| Project/Area Number |
22550130
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Tokyo University of Science, Yamaguchi |
|---|
Principal Investigator |
|
|---|
| Research Collaborator |
OHSHIMA Shuhei 山口東京理科大学, 大学院修士課程
INOUE Takeshi 山口東京理科大学, 大学院修士・博士課程
YAHIRO Hiroshi 山口東京理科大学, 大学院修士課程
USUI Kazuki 山口東京理科大学, 基礎工学部
SUMIYOSHI Makoto 山口東京理科大学, 工学部
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
|---|
| Keywords | ずれ応力 / 高圧実験 / フォトクロミズム / メカノクロミズム / 赤外ラマンスペクトル / スピロピラン / ジアリールエテン / アゾベンゼン / 剪断歪み / ラマンスペクトル / 高圧 / 赤外スペクトル / 異性化 |
|---|
| Research Abstract |
The purpose of this study is to create the "Shearchromism" which is able to control the photochromic properties by the application of shear stress coupled with the light irradiation. In order to investigate the molecular structures of photochromic compounds, we have performed the in situ observations under microscope with spectroscopic measurements. For nitrospiropyrans, the photoisomerization between open and closed-ring isomers was suppressed by the shear stress and its response was depended on the molecular shape. For diarylethene of PFCP, it was suggested that the photochromic behavior could be adjusted by the effect of shear stress and light. For azobenzene derivative, the Raman spectra suggest that the shear stress acts the molecules in the crystals in the same way as light irradiation.
|
