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Functionalization of dye-sensitized solar cell electrolytes by synergetic use of aromatic onium based ionic liquids

Research Project

Project/Area Number 22550131
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionWakayama National College of Technology

Principal Investigator

TSUNASHIMA Katsuhiko  和歌山工業高等専門学校, 物質工学科, 准教授 (90550070)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsイオン液体 / 四級オニウム塩 / 芳香族化合物 / 有機太陽電池 / 色素増感型太陽 電池 / 電解質 / 色素増感型太陽電池 / 芳香話化合物
Research Abstract

Ionic liquids have been regarded as promising electrolytes for dye-sensitized solar cells. In this work, new class of ionic liquids based on quaternary phosphonium cations containing phenyl group(s) was synthesized, physicochemically and electrochemically characterized in order to evaluate the possibility of the ionic liquids as dye-sensitized solar cell electrolytes. It was found that the ionic liquids showed favorable transport property and high thermal and electrochemical stabilities, which might be attributed to the interactions associated with aromatic rings in the phosphonium cations.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (48 results)

All 2013 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (37 results) (of which Invited: 1 results) Book (3 results)

  • [Journal Article] Physicochemical Properties of Trialkylphosphonium-Based Protic Ionic Liquids2012

    • Author(s)
      Katsuhiko Tsunashima, MasahiroFukushima, Masahiko Matsumiya
    • Journal Title

      Electrochemistry

      Volume: 80 Issue: 11 Pages: 904-906

    • DOI

      10.5796/electrochemistry.80.904

    • NAID

      130002147450

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Physical and electrochemical characterization of ionic liquids based on quaternary phosphonium cations containing a carbon-carbon double bond2011

    • Author(s)
      Katsuhiko Tsunashima, Yasushi Ono, Masashi Sugiya
    • Journal Title

      Electrochimica Acta

      Volume: 56巻 Issue: 11 Pages: 4351-4355

    • DOI

      10.1016/j.electacta.2011.01.023

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low viscous and highly conductive phosphonium ionicliquids based on bis(fluorosulfonyl)- amide anion as potential electrolytes2011

    • Author(s)
      Katsuhiko Tsunashima, Atsuko Kawabata, Masahiko Matsumiya, Shun Kodama, Rryuichi Enomoto, Masashi Sugiya, Yoshihito Kunugi
    • Journal Title

      Electrochemistry Communications

      Volume: 13巻 Issue: 2 Pages: 178-181

    • DOI

      10.1016/j.elecom.2010.12.007

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Methoxymethyl-Substituted Quaternary Phosphonium Ionic Liquids as Electrolytes for Dye-Sensitized Solar Cells2011

    • Author(s)
      Y.Kunugi, N.Hamada, S.Kodama, M.Sugiya, K.Tsunashima
    • Journal Title

      Electrochemistry

      Volume: Vol.79 Pages: 810-812

    • NAID

      130002150480

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low viscous and highly conductive phosphonium ionic liquids based on bis(fluorosulfonyl)amide anion as potential electrolytes2011

    • Author(s)
      K.Tsunashima, A.Kawabata, M.Matsumiya, S.Kodama, R.Enomoto, M.Sugiya, Y.Kunugi
    • Journal Title

      Electrochemistry Communications

      Volume: Vol.13 Pages: 178-181

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical and electrochemical characterization of ionic liquids based on quaternary phosphonium cations containing a carbon-carbon double bond2011

    • Author(s)
      K.Tsunashima, Y.Ono, M.Sugiya
    • Journal Title

      Electrochimica Acta

      Volume: Vol.56 Pages: 4351-4355

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical and electrochemical properties of room-temperature dicyanamide ionic liquids based on quaternary phosphonium cations2010

    • Author(s)
      Katsuhiko Tsunashima, Shun Kodama, Masashi Sugiya, Yoshihito Kunugi
    • Journal Title

      Electrochimica Acta

      Volume: 56巻 Issue: 2 Pages: 762-766

    • DOI

      10.1016/j.electacta.2010.08.106

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Physical and electrochemical properties of room-temperature dicyanamide ionic liquids based on quaternary phosphonium cations2010

    • Author(s)
      K.Tsunashima, S.Kodama, M.Sugiya, Y.Kunugi
    • Journal Title

      Electrochimica Acta

      Volume: Vol.56 Pages: 762-766

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] ホスホニウムイオン液体の物理化学 特性に及ぼすフェニル基導入の影響2012

    • Author(s)
      永井千尋,綱島克彦,小野恭史,松宮正 彦
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター
    • Year and Date
      2012-12-08
    • Related Report
      2012 Final Research Report
  • [Presentation] 不飽和結合を有する FSA アニオン型ホスホニウムイオン液体の物 性と電気化学特性2012

    • Author(s)
      酒井祐輝,綱島克彦,小野恭史,松宮正 彦,米川文広
    • Organizer
      第3回イオン液体討 論会
    • Place of Presentation
      沖縄県男女共 同参画センター
    • Year and Date
      2012-12-08
    • Related Report
      2012 Final Research Report
  • [Presentation] ビス(フルオロスルホニル)アミド型イオン液体を用いたポリピロールの電解 重合膜の生成とその電気化学的挙動2012

    • Author(s)
      綱島克彦,松林高弘,小野恭史,松宮正 彦
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター
    • Year and Date
      2012-12-08
    • Related Report
      2012 Final Research Report
  • [Presentation] Electrosynthesis of Polypyrrole in Low-Viscosity Ionic Liquids2012

    • Author(s)
      Katsuhiko Tsunashima, Takahiro Matsubayashi, Yasushi Ono, Masahiko Matsumiya
    • Organizer
      2012 Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-10
    • Related Report
      2012 Final Research Report
  • [Presentation] リン系イオン液体の特性と色 素増感型太陽電池への応用2012

    • Author(s)
      綱島克彦
    • Organizer
      有機太陽電 池研究会第2回研究会
    • Place of Presentation
      和歌山大学
    • Year and Date
      2012-09-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Electro- polymerization of pyrrole in 1-ethyl-3-methylimidazolium bis(fluoro- sulfonyl)amide ionic liquid2012

    • Author(s)
      Katsuhiko Tsunashima, Takahiro Matsubayashi, Yasushi Ono
    • Organizer
      63rd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Prague,Czech Republic
    • Year and Date
      2012-08-21
    • Related Report
      2012 Final Research Report
  • [Presentation] Physical and electrochemical properties of ionicliquids based on --bond-containing phosphonium cations2012

    • Author(s)
      Katsuhiko Tsunashima, Seiya Kikuchi, Yuhei Yamanaka, Masahiko Matsumiya, Yasushi Ono
    • Organizer
      63rd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Prague Czech Republic
    • Year and Date
      2012-08-20
    • Related Report
      2012 Final Research Report
  • [Presentation] ビス(フルオロスルホニル)アミド型 イオン液体を用いたピロールの電解酸化 重合反応2012

    • Author(s)
      綱島克彦,松林高弘,小野恭史,松宮正 彦
    • Organizer
      第36回有機電子移動化学討論 会
    • Place of Presentation
      ルミエール府中
    • Year and Date
      2012-06-21
    • Related Report
      2012 Final Research Report
  • [Presentation] ベンゾトリアゾレートアニオンを有する四級ホスホニウム塩の電気化学的挙動2012

    • Author(s)
      綱島克彦, 久道和納
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松(静岡県浜松市)
    • Year and Date
      2012-03-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] ホスホニウムイオン液体特性に及ぼすニ トリル基導入の影響2012

    • Author(s)
      綱島克彦,山中悠平,松宮正彦,小玉春
    • Organizer
      電気化学会第79回 大会
    • Place of Presentation
      アクトシティ浜松
    • Year and Date
      2012-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] ホスホニウムイオン液体特性に及ぼすニトリル基導入の影響2012

    • Author(s)
      綱島克彦, 山中悠平, 松宮正彦, 小玉春
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松(静岡県浜松市)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] ベンゾトリアゾレートアニオンを有する四級ホスホニウム型イオン液体の物性と電気化学特性2011

    • Author(s)
      綱島克彦, 久道和納
    • Organizer
      第2回イオン液体討論会
    • Place of Presentation
      キャンパスプラザ京都
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Physical and electrochemical properties of bis(fluorosulfonyl)- amide-based phosphonium ionic liquids2011

    • Author(s)
      Katsuhiko Tsunashima, Atsuko Kawabata, Masahiko Matsumiya, Shun Kodama
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Niigata Japan
    • Year and Date
      2011-09-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Physical and electrochemical properties of bis(fluorosulfonyl)amide-based phosphonium ionic liquids2011

    • Author(s)
      K.Tsunashima, A.Kawabata, M.Matsumiya, S.Kodama
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Physical and electrochemical characterization of room-temperature phosphonium ionic liquids based oncyano-containing anions2011

    • Author(s)
      Katsuhiko Tsunashima, Shinpei Yamamoto, Yoshihito Kunugi, Shun Kodama
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Niigata Japan
    • Year and Date
      2011-09-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Physical and electrochemical characterization of room-temperature phosphonium ionic liquids based on cyano-containing anions2011

    • Author(s)
      K.Tsunashima, S.Yamamoto, Y.Kunugi, S.Kodama
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2011-09-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] 色素増感太陽電池の電解液へ用いる4級ホスホニウム塩の多彩な応用2011

    • Author(s)
      尾棹敬子, 小玉春, 杉矢正, 綱島克彦, 功刀義人
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Class of Bis(fluorosulfonyl)amide Ionic Liquids Based on Quaternary Phosphonium Cations2011

    • Author(s)
      Katsuhiko Tsunashima, Atsuko Kawabata, Masahiko Matsumiya, Shun Kodama, Yoshihito Kunugi
    • Organizer
      4th International Congress on Ionic Liquids
    • Place of Presentation
      WashingtonDC USA
    • Year and Date
      2011-06-17
    • Related Report
      2012 Final Research Report
  • [Presentation] New Class of Bis(fluorosulfonyl)amide Ionic Liquids Based on Quaternary Phosphonium Cations2011

    • Author(s)
      K.Tsunashima, A.Kawabata, M.Matsumiya, S.Kodama, Y.Kunugi
    • Organizer
      4th International Congress on Ionic Liquids
    • Place of Presentation
      Hilton Crystal City(米国バージニア州アーリントン)
    • Year and Date
      2011-06-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] FSA アニオン型ホスホニウムイオン液体 の物性と電気化学特性:アンモニウム系 との比較2011

    • Author(s)
      川端温子,綱島克彦,松宮正彦,小玉 春
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2011-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] FSAアニオン型ホスホニウムイオン液体の物性と電気化学特性:アンモニウム系との比較2011

    • Author(s)
      川端温子, 綱島克彦, 松宮正彦, 小玉春
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感太陽電池電解質としてのジシアナミド型ボスホニウムイオン液体の開発2011

    • Author(s)
      綱島克彦, 山本秦平, 小玉春, 榎本隆一, 杉矢正, 功刀義人
    • Organizer
      第16回高専シンポジウム
    • Place of Presentation
      米子コンベンションセンター(鳥取県)
    • Year and Date
      2011-01-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] チオシアネートアニオンを有する四級ホスホニウム型イオン液体の合成と物性2011

    • Author(s)
      山本秦平, 綱島克彦, 小玉春, 榎本隆一, 功刀義人
    • Organizer
      第16回高専シンポジウム
    • Place of Presentation
      米子コンベンションセンター(鳥取県)
    • Year and Date
      2011-01-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] 低粘度型四級ホスホニウムイオン液体の設計と特性評価2011

    • Author(s)
      綱島克彦, 川端温子, 松宮正彦, 小玉春, 榎本隆一, 杉矢正, 功刀義人
    • Organizer
      第1回イオン液体討論会
    • Place of Presentation
      とりぎん文化会館(鳥取県)
    • Year and Date
      2011-01-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] シアノ系アニオンを有する四級ホスホニウム型イオン液体の合成と物性2011

    • Author(s)
      山本秦平, 綱島克彦, 小玉春, 杉矢正, 功刀義人
    • Organizer
      第1回イオン液体討論会
    • Place of Presentation
      とりぎん文化会館(鳥取県)
    • Year and Date
      2011-01-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] New class of room- temperature phosphonium ionic liquids based on a dicyanamide anion2010

