] Preparation and Photovoltaic Application of Fullerene–Porphyrin Composite Micropowder2013

    • Author(s)
      K. Kimura, T. Oku and T. Akiyama
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 7 Pages: 694-696

    • DOI

      10.1246/cl.130114

    • NAID

      10031183262

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of C60 assembly films via an fullerene-amineaddition reaction by using stepwise immersion2013

    • Author(s)
      S. Banya, T. Matsumoto, T. Oku and T. Akiyama
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: Vol. 433 Pages: 012007-012007

    • DOI

      10.1088/1742-6596/433/1/012007

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical half-cells using mixture films of fullerene-ethylenediamine adduct microparticles and polythiophene2013

    • Author(s)
      T. Akiyama, S. Matsumura, K.-i. Matsuoka, T. Oku and S. Yamada
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: Vol. 433 Pages: 012010-012010

    • DOI

      10.1088/1742-6596/433/1/012010

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Solubilization and Photovoltaic Application of C60 Fullerene-Ethylenediamine Adduct2013

    • Author(s)
      T. Akiyama, T. Ueda, Y. Ono, K. Kimura, K.-i. Matsuoka, S. Yamada and T. Oku
    • Journal Title

      Chem. Lett.

      Volume: Vol. 42 Issue: 2 Pages: 177-179

    • DOI

      10.1246/cl.2013.177

    • NAID

      10031143837

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Photovoltaic Application of Fullerene-Porphyrin Composite Micropowder2013

    • Author(s)
      Kento Kimura, Takeo Oku, Tsuyoshi Akiyama*
    • Journal Title

      Chemsitry Letters

      Volume: -

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] フラーレン−エチレンジアミン集合体の機能化と光電気化学応用2014

    • Author(s)
      番家朔人、鈴木厚志、奥健夫、秋山毅
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋市(名古屋大学)
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 有機電子材料を指向した溶媒可溶なフラーレン−ジアミン集合体の創製2014

    • Author(s)
      泉本大輔、木村健人、小野有司、番家朔人、奥健夫、秋山毅
    • Organizer
      日本化学会第9 4春季年会
    • Place of Presentation
      名古屋市(名古屋大学)
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 有機電子材料を指向した溶媒可溶なフラーレン-ジアミン集合体の創製2014

    • Author(s)
      泉本 大輔、木村 健人、小野 侑司、番家 翔人、奥 健夫、秋山 毅
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン-エチレンジアミン集合体の機能化と光電気化学応用2014

    • Author(s)
      番家 翔人、鈴木 厚志、奥 健夫、秋山 毅
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン-エチレンジアミン聞の相互付加反応に基づくC_<60>集合体薄膜の作製と有機薄膜太陽電池への応用2013

    • Author(s)
      秋山毅、番家朔人、藤田克彦、奥健夫
    • Organizer
      第32回固体・表面光化学討論会
    • Place of Presentation
      新宿区(早稲田大学)
    • Year and Date
      2013-12-12
    • Related Report
      2013 Final Research Report
  • [Presentation] フラーレンージアミン集合体膜を用いた逆型有機薄膜太陽電池の作製と評価2013

    • Author(s)
      番家朔人、松本泰輔、奥健夫、秋山毅
    • Organizer
      第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      豊中市(大阪大学)
    • Year and Date
      2013-08-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation and microscopic analysis of fullerene-diamine adducts as organic electronic material2013

    • Author(s)
      小野有司、秋山毅、奥健夫
    • Organizer
      第45回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      豊中市(大阪大学)
    • Year and Date
      2013-08-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Facile Fabrication of [60]Fullerene-Diamine Assembly Using an Alternate Immersion Process and Its Photovoltaic Application2013

    • Author(s)
      S. Banya, T. Matsumoto, T. Oku and T. Akiyama
    • Organizer
      9th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Shape Changing of C60-Ethylenediamine Adducts2013

    • Author(s)
      Y. Ono, T. Akiyama and T. Oku
    • Organizer
      9th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレンージアミン集合体膜を用いた逆型有機薄膜太陽電池の作製と評価2013

    • Author(s)
      番家 翔人、松本 泰輔、奥 健夫、秋山 毅
    • Organizer
      第45回 フラーレン・ナノチューブ・グラフェン&#8232;総合シンポジウム
    • Place of Presentation
      大阪大学 大阪大学会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation and microscopic analysis of fullerene-diamine adducts as organic electronic material2013

    • Author(s)
      小野 侑司、秋山 毅、奥 健夫
    • Organizer
      第45回 フラーレン・ナノチューブ・グラフェン&#8232;総合シンポジウム
    • Place of Presentation
      大阪大学 大阪大学会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン-アミン間の付加反応に基づく新規フラーレン集合体の作製と構造評価2013

    • Author(s)
      泉本 大輔、小野 侑司、木村 健人、奥 健夫、秋山 毅
    • Organizer
      第57回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都市 京都テルサ
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン-ジアミン付加体の構造と分光特性の相関2013

    • Author(s)
      小野 侑司、奥 健夫、秋山 毅
    • Organizer
      第7回有機π電子系シンポジウム
    • Place of Presentation
      高崎市 高崎ビューホテル
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン誘導体とエチレンジアミンを用いたフラーレン分子集合体の創製2013

    • Author(s)
      番家 翔人、奥 健夫、秋山 毅
    • Organizer
      第7回有機π電子系シンポジウム
    • Place of Presentation
      高崎市 高崎ビューホテル
    • Related Report
      2013 Annual Research Report
  • [Presentation] フラーレン-ジアミン間の付加反応を利用したC60集合体薄膜の作製と光電気化学応用2013

    • Author(s)
      番家翔人・松本泰輔・奥 健夫・秋山 毅
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン‐ジアミン交互付加体の作製と光電変換への応用2013

    • Author(s)
      小野侑司・木村健人・上田大喜・奥 健夫・秋山 毅
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン-ジアミン聞の付加反応を用いた新規フラーレン集合体の創製2012

    • Author(s)
      木村健人、小野有司、奥健夫、秋山毅
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      松山市(道後温泉)
    • Year and Date
      2012-12-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Photoelectrochemical Half-Cell consisting of C_<60>-Ethylenediamine Adduct and a Polythiophene2012

    • Author(s)
      T. Akiyama, S. Matsumura, K-i. Matsuoka, T. Oku, S. Yamada
    • Organizer
      The Asia-Pacific Interdisciplinary Research Conference (AP-IRC2012)
    • Place of Presentation
      田原市(伊良湖シーパーク&スパ)
    • Year and Date
      2012-11-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Fabrication and Photoelectrochemical Properties of C_<60> Fullerene-Porphyrin Composite Particle2012

    • Author(s)
      K. Kimura, T. Akiyama and T. Oku
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      草津市(立命館大学BKC)
    • Year and Date
      2012-06-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of fullerene-diamine adducts for organic solar cells2012

    • Author(s)
      T. Akiyama
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      草津市(立命館大学BKC)
    • Year and Date
      2012-06-23
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Development of fullerene-diamine adducts for organic solar cells2012

    • Author(s)
      T. Akiyama
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Fabrication and Photoelectrochemical Properties of C60 Fullerene-Porphyrin Composite Particle2012

    • Author(s)
      K. Kimura, T. Akiyama, T. Oku
    • Organizer
      8th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication and evaluation of C60 multilayer films using fullerene-amine addition reaction2012

    • Author(s)
      S. Banya, T. Akiyama, T. Oku
    • Organizer
      The Asia-Pacific Interdisciplinary Research Conference
    • Place of Presentation
      伊良湖シーパーク&スパ(愛知)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Photoelectrochemical Half-Cell consisting of C60-Ethylenediamine Adduct and a Polythiophene2012

    • Author(s)
      T. Akiyama, S. Matsumura, K-i. Matsuoka, T. Oku, S. Yamada
    • Organizer
      The Asia-Pacific Interdisciplinary Research Conference
    • Place of Presentation
      伊良湖シーパーク&スパ(愛知)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン-アミン間の付加反応を利用したフラーレン薄膜の創製2012

    • Author(s)
      番家 翔人、小野 侑司、木村 健人、秋山 毅、奥 健夫
    • Organizer
      第56回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都テルサ(京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン-ジアミン間の付加反応を用いた新規フラーレン集合体の創製2012

    • Author(s)
      木村 健人、小野 侑司、奥 健夫、秋山 毅
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      道後温泉(愛媛)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン-ジアミン付加体を用いた有機薄膜太陽電池の開発2012

    • Author(s)
      小野 侑司、木村 健人、上田 大喜、奥 健夫、秋山 毅
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      道後温泉(愛媛)
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレン-アミン間の相互作用を用いたπ電子分子集合体の創製2011

    • Author(s)
      木村健人、上田大喜、奥健夫、秋山毅
    • Organizer
      第5回有機π電子系シンポジウム
    • Place of Presentation
      ホテルアウィーナ大阪(大阪市)
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] フラーレン-ジアミン付加体の合成と光電気化学応用2011

    • Author(s)
      上田大喜、木村健人、秋山毅、奥健夫
    • Organizer
      第55回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都市(京都教育文化センター)
    • Year and Date
      2011-10-21
    • Related Report
      2013 Final Research Report
  • [Presentation] フラーレン-ジアミン付加体の合成と光電気化学応用2011

    • Author(s)
      上田大喜、木村健人、秋山毅、奥健夫
    • Organizer
      第55回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都教育文化センター
    • Year and Date
      2011-10-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光電変換を指向したフラーレン-機能性分子複合薄膜の創製2011

    • Author(s)
      木村健人、奥健夫、秋山毅、鈴木厚志
    • Organizer
      第55回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都教育文化センター
    • Year and Date
      2011-10-21
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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