• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Strongly-correlated electron system on pyrochlore-type oxides with metal-insulator transition

Research Project

Project/Area Number 22550129
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionDoshisha University

Principal Investigator

KATO Masaki  同志社大学, 理工学部, 教授 (90271006)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords金属絶縁体転移 / 電子相関 / 遷移金属酸化物 / スピングラス / 金属-絶縁体転移 / パイロクロア型酸化物 / スピンフラストレーション / 反強磁性 / 金属-絶縁体転移 / 金属-絶緑体転移
Research Abstract

The pyrochlore ruthenates Pb2-xLnxRu2O7- (Ln = Y, Nd) have been successfully synthesized by the solid-state reaction. The solid-solution compounds of Pb2-xLnxRu2O7- (Ln = Y, Nd) undergo a crossover from metallic (x = 0) to insulating (x = 2) with increasing x. Owing to a localized magnetic moment on Ru site, these compounds with x > 0.2 also indicate the spin-glass like behaviors at low temperature (T < TSG). As a result of electric resistivity measurements, the samples with 0.4 ? χ ? 0.8 show the metal-insulator transition. In the metallic region, values of electric resistivity obey T2 dependencies which indicate the strongly correlated electron behaviors in this system.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2012 2011 2010

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (16 results)

  • [Journal Article] Magnetic susceptibility of η-carbide-type molybdenum and tungsten carbides and nitrides2012

    • Author(s)
      T.Waki
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 344 Pages: 12017-12017

    • DOI

      10.1088/1742-6596/344/1/012017

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and magnetic properties of Cu oxides with low-dimensional structure2012

    • Author(s)
      M. Kato, Y. Nogi, S. Hongo, K. Hirota
    • Journal Title

      J. Phys

      Volume: 344 Pages: 1-6

    • DOI

      10.1088/1742-6596/344/1/012010

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] HIP synthesis of η-carbide-type nitrides Fe_3W_3N and Fe_6W_6N and their magnetic properties2011

    • Author(s)
      T.Waki
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 500 Issue: 39 Pages: 9451-9455

    • DOI

      10.1016/j.jallcom.2011.07.025

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of elemental substitutions on ruthenates with pyrochlore-type structure2011

    • Author(s)
      M. Kato, S. Harada, M. Fukatsu, K. Hirota
    • Journal Title

      J. Phys

      Volume: 313 Pages: 1-6

    • DOI

      10.1088/1742-6596/273/1/012152

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of elemental substitutions on ruthenates with pyrochlore-type structure2011

    • Author(s)
      M.Kato, S.Harada, M.Fukatsu K.Hirota
    • Journal Title

      Journal of Physics : Condensed Matter

      Volume: (掲載確定)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crossover from metallic to semiconducting in Pb2-xLnxRu2O7-δ (Ln = Sm, Eu) compounds with pyrochlore structure2010

    • Author(s)
      M. Kato, T. Imamura, M. Fukatsu, K. Hirota
    • Journal Title

      Mater. Sci. Forum

      Volume: 631-632 Pages: 483-488

    • DOI

      10.4028/www.scientific.net/msf.631-632.483

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crossover from Metallic to Semiconducting in Pb_<2-x>Ln_xRu_2O_<7-δ> (Ln=Eu, Sm) Compounds with Pyrochlore Structure2010

    • Author(s)
      M.Kato, T.Imamura, M.Fukatsu, K.Hirota
    • Journal Title

      Materials Science Forum

      Volume: 631-632 Pages: 483-488

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of (Ca_<1-x>La_x)MnO_3 ceramics with a high relative density and their power factor2010

    • Author(s)
      H.Taguchi, T.Kugi, M.Kato, K.Hirota
    • Journal Title

      Journal of American Ceramic Society

      Volume: 93 Pages: 3009-3011

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Bi-Ru系パイロクロア型酸化物Bi2-xNdxRu2O7-dにおける合成と物性評価2012

    • Author(s)
      伊藤誠扇,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度秋季大会
    • Place of Presentation
      立命館大学(滋賀県草津市)
    • Year and Date
      2012-11-21
    • Related Report
      2012 Final Research Report
  • [Presentation] パイロクロア型ルテニウム酸化物Pb2-xYxRu2O7-dにおける合成と元素置換効果2012

    • Author(s)
      相羽貴司,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度春季大会
    • Place of Presentation
      京都工芸繊維大学(京都市)
    • Year and Date
      2012-05-24
    • Related Report
      2012 Final Research Report
  • [Presentation] ガーネット型化合物AgCa2Cu2V3O12の元素置換と物性評価2012

    • Author(s)
      賢谷直人,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] スピンスパイラル磁気構造を有するBa2CuGe2O7の磁気的相互作用における元素置換効果2012

    • Author(s)
      小川裕史,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] パイロクロア型ルテニウム酸化物Pb2-xYxRu2O7-dにおける合成と元素置換効果2012

    • Author(s)
      相羽貴司,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Bi-Ru系パイロクロア型酸化物Bi2-xNdxRu2O7における合成と物性評価2012

    • Author(s)
      伊藤誠扇,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度秋季大会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 三角格子構造を有する層状遷移金属酸化物の合成および物性評価2012

    • Author(s)
      栢森勇佑,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度秋季大会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 電気伝導性酸化物La4BaCu5O13-dの元素置換効果と物性評価2012

    • Author(s)
      杉原正弥,林田浩一,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度秋季大会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] マグネリ相VnO2n-1の合成と金属-非金属転移2012

    • Author(s)
      岩垣一規,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成24年度秋季大会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低次元構造を有するBa-In-Cu系酸化物の合成と物性評価2011

    • Author(s)
      松尾有希子,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪大学(吹田市)
    • Year and Date
      2011-10-28
    • Related Report
      2012 Final Research Report
  • [Presentation] 層状コバルト酸化物CoNb_2O_6の合成と物性評価2011

    • Author(s)
      大河内亮, 加藤将樹, 廣田健
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪大学コンベンションセンター(大阪)
    • Year and Date
      2011-10-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 体次元構造を有するNa-In-Cu系酸化物の合成と物性評価2011

    • Author(s)
      松尾有希子, 加藤将樹, 廣田健
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪大学コンベンションセンター(大阪)
    • Year and Date
      2011-10-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 電気伝導性酸化物La_4BaCu_5O_<13-δ>の元素置換および酸素不定比性と物性評価2011

    • Author(s)
      林田浩一, 加藤将樹, 廣田健
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪大学コンベンションセンター(大阪)
    • Year and Date
      2011-10-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] アナターゼ型およびルチル型構造をもつTi1-xMxO2 (M = Nb,Ta) 化合物の合成と物性評価2010

    • Author(s)
      東佳子,加藤将樹,廣田健
    • Organizer
      粉体粉末冶金協会平成22年度秋季大会
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2010-11-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and physical properties of Cu oxides with low-dimensional tri-rutile and α-PbO2 type structure2010

    • Author(s)
      Masaki Kato
    • Organizer
      International and Interdisciplinary Workshop on Novel Phenomena in Integrated Complex Sciences: from Non-living to Living Systems
    • Place of Presentation
      Coop-Inn Kyoto,京都市
    • Year and Date
      2010-10-14
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and physical properties of Cu oxides with low-dimensional tri-rutile and α-PbO2 type structure2010

    • Author(s)
      Masaki Kato
    • Organizer
      International and Interdisciplinary Workshop on Novel Phenomena in Integrated Complex Sciences : from Non-living to Living Systems
    • Place of Presentation
      Coop-Inn Kyoto(京都)
    • Year and Date
      2010-10-14
    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi