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Evaluation of ionic conduction studied by simultaneous DTA and NMR

Research Project

Project/Area Number 22550126
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionNihon University

Principal Investigator

YAMADA Koji  日本大学, 生産工学部, 教授 (10166704)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords示差熱分析 / 固体 NMR / イオン伝導性 / ガラス転移 / 相転移 / 分子運動 / 固体NMR
Research Abstract

Solid materials such as inorganic glasses and polymer electrolytes are expected as electrolytes of the all solid-state fuel cell or lithium secondary battery. Broad line NMR isa sensitive technique to detect ionic and/or molecular diffusion. On the other hand, DSC/DTA is an indispensable technique to detect glass transition, crystallization, phase transition and melt of the sample. We have constructed simultaneous NMR and DTA measurement system on the basis of our previous experiences on these techniques. Using this new system, ionic diffusional motions in ionicliquid-based polymer electorlytes and glass forming aquous LiCl solutions were evaluated satisfactorily.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (19 results)

All 2013 2012 2011 2010

All Journal Article (10 results) (of which Peer Reviewed: 9 results) Presentation (8 results) Book (1 results)

  • [Journal Article] Study of Ion Diffusional Motion in Ionic Liquid based Polymer Electrolytes by Simultaneous Solid State NMR and DTA2013

    • Author(s)
      Authors, D. Rajput, K. Yamada, S. Sekhon
    • Journal Title

      J. Phys. Chem. B

      Volume: 117(8) Issue: 8 Pages: 2475-2481

    • DOI

      10.1021/jp3116512

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ion transport properties of ionic liquid based2012

    • Author(s)
      S. Sekhon, D. P. Kaur, J.-S.
    • Journal Title

      Electrochimica Acta

      Volume: 60 Pages: 366-374

    • DOI

      10.1016/j.electacta.2011.11.072

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conductivity Study on PEO Based Polymer Electrolytes Containing Hexafluorophosphate Anion: Effect of Plasticizer2012

    • Author(s)
      J.P. Sharma, K. Yamada, S. Sekhon
    • Journal Title

      Macromol. Symp.

      Volume: 315

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conductivity studies of plasticized PEO?HPF6?fumed silica nanocomposite polymer electrolyte system2012

    • Author(s)
      J. P. Sharma, K. Yamada, S. S. Sekhon
    • Journal Title

      Ionics

      Volume: 18 Issue: 1-2 Pages: 151-158

    • DOI

      10.1007/s11581-011-0610-y

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conductivity Study on PEO Based Polymer Electrolytes Containing Hexafluorophosphate Anion: Effect of Plasticizer2012

    • Author(s)
      J. P. Sharma
    • Journal Title

      Macromol. Symp.

      Volume: 315 Issue: 1 Pages: 188-197

    • DOI

      10.1002/masy.201250523

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 複素インピーダンス法によるリチウムイオン導電率評価法2012

    • Author(s)
      山田康治
    • Journal Title

      マテリアルステージ

      Volume: 12(9) Pages: 49-51

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Tunable Perovskite Semiconductor CH3NH3SnX3 (X : Cl, Br or I) Characterized by X-ray and DTA2011

    • Author(s)
      K. Yamada, K. Nakada, Y. Takeuchi, K. Nawa,Y. Yamane
    • Journal Title

      Bull. Chem. Soc. Jap.

      Volume: 84(9) Issue: 9 Pages: 926-932

    • DOI

      10.1246/bcsj.20110075

    • NAID

      130004152966

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium Ion Conduction Mechanism in LiInI4 Studied by Single Crystal 7Li NMR2011

    • Author(s)
      K. Yamada, S. Matsuyama, Y. Tomita, Y.Yamane
    • Journal Title

      Solid State Ionics

      Volume: 189 Issue: 1 Pages: 7-12

    • DOI

      10.1016/j.ssi.2011.02.020

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lithium Ion Conduction Mechanism in LiInI_4 Studied by Single Crystal^7Li NMR2011

    • Author(s)
      Koji Yamada, et al
    • Journal Title

      Solid State Ionics

      Volume: (in Press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Li^+Ionic Diffusion in LiCuO_2Exposed to Heating-Cooling Cycles2010

    • Author(s)
      Koichi Nakamura, et al
    • Journal Title

      J.Phys.Soc.Jpn.Suppl.

      Volume: 79 Pages: 80-83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 単結晶NMRによるイオン伝導機構の研究2011

    • Author(s)
      山田康治
    • Organizer
      第55回固体イオニクス研究会
    • Place of Presentation
      奈良
    • Year and Date
      2011-05-20
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] ハロゲン化物をベースとしたイオン伝導体探索と伝導機構2011

    • Author(s)
      村山駿、山根庸平、山田康治
    • Organizer
      第37回固体イオニクス討論会
    • Place of Presentation
      鳥取
    • Related Report
      2012 Final Research Report
  • [Presentation] リチウムイオン伝導体Li3(1-x)Na3xInBr6の構造と評価2010

    • Author(s)
      村山駿、山根庸平、山田康治
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-30
    • Related Report
      2012 Final Research Report
  • [Presentation] メカニカルミリング法によるCsHSO4をベースとする水結合型無機固体酸塩の合成とプロトン伝導性2010

    • Author(s)
      山根庸平、山田康治
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-30
    • Related Report
      2012 Final Research Report
  • [Presentation] イオン液体の動的挙動2010

    • Author(s)
      西村大地郎、山根庸平、山田康治
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-30
    • Related Report
      2012 Final Research Report
  • [Presentation] 19FNMRによる電気二重層キャパシタの充放電挙動2010

    • Author(s)
      段下隆太郎、山根庸平、山田康治
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-30
    • Related Report
      2012 Final Research Report
  • [Presentation] Lithium Ion Conduction Mechanism in LiInI4Studied by Single Crystal^7Li NMR Spectroscopy2010

    • Author(s)
      K.Yamada, S.Matsuyama and Y.Yamane
    • Organizer
      12^<th> Asian Conference on Solid State Ionics
    • Place of Presentation
      Wuhan University of Technology, Wuhan, China.
    • Related Report
      2012 Final Research Report
  • [Presentation] Lithium Ion Conduction Mechanism in LiInI_<4> Studied by Single Crystal ^7 Li NMR Spectroscopy2010

    • Author(s)
      Koji Yamada, et al
    • Organizer
      12^<th> Asian Conference on Solid State Ionics
    • Place of Presentation
      Wuhan, China
    • Related Report
      2010 Annual Research Report
  • [Book] マテリアルステージ2012

    • Author(s)
      山田康治
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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