    • Author(s)
      Katsuhiko Tsunashima, Masashi Sugiya, Yoshihito Kunugi
    • Organizer
      2010International Chemical Congress ofPacific Basin Societies
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
    • Related Report
      2012 Final Research Report
  • [Presentation] New class of room-temperature phosphonium ionic liquids based on a dicyanamide anion2010

    • Author(s)
      K.Tsunashima, M.Sugiya, Y.Kunugi
    • Organizer
      2010International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu Convention Center(ホノルル, 米国)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] FSAアニオンを有する四級ホスホニウム型イオン液体の合成と物性2010

    • Author(s)
      綱島克彦, 川端温子, 松宮正彦, 小玉春, 杉矢正
    • Organizer
      2010年電気化学秋季大会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2010-09-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] ビス(フルオロスルホニル)アミド型イオン液体を用いたピロールの電解酸化重合反応

    • Author(s)
      綱島克彦,松林高弘,小野恭史,松宮正彦
    • Organizer
      第36回有機電子移動化学討論会
    • Place of Presentation
      ルミエール府中(東京都府中市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Physical and electrochemical properties of ionic liquids based on p-bond-containing phosphonium cations

    • Author(s)
      K. Tsunashima, S. Kikuchi, Y. Yamanaka, M. Matsumiya, Y. Ono
    • Organizer
      63rd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Clarion Congress Hotel, Prague, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electrochemical behavior of quaternary phosphonium ionic liquids based on benzotriazolate anion

    • Author(s)
      K. Tsunashima, K. Kudo
    • Organizer
      63rd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Clarion Congress Hotel, Prague, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electropolymerization of pyrrole in 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide ionic liquid

    • Author(s)
      K. Tsunashima, T. Matsubayashi, Y. Ono
    • Organizer
      63rd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Clarion Congress Hotel, Prague, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] リン系イオン液体の特性と色素増感型太陽電池への応用

    • Author(s)
      綱島克彦
    • Organizer
      有機太陽電池研究会第2回研究会
    • Place of Presentation
      和歌山大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Electrosynthesis of Polypyrrole in Low-Viscosity Ionic Liquids

    • Author(s)
      K. Tsunashima, T. Matsubayashi, Y. Ono, M. Matsumiya
    • Organizer
      2012 Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Honolulu Convention Center, Hawaii, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] ホスホニウムイオン液体の物理化学特性に及ぼすフェニル基導入の影響

    • Author(s)
      永井千尋,綱島克彦,小野恭史,松宮正彦
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター 「てぃるる」(那覇市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 不飽和結合を有するFSAアニオン型ホスホニウムイオン液体の物性と電気化学特性

    • Author(s)
      酒井祐輝,綱島克彦,小野恭史,松宮正彦,米川文広
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター 「てぃるる」(那覇市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ビス(フルオロスルホニル)アミド型イオン液体を用いたポリピロールの電解重合膜の生成とその電気化学的挙動

    • Author(s)
      綱島克彦,松林高弘,小野恭史,松宮正彦
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター 「てぃるる」(那覇市)
    • Related Report
      2012 Annual Research Report
  • [Book] 非水系電解 液中での電気化学測定-有機溶媒とイオ ン液体を使いこなす-2013

    • Author(s)
      綱島克彦
    • Publisher
      技術情報協会
    • Related Report
      2012 Final Research Report
  • [Book] 『電気化学/インピーダンス測定のノウハウと正しいデータ解釈』,第3章, 第1節[4]「非水系電解液中での電気化学測定 -有機溶媒とイオン液体を使いこなす-」2013

    • Author(s)
      綱島克彦
    • Total Pages
      5
    • Publisher
      株式会社技術情報協会
    • Related Report
      2012 Annual Research Report
  • [Book] 『リチウム二次電池部材の測定・分析データ集』,第5章, 第7節「電解液の電気分解 ~イオン液体の電気化学的安定性の評価~」2012

    • Author(s)
      綱島克彦
    • Publisher
      株式会社技術情報協会
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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